• Title/Summary/Keyword: Column reactor system

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Microfluidic Biosensor System for HDL Cholesterol

  • Kim, Joo-Eun;Paek, Se-Hwan
    • 한국생물공학회:학술대회논문집
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    • 2003.10a
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    • pp.717-720
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    • 2003
  • A chromogenic biosensor employing microfluidics on a chip has been developed for the determination of high-density lipoprotein (HDL) cholesterol (HDL-C) in human serum. We have investigated a plain and effective method to immobilize enzymes within the microchip without chemically modifying micro-channel or technically micro-fabricating column reactor and fluid channel network. In assessing risk factors of coronary heart disease, a micro-chip system would minimize requirements of instrument and reagent handling.

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Effect of Hydrophilic- and Hydrophobic-Media on the Fermentative Hydrogen Production in Trickling Bed Biofilter (생물학적 수소생산을 위한 Trickling Bed Biofilter에서의 친수성과 소수성 담체의 영향)

  • Jeon, Byung-Seung;Lee, Sun-Mi;Kim, Yong-Hwan;Chae, Hee-Jeong;Sang, Byoung-In
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.465-469
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    • 2006
  • Two mesophilic trickling bed bioreactors filled with two different types of media, hydrophilic- and hydrophobic-cubes, were designed and tested for hydrogen production via anaerobic fermentation of sucrose. Each reactor consisted of a column packed with polymeric cubes and inoculated with heat-treated sludge obtained from anaerobic digestion tank. A defined medium containing sucrose was fed with changing flow rate into the capped reactor, hydraulic retention time and recycle rate. Hydrogen concentrations in gas-phase were constant, averaging 40% for all conditions tested. Hydrogen production rates increased up to $10.5 L{\cdot};h^{-1}{\cdot}L^{-1}$ of reactor when influent sucrose concentrations and recycle rates were varied. Hydrophobic media provided higher value of hydrogen production rate than hydrophilic media at the same operation conditions. No methane was detected when the reactor was under a normal operation. The major fermentation by-products in the liquid effluent of the both trickling biofilters were acetate and butyrate. The reactor filled with hydrophilic media became clogged with biomass and bio gas, requiring manual cleaning of the system, while no clogging occurred in the reactor with hydrophobic media. In order to make long-term operation of the reactor filled with hydrophilic media feasible, biofilm accumulation inside the media in the reactor with hydrophilic media and biogas produced from the reactor will need to be controlled through some process such as periodical backwashing or gas-purging. These tests using trickling bed biofilter with hydrophobic media demonstrate the feasibility of the process to produce hydrogen gas in a trickle-bed type of reactor. A likely application of this reactor technology could be hydrogen gas recovery from pre-treatment of high carbohydrate-containing wastewaters.

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Reaction Kinetic Study on Pyrolysis of Waste Polystyrene using Wetted Column Reactor (Wetted Column 반응기를 이용한 폴리스티렌 열분해 반응속도론적 연구)

  • You, Young Gil;Yoon, Byung Tae;Kim, Seong Bo;Choi, Myoung Jae;Choi, Cheong Song
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.535-539
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    • 2008
  • Conversion to oil, yield of styrene and formation of side products such as ${\alpha}-methyl$ styrene, ethyl benzene, benzene, toluene, dimer and trimer were affected by residue formed during thermal degradation. Also, control of reaction temperature had a difficulty at the first stage. Thus, new reaction system using wetted-wall type reactor was proposed and examined on various parameters such as reaction temperature, feeding rate and removal velocity of formed vapor. Optimun condition was obtained from continuous thermal degradation using wetted-wall type reactor and reaction kinetic study was carried out at new type reactor.

The Characteristics of Bioremediation for VOCs in Soil Column (VOCs 처리를 위한 미생물의 토양복원화 특성)

  • 손종렬;장명배;조광명
    • Journal of environmental and Sanitary engineering
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    • v.17 no.1
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    • pp.52-56
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    • 2002
  • The study was carried out to evaluate the characteristics of biodegradation by Pseudomonas putida G7 in soil column. The reactor system was used to investigate mass transfer of VOCs as Toluene in a column of unsaturated soil. Determination of the fate of VOCs in unsaturated soil is necessary to evaluate the feasibility of natural attenuation as a VOCs remediation strategy. The objective of this study was to develop a mechanistically based mathematical model that would consider the interdependence of VOC transport, microbial activity, and sorptive interactions in a moist, unsaturated soil. Because the focus of the model was on description of natural attenuation, the advective VOCs transport that is induced in engineered remediation processes such as vapor extraction was not considered. It can be concluded that the coefficient for gas liquid mass-transfer was found to be a key parameter controlling the ability of bacteria to VOCs. Finally, it appeared that bioremediation technology of VOCs which are difficult to be decomposed by chemical methods.

Dynamic Modeling of the Free Piston Stirling Pump for the Passive Safety Injection of the Next Generation Nuclear Power Plant (차세대 신형원자로의 피동형 안전 주입장치를 위한 프리피스톤 스터링 펌프의 동특성 모델)

  • Lee, Jae-Young
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.11a
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    • pp.149-154
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    • 1999
  • This paper describes a passive safety injection system with free piston Stirling pump working withabundant decay heat in the nuclear reactor during the hypothetical accident. The water column in the tube assembly connected from the hot chamber to the cold chamber in the pump oscillates periodically due to thermal volume changes of non-condensable gas in each chamber. The oscillating pressure in the water column is converted into the pumping power with a suction-and-bleed type valve assembly. In this paper a dynamic model describing the frequency of oscillation and pumping pressure is developed. It was found that the pumping pressure is a function of the temperature difference between the chambers. Also, the frequency oscillation depends on the length of the tube with water column.

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CHARACTERISTICS OF SELF-LEVELING BEHAVIOR OF DEBRIS BEDS IN A SERIES OF EXPERIMENTS

  • Cheng, Songbai;Yamano, Hidemasa;Suzuki, TYohru;Tobita, Yoshiharu;Nakamura, Yuya;Zhang, Bin;Matsumoto, Tatsuya;Morita, Koji
    • Nuclear Engineering and Technology
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    • v.45 no.3
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    • pp.323-334
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    • 2013
  • During a hypothetical core-disruptive accident (CDA) in a sodium-cooled fast reactor (SFR), degraded core materials can form roughly conically-shaped debris beds over the core-support structure and/or in the lower inlet plenum of the reactor vessel from rapid quenching and fragmentation of the core material pool. However, coolant boiling may ultimately lead to leveling of the debris bed, which is crucial to the relocation of the molten core and heat-removal capability of the debris bed. To clarify the mechanisms underlying this self-leveling behavior, a large number of experiments were performed within a variety of conditions in recent years, under the constructive collaboration between the Japan Atomic Energy Agency (JAEA) and Kyushu University (Japan). The present contribution synthesizes and gives detailed comparative analyses of those experiments. Effects of various experimental parameters that may have potential influence on the leveling process, such as boiling mode, particle size, particle density, particle shape, bubbling rate, water depth and column geometry, were investigated, thus giving a large palette of favorable data for the better understanding of CDAs, and improved verifications of computer models developed in advanced fast reactor safety analysis codes.

Quantitative Comparison and Analysis of Decommissioning Scenarios Using the Analytic Hierarchy Process Method and Digital Mock-up System (계층화 분석과정법과 디지털 목업을 이용한 정량적 해체 시나리오 평가)

  • Kim, Sung-Kyun;Park, Hee-Sung;Jung, Chong-Hun;Lee, Kune-Woo
    • Journal of Energy Engineering
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    • v.16 no.3
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    • pp.93-102
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    • 2007
  • This paper presents a scenario evaluation model of the AHP (Analytic Hierarchy Process) to evaluate dismantling scenarios considering quantitative and qualitative considerations. And decommissioning information producing modules which can obtain a dismantling schedule, quantify radioactive waste, visualize a radioactive inventory, estimate a decommissioning cost, and estimate a worker's exposure was developed to assess qualitatively decommissioning information. The digital mock-up (DMU) system was developed to verify dismantling processes and find error of scenarios in virtual space. It combines and manages the decommissioning information producing modules, the decommissioning DB, and the dismantling evaluation module synthetically. By using AHP model and DMU system, the thermal column in KRR-1 was evaluated on plasma arc cutting scenario and nibbler cutting scenario using the developed decommissioning DMU system.

Removal Characteristics of Heavy Metals in Acid Mine Drainage (AMD) Using Porous Starfish Ceramics (II) - Treatment of AMD in a Column Reactor System (불가사리 소재 다공성 세라믹을 이용한 산성광산배수 내 중금속의 제거특성(II) - 컬럼연속 실험을 통한 산성광산배수의 처리특성)

  • Lee, Yonghwan;Yim, Soobin
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.12
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    • pp.25-34
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    • 2014
  • The objective of this study was to investigate the removal characteristics and the elimination mechanism of heavy metals in Acid Mine Drainage (AMD) using spherical-type porous Zeolite-StarFish ceramics (porous ZSF ceramics) packed in a continuous column reactor system. The average removal efficiencies of heavy metals in AMD were Al 98.7, As 98.7, Cd 96.0, Cu 89.1, Fe 99.5, Mn 94.4, Pb 96.3 and Zn 80.8 % during 110 days of operation time. The average removal capacity of porous ZSF ceramics for heavy metals were measured to be Al 21.76, As 1.52, Cd 1.27, Cu 3.41, Fe 44.83, Mn 3.48, Pb 2.36 and Zn $3.76mg/kg{\cdot}day$. The analysis results of mechanism using SEM, EDS and XRD exhibited that the porous ZSF ceramics could act as a multi-functional ceramics for the removal of heavy metals in AMD through the reactions of precipitation, adsorption and ion-exchange. The experimental results of column reactor system displayed that the porous ZSF ceramics would be a consistently efficient agent for the removal of heavy metals in AMD for a long term.

Bio-regeneration of Ion-exchange Resin for Treating Reverse Osmosis Concentrate (RO 농축폐액의 처리를 위한 이온교환수지의 생물재생)

  • Bae, Byung-Uk;Nam, Youn-Woo
    • Journal of Korean Society on Water Environment
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    • v.30 no.5
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    • pp.517-523
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    • 2014
  • In order to remove both nitrate and sulfate present in the concentrate of RO(reverse osmosis) process, a combined bio-regeneration and ion-exchange(IX) system was studied. For this purpose, both denitrifying bacteria(DNB) and sulfate reducing bacteria(SRB) were simultaneously cultivated in a bio-reactor under anaerobic conditions. When the IX column containing a nitrate-selective A520E resin was fully exhausted by nitrate and sulfate, the IX column was bio-regenerated by pumping the supernatant of the bio-reactor, which contains MLSS concentration of $125{\pm}25mg/L$, at the flowrate of 360 BV/hr. Even though the nitrate-selective A520E resin was used, the breakthrough curves of ionic species showed that sulfate was exhausted earlier than nitrate. The reason for this result is due to the fact that the concentration of sulfate in RO concentrate was 36 to 48 times higher than nitrate. The bio-reactor was successfully operated at a volumetric loading rate of 0.6 g $COD/l{\cdot}d$, nitrate-N loading rate of 0.13 g $NO_3{^-}-N/l{\cdot}d$, and sulfate loading rate of 0.08 g $SO_4{^{2-}}/l{\cdot}d$. The removal rate of SCOD, nitrate-N, sulfate was 90, 100, and 85%, respectively. When the virgin resin was fully exhausted and consecutively bio-regenerated for 2 days, 81% of nitrate and 93% of sulfate were reduced. When the virgin resin was repeatedly used up to 4 cycles of service and bio-regeneration, the ion-exchange capacity of bio-regenerated resin decreased to 95, 91, 88, and 81% of virgin resin.

Clean-up of Contaminated Groundwater by Permeable Reactive Barrier (투수성 반응벽에 의한 오염지하수 복원효과 분석)

  • 정하익;김상근
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.03b
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    • pp.542-547
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    • 2000
  • It has become interested in the concept of permeable barriers for the containment and/or destruction of contaminated groundwater. The purpose of these trench-like barriers is to provide in situ capture and possibly destruction of the contaminant while preserving groundwater flow to uncontaminated zones. For instance, a trichloreethylene(TCE) plume may be contained by a permeable in which reactive iron reduces TCE to ethylene and ethane, compounds which can be easily biodegraded. The objective of this research is to examine the feasibility of using zero-valent iron as a clean-up media in permeable reactive barrier system. A series of laboratory column tests are performed. The concentration of influent and effluent water and the rate of clean up are analysed from these test results. The experimental result shows that the majority of the contamination in groundwater is removed in the reactor. And it shows the corresponding increase in the concentration of chloride ions through the reactor. Results from this study indicate that permeable reactive barrier containing admixtures of zero-valent iron and other materials can effectively clean up groundwater contaminated with organic compounds.

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