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Visualization Study on Microscale Wetting Dynamics of Water Droplets on Dry and Wet Hydrophilic Membranes

  • Park, Kyungjin (Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH)) ;
  • Kim, Seong Yeon (Department of Chemical Engineering, McGill University) ;
  • Hong, Jiwoo (School of Mechanical Engineering, Soongsil University) ;
  • Kim, Jong Hyun (Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH)) ;
  • Lim, Geunbae (Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH))
  • Received : 2021.10.30
  • Accepted : 2021.12.14
  • Published : 2022.05.01

Abstract

The wetting dynamics of water droplets dispensed on the surface of dry and wet hydrophilic membranes were investigated experimentally from a microscale point of view. By using a high-speed, white-beam x-ray microimaging (WXMI) synchrotron, consecutive images displaying the dynamic motions of the droplets were acquired. Through analyzing the characteristics observed, it was found that the dry hydrophilic membrane showed local hydrophobicity at a certain point during the absorption process with apparent contact angles greater than 90. While on the other hand, the apparent contact angles of a water droplet absorbing into the wet membrane remained less than 90 and showed total hydrophilicity. The observations and interpretation of characteristics that affect the contact, wetting, recoiling, and dynamic behaviors of droplets are significant for controlling liquid droplet impingement in a desired manner.

Keywords

Acknowledgement

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2021R1I1A1A01061221).

References

  1. Wang, M.-J., Lin, F.-H., Ong, J. Y. and Lin, S.-Y., "Dynamic Behaviors of Droplet Impact and Spreading-Water on Glass and Paraffin," Colloids and Surfaces A: Physicochemical and Engineering Aspects, 339(1-3), 224-231(2009). https://doi.org/10.1016/j.colsurfa.2009.02.023
  2. Rein, M., "Phenomena of Liquid Drop Impact on Solid and Liquid Surfaces," Fluid Dynamic Research, 1993.
  3. Modaressi, H. and Garnier, G., "Mechanism of Wetting and Absorption or Water Droplets on Sized Paper: Effects of Chemical and Physical Heterogeneity," Langmuir, 18(3), 642-649(2002). https://doi.org/10.1021/la0104931
  4. Modak, C. D., Kumar, A., Tripathy, A. and Sen, P., "Drop Impact Printing," Nat Commun, 11(1), 4327(2020). https://doi.org/10.1038/s41467-020-18103-6
  5. Kwon, K.-S.; Kim, H.-S. and Choi, M., "Measurement of Inkjet First-drop Behavior Using a Highspeed Camera," Rev Sci Instrum, 87(3), 035101(2016). https://doi.org/10.1063/1.4940934
  6. Krainer, S., Smit, C. and Hirn, U., "The Effect of Viscosity and Surface Tension on Inkjet Printed Picoliter Dots," Rsc Adv, 9(54), 31708-31719(2019). https://doi.org/10.1039/C9RA04993B
  7. Li, Z., Kong, Q., Ma, X., Zang, D., Guan, X. and Ren, X., "Dynamic Effects and Adhesion of Water Droplet Impact on Hydrophobic Surfaces: Bouncing or Sticking," Nanoscale 9(24), 8249-8255(2017). https://doi.org/10.1039/c7nr02906c
  8. Wijshoff, H., "Drop Dynamics in the Inkjet Printing Process," Curr Opin Colloid In 36, 20-27(2018). https://doi.org/10.1016/j.cocis.2017.11.004
  9. Gao, Y. S., Jung, S. W. and Pan, L., "Interaction Forces between Water Droplets and Solid Surfaces across Air Films," Acs Omega 4(15), 16674-16682(2019). https://doi.org/10.1021/acsomega.9b02646
  10. Li, X., Ma, X. and Lan, Z., "Behavioral Patterns of Drop Impingement onto Rigid Substrates with a Wide Range of Wettability and Different Surface Temperatures," Aiche J., 55(8), 1983-1992(2009). https://doi.org/10.1002/aic.11849
  11. Shen, J., Liburdy, J. A., Pence, D. V. and Narayanan, V., "Droplet Impingement Dynamics: Effect of Surface Temperature During Boiling and Non-boiling Conditions," Journal of Physics: Condensed Matter, 21(46), 464133(2009). https://doi.org/10.1088/0953-8984/21/46/464133
  12. Verplanck, N., Coffinier, Y., Thomy, V. and Boukherroub, R., "Wettability Switching Techniques on Superhydrophobic Surfaces," Nanoscale Research Letters, 2(12), 577-596(2007). https://doi.org/10.1007/s11671-007-9102-4
  13. Larher, Y., "A Very Simple Derivation of Young's Law with Gravity Using a Cylindrical Meniscus," Langmuir, 13(26), 7299-7300(1997). https://doi.org/10.1021/la970786n
  14. Tran, P. A. and Webster, T. J., "Understanding the Wetting Properties of Nanostructured Selenium Coatings: the Role of Nanostructured Surface Roughness and Air-pocket Formation," Int J Nanomed, 8, 2001-2009(2013).
  15. Nakajima, A. and Nakajima, A., "Design of Hydrophobic Surfaces for Liquid Droplet Control," NPG Asia Mater. NPG Asia Materials, 3, 49-56(2011). https://doi.org/10.1038/asiamat.2011.55
  16. Yonemoto, Y. and Kunugi, T., "Theoretical Model of Droplet Wettability on a Low-Surface-Energy Solid under the Influence of Gravity," The Scientific World Journal, 2014, 647694(2014).
  17. Banerjee, S., "Simple Derivation of Young, Wenzel and Cassie-Baxter Equations and its Interpretations," arXiv preprint arXiv: 0808.1460 (2008).
  18. Whyman, G., Bormashenko, E. and Stein, T., "The Rigorous Derivation of Young, Cassie-Baxter and Wenzel Equations and the Analysis of the Contact Angle Hysteresis Phenomenon," Chemical Physics Letters, 450(4-6), 355-359(2008). https://doi.org/10.1016/j.cplett.2007.11.033
  19. Huang, X. M. and Gates, I., "Apparent Contact Angle around the Periphery of a Liquid Drop on Roughened Surfaces," Sci Rep-Uk, 10(1), (2020).
  20. Ferrari, M., "Switching Surface Wettability Properties," Journal of Adhesion Science and Technology, 28(8-9), 791-814(2014). https://doi.org/10.1080/01694243.2012.705090
  21. Pandey, P. R. and Roy, S., "Is it Possible to Change Wettability of Hydrophilic Surface by Changing Its Roughness?," The Journal of Physical Chemistry Letters, 4(21), 3692-3697(2013). https://doi.org/10.1021/jz401946v
  22. Chen, L. and Li, Z., "Bouncing Droplets on Nonsuperhydrophobic Surfaces," Phys Rev E Stat Nonlin Soft Matter Phys, 82(1-2), 016308(2010). https://doi.org/10.1103/PhysRevE.82.016308
  23. Kim, S., Choi, H., Polycarpou, A. A. and Liang, H., "Morphology-influenced Wetting Model of Nanopore Structures," Friction, 4(3), 249-256(2016). https://doi.org/10.1007/s40544-016-0122-x
  24. Bae, K. J., Yao, W. H., He, Y. L. and Cho, Y. R., "Wetting Behavior of Liquids on Micro- Patterned Polymer Surfaces Fabricated by Thermal Imprinting," Korean J Met Mater, 55(9), 624-631(2017). https://doi.org/10.3365/KJMM.2017.55.9.624
  25. Bormashenko, E., "Wetting Transitions on Biomimetic Surfaces," Philos T R Soc A, 368(1929), 4695-4711(2010). https://doi.org/10.1098/rsta.2010.0121
  26. Li, Y.; Li, J.; Liu, L.; Yan, Y.; Zhang, Q.; Zhang, N.; He, L.; Liu, Y.; Zhang, X.; Tian, D.; Leng, J. and Jiang, L., "Switchable Wettability and Adhesion of Micro/Nanostructured Elastomer Surface via Electric Field for Dynamic Liquid Droplet Manipulation," Advanced Science, 7(18), 2000772(2020). https://doi.org/10.1002/advs.202000772
  27. Shetabivash, H. and Dolatabadi, A., "Numerical Investigation of Air Mediated Droplet Bouncing on Flat Surfaces," AIP Advances, 7(9), 095003 (2017). https://doi.org/10.1063/1.4993837
  28. Quetzeri-Santiago, M. A.; Castrejon-Pita, A. A. and Castrejon-Pita, J. R., "The Effect of Surface Roughness on the Contact Line and Splashing Dynamics of Impacting Droplets," Sci Rep-Uk 9(1), 15030(2019). https://doi.org/10.1038/s41598-019-51490-5
  29. Kannangara, D., Zhang, H. and Shen, W., "Liquid-paper Interactions During Liquid Drop Impact and Recoil on Paper Surfaces," Colloids and Surfaces A: Physicochemical and Engineering Aspects, 280(1-3), 203-215(2006). https://doi.org/10.1016/j.colsurfa.2006.02.008
  30. Lee, K., Ivanova, N., Starov, V., Hilal, N. and Dutschk, V., "Kinetics of Wetting and Spreading by Aqueous Surfactant Solutions," Advances in Colloid and Interface Science, 144(1-2), 54-65(2008). https://doi.org/10.1016/j.cis.2008.08.005