• Title/Summary/Keyword: Conductive mechanism

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Characteristics of photo-thermal reduced Cu film using photographic flash light

  • Kim, Minha;Kim, Donguk;Hwang, Soohyun;Lee, Jaehyeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.293.1-293.1
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    • 2016
  • Various materials including conductive, dielectric, and semi-conductive materials, constitute suitable candidates for printed electronics. Metal nanoparticles (e.g. Ag, Cu, Ni, Au) are typically used in conductive ink. However, easily oxidized metals, such as Cu, must be processed at low temperatures and as such, photonic sintering has gained significant attention as a new low-temperature processing method. This method is based on the principle of selective heating of a strongly absorbent film, without light-source-induced damage to the transparent substrate. However, Cu nanoparticles used in inks are susceptible to the growth of a native copper-oxide layer on their surface. Copper-oxide-nanoparticle ink subjected to a reduction mechanism has therefore been introduced in an attempt to achieve long-term stability and reliability. In this work, a flash-light sintering process was used for the reduction of an inkjet-printed Cu(II)O thin film to a Cu film. Using a photographic lighting instrument, the intensity of the light (or intense pulse light) was controlled by the charged power (Ws). The resulting changes in the structure, as well as the optical and electrical properties of the light-irradiated Cu(II)O films, were investigated. A Cu thin film was obtained from Cu(II)O via photo-thermal reduction at 2500 Ws. More importantly, at one shot of 3000 Ws, a low sheet resistance value ($0.2527{\Omega}/sq.$) and a high resistivity (${\sim}5.05-6.32{\times}10^{-8}{\Omega}m$), which was ~3.0-3.8 times that of bulk Cu was achieved for the ~200-250-nm-thick film.

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Atomic Force Microscopy Study on Correlation between Electrical Transport and Nanomechanical properties of Graphene Layer

  • Kwon, Sang-Ku;Choi, Sung-Hyun;Chung, H.J.;Seo, S.;Park, Jeong-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.85-85
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    • 2010
  • Graphene, the building block of graphite, is one of the most promising materials due to their fascinating electronic transport properties. The pseudo-two-dimensional sp2 bonding in graphene layers yields one of the most effective solid lubricants. In this poster, we present the correlation between electrical and nanomechanical properties of graphene layer grown on Cu/Ni substrate with CVD (Chemical Vapor Deposition) method. The electrical (current and conductance) and nanomechanical (adhesion and friction) properties have been investigated by the combined apparatus of friction force microscopy/conductive probe atomic force microscopy (AFM). The experiment was carried out in a RHK AFM operating in ultrahigh vacuum using cantilevers with a conductive TiN coating. The current was measured as a function of the applied load between the AFM tip and the graphene layer. The contact area has been obtained with the continuum mechanical models. We will discuss the influence of mechanical deformation on the electrical transport mechanism on graphene layers.

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Influences on Distribution of Solute Atoms in Cu-8Fe Alloy Solidification Process Under Rotating Magnetic Field

  • Zou, Jin;Zhai, Qi-Jie;Liu, Fang-Yu;Liu, Ke-Ming;Lu, De-Ping
    • Metals and materials international
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    • v.24 no.6
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    • pp.1275-1284
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    • 2018
  • A rotating magnetic field (RMF) was applied in the solidification process of Cu-8Fe alloy. Focus on the mechanism of RMF on the solid solution Fe(Cu) atoms in Cu-8Fe alloy, the influences of RMF on solidification structure, solute distribution, and material properties were discussed. Results show that the solidification behavior of Cu-Fe alloy have influenced through the change of temperature and solute fields in the presence of an applied RMF. The Fe dendrites were refined and transformed to rosettes or spherical grains under forced convection. The solute distribution in Cu-rich phase and Fe-rich phase were changed because of the variation of the supercooling degree and the solidification rate. Further, the variation in solute distribution was impacted the strengthening mechanism and conductive mechanism of the material.

Non-conductive Film Effect on Ni-Sn Intermetallic Compounds Growth Kinetics of Cu/Ni/Sn-2.5Ag Microbump during Annealing and Current Stressing (열처리 및 전류인가 조건에서 Cu/Ni/Sn-2.5Ag 미세범프의 Ni-Sn 금속간화합물 성장 거동에 미치는 비전도성 필름의 영향 분석)

  • Kim, Gahui;Ryu, Hyodong;Kwon, Woobin;Son, Kirak;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.2
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    • pp.81-89
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    • 2022
  • The in-situ electromigration(EM) and annealing test were performed at 110, 130, and 150℃ with a current density of 1.3×105 A/cm2 conditions to investigate the effect of non-conductive film (NCF) on growth kinetics of intermetallic compound (IMC) in Cu/Ni/Sn-2.5Ag microbump. As a result, the activation energy of the Ni3Sn4 IMC growth in the annealing and EM conditions according to the NCF application was about 0.52 eV, and there was no significant difference. This is because the growth rate of Ni-Sn IMC is much slower than that of Cu-Sn IMC, and the growth behavior of Ni-Sn IMC increases linearly with the square root of time, so it has the same reaction mechanism dominated by diffusion. In addition, there is no difference in the activation energy of the Ni3Sn4 IMC growth because the EM resistance effect of the back stress according to the NCF application is not large.

High operating temperature stable OLEDs with reduced reflectivity cathodes

  • Popovic, Zoran D.;Aziz, Hany;Vamvounis, George;Hu, Nan-Xing;Paine, Tony
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.21-24
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    • 2003
  • The understanding of the mechanism of device degradation has been accomplished recently, for devices using $AlQ_3$ electron transport and emitter molecule. In this presentation the experimental evidence for the degradation mechanism of $AlQ_3$ based devices will be reviewed, showing that the hypothesis of an unstable $AlQ_3^+$ cation explains a large amount of experimental data. This hypothesis, however, explains not only the room temperature device degradation in time but also sheds light on temperature stability of OLEDs. Dependence of half-life of a series of devices with an emitter layer composed of a mixture of $AlQ_3$ and different hole transport molecules (mixed emitter layer) will be discussed when they are operated at elevated temperatures. These results can also be explained in the framework of an unstable $AlQ_3^+$ species. An OLED structure containing a doped mixed emitter layer will be described, which shows extraordinary stability, half-life of 1200 hours at operating temperature of 70 C and initial luminance of 1650 $cd/m^2$. We will also discuss a novel Black $Cathode^{TM}$ OLED with reduced optical reflectivity, which is also stable at elevated temperatures. The new cathode utilizes a conductive light-absorbing layer made of a mixture of metals and organic materials.

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Proposition of copper-foil magnetic sensor for the two-axis remote measurement of bending vibration of a non-metallic cylinder (비금속 배관에서의 원격 2 축 굽힘 진동 측정을 위한 동박 패치형 자기 센서의 제안)

  • Kim, Jin-Ki;Han, Soon-Woo;Kim, Yoon-Young
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.322-325
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    • 2007
  • This paper suggests a non-contact sensor for measuring bending vibration of a non-metallic cylinder in two orthogonal directions simultaneously. Recent research shows that a solenoid can pick up bending vibrations of a nonmetallic cylinder based on the reversed Lorentz force mechanism if an electrical conductive patch is attached to the cylinder. In this work, pairs of specially designed patches are used to make two independent paths for the current induced by bending vibrations, which enables the measurement of bending vibrations along two orthogonal directions simultaneously. The working performance of the developed sensor was verified by using two accelerometers.

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Proposition of Copper - Foil Magnetic Sensor for the Two-axis Remote Measurement of Bending Vibration of a Non-metallic Cylinder (비금속 배관에서의 원격 2축 굽힘 진동 측정을 위한 동박 패치형 자기 센서의 제안)

  • Kim, Jin-Ki;Han, Soon-Woo;Kim, Yoon-Young
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.18 no.4
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    • pp.381-385
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    • 2008
  • This paper suggests a non-contact sensor for measuring bending vibration of a non-metallic cylinder in two orthogonal directions simultaneously. Recent research shows that a solenoid can pick up bending vibrations of a nonmetallic cylinder based on the reversed Lorentz force mechanism if an electrically conductive patch is attached to the cylinder. In this work, pairs of specially designed patches are used to make two independent paths for the current induced by bending vibrations, which enables the measurement of bending vibrations along two orthogonal directions simultaneously. The working performance of the developed sensor was verified by using two accelerometers.

A Study on the Insulation Breakdown of Mica-Epoxy Composites (Mica-Epoxy 복합재료의 절연파괴에 관한 연구)

  • Kim, Hui-Gon;Kim, Hui-Su
    • Korean Journal of Materials Research
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    • v.7 no.8
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    • pp.650-653
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    • 1997
  • In large generators in power plants, stator winding insulations is exposed to a combination of thermal, electrical, mechanical, environmental stresses in service. These combined stresses cause insulation aging which leads to final insulation breakdown. In order to identify the breakdown mechanism, the stator winding insulation materials which are composed of mica-epoxy is analyzed by the component of materials with EDS, SEM techniques. We concluded that the potassium ions of mica are replaced by hydrogen ions at boundary area of mica-epoxy and/or mica-mica. It is proposed that through these phenomena, the conductive layers of potassium ions enable high voltage fields of multiple stresses to create voids and microcracks.

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Growing High-Quality Ir-Sb Nanostructures by Controlled Electrochemical Deposition

  • Nisanci, Fatma Bayrakceken
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.165-171
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    • 2020
  • The electrochemical preparation and spectroscopic characterisation of iridium-antimony (Ir-Sb) species is important owing to their potential applications as nanostructure materials. Nanostructures, i.e. nanoflower and nanodisk, of Ir-Sb were electrodeposited on conductive substrates using a practical electrochemical method based on the simultaneous underpotential deposition (UPD) of Ir and Sb from the IrCl3 and Sb2O3 at a constant potential. Electrochemical UPD mechanism of Ir-Sb was studied using cyclic voltammetry and potential-controlled electrochemical deposition techniques. Herein, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron and Raman spectroscopy were used to determine the morphological and structural properties of the electrochemically-synthesised Ir-Sb nanostructures.

Effects of Annealing on the Microstructure and Electrical Properties of ZnO Varistor (ZnO 바리스터 제조시 소결후 열처리 조건에 따른 미세구조 및 전기적 특성에 관한 연구)

  • Soh, J.J.;Han, S.W.;Kim, H.S.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1679-1681
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    • 1996
  • ZnO varistor with composition of 89wt%-ZnO, 3.0wt%-$Bi_{2}O_{3}$, 3.6wt%-$Sb_{2}O_{3}$, 1.16wt%-CoO, 0.88wt%-NiO, 0.71wt%-$MnO_2$, 0.93wt%-$Cr_{2}O_{3}$, 0.013wt%-$Al_{2}O_{3}$ was fabricated by sintering methods. The effects of annealing on the J-E characteristics of ZnO varistors were investigated. These changes of electric properties were found to be caused by the variation of grains and grain boundary related to annealing. And the conductive mechanism and micostructure of ZnO varistor were researched using I-V meter, SEM and XRD.

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