• Geomechanics and Engineering
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• 제33권1호
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• pp.65-75
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• 2023

Recycled concrete aggregate (RCA) is widely used as a construction material in road construction, concrete structures, embankments, etc. However, it has been reported that calcite (CaCO₃) precipitation from RCA can be a cause of clogging when used in drainage applications. An accelerated calcite precipitation (ACP) procedure has been devised to evaluate the long-term geochemical performance of RCA in subsurface drainage systems. While the ACP procedure was useful for the French Drain application, there remained opportunities for improvement. In this study, key factors that control the formation of calcite precipitation were quantitatively evaluated, and the results were used to improve the current prototype ACP method. A laboratory parametric study was carried out by investigating the effects of reaction temperature and time on the formation of calcite precipitation of RCA, with determining an optimum reaction temperature and time which maximizes calcite precipitation. The improved ACP procedure was then applied to RCA samples that were graded for Type I Underdrain application, to compare the calcite precipitation. Two key findings are (1) that calcite precipitation can be maximized with the optimum heating temperature (75℃) and time (17 hours), and (2) the potential for calcite precipitation from RCA is not as significant as for limestone. With the improved ACP procedure, the total amount of calcite precipitation from RCAs within the life cycle of a drain system can be determined when RCAs from different sources are used as pipe backfill materials in a drain system.

• 한국결정성장학회지
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• 제24권6호
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• pp.246-251
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• 2014

최근 태양전지의 효율을 증가시키기 위한 연구가 많이 이루어지고 있으며, 특히 단결정 실리콘 웨이퍼의 경우 높은 효율을 낼 수 있는 소재로써 고효율 태양전지연구에 많이 이용되고 있다. 본 연구에서는 단결정으로 Czochralski(Cz)-Si 성장 시 산소농도를 다르게 하여 산소석출결함의 변화와 그에 따른 셀효율과의 관계를 비교하였다. 산소불순물은 Cz법으로 성장시킨 실리콘의 주된 불순물이다. 산소불순물 존재 시 태양전지 공정에서 산소석출결함이 생성되며 발생된 산소석출결함은 셀효율에 악영향을 미치게 된다. 그러므로 고효율 태양전지를 위한 웨이퍼를 생산하기 위한 산소석출결함 밀도와 셀효율의 상관성을 연구하였다. 또한 산소농도에 따른 산소석출결함을 분석하여 산소석출결함이 발생되지 않는 잉곳 내 산소농도 범위를 연구하여 14.5 ppma 이하에서 Bulk Micro Defect(BMD)가 발생하지 않음을 확인하였다.

• 한국결정성장학회지
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• 제22권2호
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• pp.99-104
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• 2012

BCP(biphasic calcium phosphate) 분말을 제조하기 위하여 $Ca(NO_3)_2{\cdot}4H_2O$, $(NH_4)_2HPO_4$를 출발 물질로 공침법(co-precipitation process)을 이용하여 합성하였다. 합성된 분말의 열처리 전 후의 HAp(Hydroxyapatite)/${\beta}$-TCP(${\beta}$-Tricalcium phosphate) 결정상 비율 및 분광학적 특성을 XRD 및 FT-IR를 이용하여 분석하였다. BCP 분말의 생체활성 거동을 평가하기 위하여 Hanks' Balanced Salt Solution(HBSS)에 침적시켜 시간에 따라 형상, 이온농도의 변화 및 결정상을 분석한 결과 낮은 결정화도의 HAp가 생성됨을 확인하였다. BCP분말의 세포독성 평가에서도 대조군에 비하여 세포성장률이 우수함을 관찰하였다.

• 소성∙가공
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• 제24권4호
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• pp.287-292
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• 2015

The possibility of chemical precipitation for recycled ammonium paratungstate (APT) was studied. WO₃ particles were synthesized by chemical precipitation method using a 1:2 weight ratio of APT:DI-water. At the 500℃ sintering temperature, the X-ray diffraction results showed that APT completely decomposed to WO₃. For the granulated powder WC-Co, vacuum heat treatment at proper temperatures increases tap density and flow-ability. Hardness of the WC-Co thermal spray coating layer was measured in the range HV 831~1266. Spray conditions for the best characteristic values were an oxygen flow rate=1500 scfh, a fuel flow rate = 5.25gph and a gun distance = 320mm.

• 한국세라믹학회지
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• 제40권8호
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• pp.798-803
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• 2003

In synthesis of nano powders, the hard agglomeration for the synthesized powders occurred during the drying processing. In order to avoid hard agglomeration in particles the freeze drying process was used in this experiment. e fabricated the Yttira-Doped Ceria(YDC) nano powder by co-precipitation. Starting materials used in experiments were the cerium(III) nitrate and yttrium(III) nitrate solution with 야-water, which two solutions were mixed and then the precipitated hydroxides were prepared for adding sodium hydroxide. The co-precipitated powders were dried by the thermal drying at 8$0^{\circ}C$ for 24 h and by freeze drying at -4$0^{\circ}C$, 30 mtorr for 72 h. The lattice parameter and crystallite size as a function of calcination temperature was characterized by XRD analysis. The lattice parameter of YDC was decreased with addition amount of yttrium and was estimated as 5.401683 $\AA$ at $700^{\circ}C$. Crystallite size were calculated by XRD-LB method, and morphologies were confirmed with the observation of TEM and SEM. The freeze dried YDC powders had medium diameter of 17 nm with more uniform size distribution than the thermal dried YDC posers, which were mainly ascribed to the difference of agglomerates formation during drying stage.

• 한국세라믹학회지
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• 제25권2호
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• pp.117-124
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• 1988

The properties of the powders of the system Al2O3-ZrO2-Y2O3 prepared by precipitation method were investigated. Al2(SO4)3$.$18H2O3, ZrOCl2$.$8H2O and YCl3$.$6H2O were used as starting materials. Amorphous aluminum hydrate prepared by precipitation method was completely transformed to alpha Al2O3 as a result of calcining at 1100$^{\circ}C$ for 1 hr and gamma, delta and theta phases appeared as transition phases. In ZrO2-Y2O3 system prepared by co-precipitation method, the crystallization temperature of ZrO2 was increase with Y2O3 contents. The coupled crystallization occured in coprecipitated Al2O3-ZrO2-Y2O3 system, therefore the formation temperature of alpha Al2O3 and ZrO2-Y2O3 system. In this ternary system, the powder morphology showed a particular shape which was composed of large Al2O3 grains having small spherical ZrO2 particles within large Al2O3 grain and relatively large ZrO2 particles along the grian boundaries.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2005년도 춘계 학술대회
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• pp.248-254
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• 2005

본 연구에서는 음이온 교환수지와 Sr-Spec 수지를 사용하여 $^{90}Sr,\;^{241}Am$ 및 Pu 동위원소들에 대하여 축차적으로 분리하는 정량법을 제시하였다. Pu 동위원소는 음이온 교환수지를 이용하여 분리하였다. 아메리슘 및 스트론튬은 옥살산 공침법을 사용하여 토양 메트릭스 성분으로부터 분리하였다. 아메리슘은 철공침법을 사용하여 스트론튬으로부터 분리한후 음이온 교환수지를 사용하여 란탄나이드 성분으로부터 순수분리하였다. 스트론튬은 Sr-Spec 수지를 사용하여 순수분리하였다. Pu 및 Am 동위원소는 알파스펙트로메타로 정량하였고 Sr-90은 액체섬광계수기를 사용하여 베타선을 측정하였다. 본 연구에서 고찰된 $^{90}Sr,\;^{241}Am$ 및 Pu 동위원소 분석법을 IAEA 기준시료에 적용하여 분석법의 타당성을 검증하였다.

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.339-343
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• 2010

A series of $Ce_1Mg_xZr_{1-x}O_2$ (CMZO) mixed metal oxide with different molar ratio were prepared by simple co-precipitation method. The prepared materials were tested for their catalytic activity performance using Knoevenagel condensation of various aromatic aldehydes with barbituric acid under solvent-free condition in microwave. The best catalytic activity was obtained with CMZO (1:0.6:0.4). The synthesized materials were characterized by using XRD, FT-IR, SEM-EDS techniques.

• 한국세라믹학회지
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• 제26권1호
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• pp.109-115
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• 1989

The properties of the powders of ZrO2-MgO system prepared by co-precipitation method using ZrOCl2.8H2O and MgCl2.6H2O as starting materials were investigated after calcination from $600^{\circ}C$ to 120$0^{\circ}C$. The crystallization temperature of amorphous ZrO2 was increased as MgO contents increased. The crystallite size of ZrO2 was increased with increasing calcination temperature. The crystallite size of tetragonal ZrO2 calcined at 100$0^{\circ}C$ for 1hr wa about 45nm, and MgO contributed effectively to promoting stability of tetragonal Zirconia.

• 한국세라믹학회지
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• 제37권2호
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• pp.181-185
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• 2000

A new technique capable of accelerating the crystallization of ferrite powder at low temperature is developed. Effects of the ultrasonic waves on the crystallization were studied for ferrite powders prepared using the co-precipitation method. The crystallization of the ferrite powders exposed to the ultrasonic waves were characterized by the XRD. The amorphous ferrite powders prepared using the co-precipitation method were crystallized as a result of the exposure to the ultrasonic waves for 5h and the crystallization of the ferrite powders became more enhanced in proportion to the time exposed. The ferrite powder exposed to the ultrasonic waves for 25h had higher crystallinity a larger specific surface area than the ferrite powder calcined at 500$^{\circ}C$ for 2h.