• Bulletin of the Korean Chemical Society
• /
• v.30 no.7
• /
• pp.1543-1546
• /
• 2009

Temperature and frequency dependent AC conductivity behavior has been studied for the chemically synthesized polyaniline-polymannuronate (PANI-PM) composites. The temperature (300 - 500 K) and frequency (100 - $10^6$ Hz) dependent AC conductivity suggests evidence for the transport mechanism in PANI-PM composites. The frequency dependence of AC conductivity has been investigated by the power law. The frequency exponent (s) is determined, and the data suggest that s decreases with temperature. The variation of s with temperature suggests that AC conduction is due to the correlated barrier hopping.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2000.11a
• /
• pp.67-70
• /
• 2000

This study was performed to investigate the material behavior of hybrid thermoplastic composites contained glass fiber and calcium carbonate. The composite was prepared with each combination ratio of calcium carbonate, and the content of glass fiber was fixed with 10% by weight. In order to investigate the material behavior for various combination ratio, tension test, flexural test, and impact test were performed. Microscopic observation were conducted to examine the fractured surface of specimen for tension test. And the material behavior of the hybrid thermoplastic composite immersed in salt water with definite time was investigated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1995.05a
• /
• pp.107-110
• /
• 1995

Space charge formation in epoxy/silica composites has been investigated by the pulsed electroacoustic (PEA) method. The addition of silica resulted in homocharge formation, which attributed to the interfacial trapping of injected charge at epoxy/silica interfaces, Homocharge accumulation with increase of voltage and silica content.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1995.11a
• /
• pp.310-312
• /
• 1995

In order to evaluate insulating reliability in epoxy composites, breakdown data were experimented in the temperature range of 20[$^{\circ}C$]∼160[$^{\circ}C$]. From these data, various parameters which are used in Weibull distribution could be derived, and using them, the reliability on a breakdown probability was calculated.

• Composites Research
• /
• v.26 no.6
• /
• pp.392-397
• /
• 2013

Functionally graded materials graded continuously and discretely, and are modeled using modified Mori- Tanaka and self-consistent methods. The proposed micromechanics model accounts for multi-phase heterogeneity and arbitrary number of layers. The influence of geometries and distinct elastic material properties of each constituent and voids on the effective elastic properties of FGM is investigated. Numerical examples of different functionally graded materials are presented. The predicted elastic properties obtained from the current model agree well with experimental results from the literature.

• Carbon letters
• /
• v.12 no.3
• /
• pp.177-179
• /
• 2011

The use of carbon nanotubes (CNTs) as a reinforcing material in a polymer matrix has increased in various industries. In this study, the flexural behavior of CNT-modified epoxy/basalt (CNT/epoxy/basalt) composites is investigated. The effects of CNT modification with silane on the flexural properties of CNT/epoxy/basalt composites were also examined. Flexural tests were performed using epoxy/basalt, oxidized CNT/epoxy/basalt, and silanized CNT/epoxy/basalt multi-scale composites. After the flexural tests, the fracture surfaces of the specimens were examined via scanning electron microscopy (SEM) to investigate the fracture mechanisms of the CNT/epoxy/basalt multi-scale composites with respect to the CNT modification process. The flexural properties of the epoxy/basalt composites were improved by the addition of CNTs. The flexural modulus and strength of the silane-treated CNT/epoxy/basalt multi-scale composites increased by approximately 54% and 34%, respectively, compared to those of epoxy/basalt composites. A SEM examination of the fracture surfaces revealed that the improvement in the flexural properties of the silane-treated CNT/epoxy/basalt multi-scale composites could be attributed to the improved dispersion of the CNTs in the epoxy.

• Journal of Korea Foundry Society
• /
• v.16 no.2
• /
• pp.132-140
• /
• 1996

Both cast and extruded composites of SiC whisker reinforced 6061 Al alloy matrix were fabricated by high pressure infiltration of the alloy melt into the SiC preform and subsequent hot extrusion of the composite ingots. The micro structures, age hardening behavior and mechanical properties have been examined on the both cast and extruded composites of SiCw/6061. The cast composites of SiCw/6061 were obtained in which SiC whiskers were randomly oriented. Hot extrusion of these cast composites lead to alignment of the whisker in the direction of extrusion. Strengthening effect of whisker in the extruded composites is lower than that of the cast composites. The cast composites of SiCw/6061 showed higher thensile strength and lower elongation than extruded composites of SiCw/6061 at all testing temperatures. Lower tensile strength and higher elongation of the extruded composites were attributable to fine grain structures in which grain boundary sliding occruued preferentially at elevated temperatures.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.05a
• /
• pp.122-125
• /
• 2001

The objective of this research is to develop hybridized yarns for thermoplastic composites, and to examine tile effect of cooling rate on mechanical properties of the composites. The co-braided yarn utilizing carbon fibers as reinforcements and Nylon 66 fibers as matrix materials has been fabricated. Thermoplastic composites have been manufactured by the hot-press forming process. For the processing conditions, cooling rates of $-2.5^{\circ}C$/min and $-60^{\circ}C$/min have been considered. Three-point bending test and losipescu shear test were performed to investigate the effect of the cooling rate and the surface treatment of carbon fibers. SEM photographs were used to investigate the fracture surfaces of the tested samples. The cooling rate of $-60^{\circ}C$/min resulted in the higher strength and elastic modulus for bending and shear tests. The composites of the epoxy-sized carbon fibers showed the lowest strength due to the degradation of the sizing material during the thermoforming process.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.10a
• /
• pp.29-32
• /
• 2001

The objective of this work was to optimize processing parameters of hybrid thermoplastic composites in compression molding. The mechanical properties of the composites manufactured with various forming conditions were measured to characterize processing parameters. Polypropylene(PP) composites containing randomly oriented long carbon fiber and carbon black were used in this work. The composite materials contained 5%, 10%, 15%, and 20% carbon fiber and 5%, 10%, 15%, 20%, and 25% carbon black by weight. Compression molding was conducted at various mold temperatures. The temperature of the material in the mid-plain was monitored during the forming. Crystallinity was also measured by using XRD. The tensile modulus of the composites increase, with increasing the mold temperature. However, the impact strength of the composites decreases as mold temperature increases.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.10a
• /
• pp.129-132
• /
• 2001

Fiber waviness is one of manufacturing defects encountered frequently in thick composite structures. It affects significantly on the behavior as well as strength of thick composites. The effects of fiber waviness on tensile/compressive nonlinear elastic behavior and strength of thick composite with fiber waviness are studied theoretically and experimentally. FEA(Finite Element Analysis) models are proposed to predict tensile/compressive nonlinear behavior and strength of thick composites. In the FEA models, both material and geometric nonlinearities were incorporated into the model using energy density, iterative mapping and incremental method. Also Tsai-Wu criteria was adopted to predict the strength of thick composites with fiber waviness. Tensile and compressive tests were conducted on the specimens with uniform fiber waviness. It was observed that the degree of fiber waviness in composites significantly affected the nonlinear behavior and strength of the composites