• Title/Summary/Keyword: CoGa 합금

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Chemical and Electronic structures of $Co_{1-x}Ga_x$ alloys by X-ray Analyses (X-선을 이용한 $Co_{1-x}Ga_x$ 합금계의 화학구조와 전자구조)

  • 유권국;이주열;지현배;이연승
    • Journal of the Korean Vacuum Society
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    • v.13 no.2
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    • pp.86-91
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    • 2004
  • Transiton-metal gallides attract wide interest as a candidate for high-temperature structural materials. In a wide composition range, in which it was known that Co-Ga alloy have CsCl (B2) crystallographic structure, a systematic study on the correlation between physical properties and electronic structures of Co-gallides was performed. $Co_{l-x}Ga$ $_{x}$ alloys ($0.35\leq$x$\leq0.55$) were prepared by arc-melting method and were annealed at $1000 ^{\circ}C$ for 48hour to increase the homogeneity. In this composition range all the prepared alloys have the CsCl (B2) structure. The chemical states and the electronic structure were studied by using x-ray photoemission spectroscopy (XPS), and x-ray absorption near-edge structure (XANES), and exhibit different physical properties depending on the composition. During the annealing, a significant oxidation has happened and all the oxygen atoms are incorporated with the Ga atoms to form a $Ga_2O_3$ phase. In a view point of electronic structure, the $Co_{l-x}Ga$ $_{x}$ alloys were formed by the Ga(p) - Co(d) hybridization.

Half-metallicity and Magnetism at the (001) Surfaces of the Quaternary Heusler Alloys CoFeCrZ (Z = Ga, Ge): A First-principles Study (4원 호이슬러 합금 CoFeCrZ(Z = Ga, Ge)의 (001) 표면에서의 자성과 반쪽금속성: 제일원리 계산 연구)

  • Kim, Dong-Chul;Lee, Jae Il
    • Journal of the Korean Magnetics Society
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    • v.25 no.2
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    • pp.31-38
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    • 2015
  • Recently, a first-principles study led to a prediction that quaternary Heusler compounds, CoFeCrZ (Z = Ga, Ge) are excellent half-metallic ferromagnets. In this study, we investigate the electronic and the magnetic properties at the (001) surfaces of CoFeCrGa and CoFeCrGe by means of the full-potential linearized augmented plane wave (FLAPW) method within generalized gradient approximation. We considered two types of surface termination: CoFe-terminated and CrZ-terminated surfaces, Z being either Ga or Ge. From the calculated total magnetic moments and the local density of states, we found that half-metallicity is not preserved for all the surfaces. But the calculated atomic density of states showed that CrGa-terminated surface of the CoFeCrGa is almost half-metallic. The magnetic moment of the Co, Fe, or Cr atoms at the surface or subsurface layers in each system had very different values.

The Effect of Magnetic Field Treatment on Enhanced Exchange Coupling of $Nd_{2}Fe_{14}B/Fe_{3}B$ Magnet (자장중 열처리에 의한 $Nd_{2}Fe_{14}B/Fe_{3}B$ 초미세립 복합자성상의 자기특성 향상)

  • 박언병;양충진
    • Journal of the Korean Magnetics Society
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    • v.6 no.2
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    • pp.80-85
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    • 1996
  • An externally applied magnetic field during annealing the $Nd_{2}Fe_{14}B/Fe_{3}B$ based spring magnet was found to enhance the exchange coupling between the hard and soft magnetic grains. More than 30 % increase in remanence values for melt-spun $Nd_{4}Fe_{73.5}Co_{3}(Hf_{1-x}-Ga_{x})B_{18.5}$(x=0, 0.5, 1.0) alloys was resulted from uniform distribution of $Fe_{3}B$, $\alpha$-Fe as well as $(Nd_{2}Fe_{14}B)$, and also from reduced grain size of those phases by 20 %. The result also showed that there is an optimum grain size exhibiting a high coercivity value which will be discussed in terms of previously simulated exchange coupling parameter.

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Sintering and Rolling Behavior of Cu-50In-13Ga Ternary Alloy Powder for Sputtering Target (스퍼터링 타겟용 Cu-50In-13Ga 3원계 합금 분말의 소결 및 압연 거동)

  • Kim, Dae-Won;Kim, Yong-Ho;Kim, Jung-Han;Kim, Dae-Guen;Lee, Jong-Hyeon;Choi, Kwang-Bo;Son, Hyeon-Taek
    • Journal of Powder Materials
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    • v.19 no.4
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    • pp.264-270
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    • 2012
  • In this study, we mainly focus on the study of densification of gas-atomized Cu-50 wt.%In-13 wt.%Ga alloy powder without occurrence of crack during the forming process. Cu-50 wt.%In-13 wt.%Ga alloy powder was consolidated by sintering and rolling processes in order to obtain high density. The phase and microstructure of formed materials were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical microscopy (OM), respectively. Warm rolling using copper can result in the improvement of density. The specimen obtained with 80% of rolling reduction ratio at $140^{\circ}C$ using cooper can have the highest density of $8.039g/cm^3$.

Thermal Stability Improvement of Ni-Silicide using Ni-Co alloy for Nano-scale CMOSFET (나노급 CMOSFET을 위한 니켈-코발트 합금을 이용한 니켈-실리사이드의 열안정성 개선)

  • Park, Kee-Young;Jung, Soon-Yen;Han, In-Shik;Zhang, Ying-Ying;Zhong, Zhun;Li, Shi-Guang;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.1
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    • pp.18-22
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    • 2008
  • In this paper, the Ni-Co alloy was used for thermal stability estimation comparison with Ni structure. The proposed Ni/Ni-Co structure exhibited wider range of rapid thermal process windows, lower sheet resistance in spite of high temperature annealing up to $700^{\circ}C$ for 30 min, more uniform interface via FE-SEM analysis, NiSi phase peak. Therefore, The proposed Ni/Ni-Co structure is highly promising for highly thermal immune Ni-silicide for nano-scale MOSFET technology.