• 제목/요약/키워드: Co-extraction

검색결과 1,228건 처리시간 0.023초

Solvent Extraction Separation of Co, Mn and Zn from leaching solution from Ni-Cd battery by Na-PC88A

  • Ahn Jong-Gwan;Park Kyoung-Ho;Sohn Jeong-Soo;Kim Dong-Jin;Lee Jaereyeong;Jeong HunSaeong
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.618-623
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    • 2003
  • Solvent extraction experiments for separation of impurities from Ni-rich solution were carried out for manufacturing of high purity Ni compounds from acid leaching solution of spent Ni-Cd secondary battery. Artificial and leaching solutions were used as aqueous phases and PC88A saponified by sodium in kerosene were used as organic phase. The extraction order is Zn>Mn>Co>Ni and extraction percentage of metal ions was increased with increase of the concentration of extractant, initial pH of aqueous phase and ratio of O/A. The separation of cobalt, zinc and manganese from nickel was effectively accomplished at the condition of extraction stage=l, O/A=1 and initial pH 5.0 with 1.0 $mol/dm^3$ PC88A saponified to $50\%$ with NaOH.

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Geochemical transport and water-sediment partitioning of heavy metals in acid mine drainage, Kwangyang Au-Ag mine area, Korea

  • Jung, Hun-Bok;Yun, Seong-Taek;Kwon, Jang-Soon;Lee, Pyeong-Koo
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.409-412
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    • 2003
  • Total extraction of stream sediments in the Kwangyang mine area shows their significant pollution with most trace metals such as Cr, Co, Fe, Pb, Cu, Ni, Zn and Cd, due to sulfide oxidation in waste dumps. Calculations of enrichment factor shows that Chonam-ri creek sediments are more severely contaminated than Sagok-ri sediments. Using the weak acid (0.1N HCl) extraction and sequential extraction techniques, the transport and sediment-water partitioning of heavy metals in mine drainage were examined for contaminated sediments in the Chonam-ri and Sagok-ri creeks of the Kwangyang Au-Ag mine area. Calculated distribution coefficient (Kd) generally decreases in the order of Pb $\geq$Al > Cu > Mn > Zn > Co > Ni $\geq$ Cd. Sequential extraction of Chonam-ri creek sediments shows that among non-residual fractions the Fe-Mn oxide fraction is most abundant for most of the metals. This indicates that precipitation of Fe hydroxides plays an important role in regulating heavy metal concentrations in water, as shown by field observations.

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웹 뉴스의 기사 추출과 요약 (Text Extraction and Summarization from Web News)

  • 한광록;선복근;유형선
    • 한국컴퓨터정보학회논문지
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    • 제12권5호
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    • pp.1-10
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    • 2007
  • 뉴스 콘텐츠 등 웹을 통해 제공되는 많은 정보들은 불필요한 클러터를 많이 포함하고 있다. 이러한 클러터들은 문서의 요약, 추출, 검색과 같은 자동화된 정보처리 시스템의 구축을 어렵게 한다. 본 논문에서는 웹 뉴스 콘텐츠를 추출하고 이를 요약하는 시스템을 구축하고자 한다. 추출 시스템은 HTML로 된 뉴스 콘텐츠를 입력받아 DOM 트리와 유사한 요소 트리를 구축하며, 이 요소 트리에서 HTML 태그의 하이퍼링크 속성을 갖는 클러터를 제외하면서 본문을 추출한다. 추출 시스템을 통해 추출된 본문은 요약시스템으로 전달되어 핵심 문장이 추출된다. 요약 시스템은 공기관계 그래프를 이용하여 구성한다. 본 논문에서 구현한 시스템을 통해 추출된 요약 문장은 SMS와 같은 메시지 서비스를 통하여 PDA이나 모바일 폰 등에 전송될 수 있을 것으로 기대된다.

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마그네슘함량이 높은 니켈 laterite광으로부터 습식공정에 의한 니켈과 코발트 회수 (Recovery of Nickel and Cobalt by a Hydrometallurgical Process from Nickel Laterite Ore with High Magnesium Content)

  • 이만승;김상배;최영윤;채종귀
    • 대한금속재료학회지
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    • 제48권1호
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    • pp.62-70
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    • 2010
  • Leaching and solvent extraction experiments have been performed to develop a hydrometallurgical process for the recovery of nickel and cobalt from nickel laterite ore with high magnesium content. Most of the nickel and magnesium in the laterite ore dissolved at leaching conditions of $80^{\circ}C$ and 100 g/L sulfuric acid concentration. while half of the cobalt and iron were leached at the same conditions. Solvent extraction experiments were carried out with D2EHPA and saponifed D2EHPA from a synthetic solution containing Ni, Co, and Mg. The extraction percentage of Co, Mg. and Ni by D2EHPA was very low in a pH range of 4.4 to 7.3. while the extraction percentage sharply increased by using saponified D2EHPA. The stripping percentage of the metals from the saponified D2EHPA increased with sulfuric acid concentration and reached 99.9% at 1 M $H_2SO_4$ solution.

Development of a gamma irradiation loop to evaluate the performance of a EURO-GANEX process

  • Sanchez-Garcia, I.;Galan, H.;Nunez, A.;Perlado, J.M.;Cobos, J.
    • Nuclear Engineering and Technology
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    • 제54권5호
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    • pp.1623-1634
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    • 2022
  • A new irradiation loop design has been developed, which provides the ability to carry out radiolytic resistance studies of extraction systems simulating process relevant conditions in an easy and simple way. The step-by-step loop configuration permits an easy modification of settings and has a relative low volume requirement. This irradiation loop has been initially set up to test the main EURO-GANEX process steps: the lanthanide (Ln) and actinide (An) co-extraction followed by the transuranic (TRU) stripping. The performance and changes in the composition have been analyzed during the irradiation experiment by different techniques: gamma spectroscopy and ICP-MS for the extraction and corrosion behavior of the full system, and HPLC-MS and Raman spectroscopy to determine the degradation of the organic and aqueous solvents, respectively. The Ln and An co-extraction step and the corrosion that occurred during the first irradiation step revealed the favorable expected results according to literature. The effects of acidity changes occurred during the irradiation process, the presence of stainless corrosion products in solution as well as the new possible degradation compounds have been explored in the An stripping step. The results obtained demonstrate the importance of developing realistic irradiation experiments where different factors affecting the performance can be easily studied and isolated.

목향과 향부자 추출물이 흰쥐의 만성 스트레스에 미치는 실험적 효과 (Experimental Effects of Aucklandiae Radix and Cyperi Rhizoma Extract on Chronic Stress in Rats)

  • 최찬헌;홍준영;정현우
    • 동의생리병리학회지
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    • 제36권2호
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    • pp.54-58
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    • 2022
  • This study aimed to investigate the anti-stress function of Aucklandiae Radix (AR) and Cyperi Rhizoma (CR). The essential oils used in the experiment were extracted from AR and CR using Steam Distillation Extraction and Super critical CO2 extraction. To observe the effects of sample administration, we measured feed intake, leukocytes, red blood cells, hemoglobin, platelets, serum serotonin content, immobility time, climbing time, and swimming time in mice subjected to chronic restraint stress as behavioral changes. The average body weight of all experimental groups increased than the average body weight of the control group. The immobility and climbing times of experimental groups A and B administered with supercritical extraction samples were shorter than those of the other experimental groups and the control group, and the swimming time was longer. The serotonin content in the blood of all experimental groups decreased compared to the normal group, and the serotonin content of the control group was increased. The authors suggest that Korean herbal medicines AR and CR may be utilized as anti-stress flavoring agents based on the above results.

홍화색소의 일반추출과 셀룰라아제추출의 비교연구 (Comparison Studies between Conventional Hot Water and Cellulase Extraction for Safflower Dyestuff)

  • 신인수;홍경옥;오태광
    • 대한가정학회지
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    • 제39권4호
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    • pp.49-59
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    • 2001
  • Natural red and yellow dyestuff was extracted from safflower (Carthamus tinctorius Linnaeus) by a new process of cellulase extraction compared with the conventional hot water extraction. Dyestuffs were extracted from safflower easily and repeatedly by means of cellulose as safflower cell wall destroyer. It means that new dyestuff extraction by cellulase improves not only yields of dyestuff from safflower successfully but also the rate of repetition of extraction. From the above experiments, the conclusions of this study were summarized as follows. 1. The optimum conditions of dyestuff extraction from safflower by general extraction method were that the solvent was the water of pH 6.0 on yellow dyestuff and 3% $K_2CO_3$ solution on red dyestuff, extraction temperature was $55^{\circ}C$, and extraction time was 30 min. 2. Among various cellulase, the NOVO cellulase was the best cell wall destroyer of safflower and finally produced the largest amount of dyestuff from safflower by cellulase extraction method. 3. The optimum conditions of dyestuff extraction by cellulase extraction method were conducted on 10 unit of cellulase per gram of safflower at $100m{\ell}$ water of pH 5.0 at $50^{\circ}C$ for 30 min.

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초임계유체 $CO_2$ 및 Co-solvent 첨가에 따른 금은화(Lonicera fles)의 Flavonoid류 추출특성 (Extraction Characteristics of Flavonoids from Lonicera flos by Supercritical Fluid Carbon Dioxide ($SF-CO_2$) with Co-solvent)

  • 서상철;조성길;홍주헌;최용희
    • 한국식품과학회지
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    • 제37권2호
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    • pp.183-188
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    • 2005
  • 순수 methanol을 cd-solvent로 첨가하였을 때 소량의 수율을 얻을 수 있었던 반면 methanol에 물을 첨가하여 수용액을 조제한 후 각각 첨가하였을 때 co-solvent의 극성도 증가에 비례하여 수율이 현저하게 증가하였다. 60% methanol을 첨가하였을 때 수율이 가장 높았으며 순수 methanol 첨가구와 비교하여 luteolin이 5.9배, quercetin이 4.1배, apigenin이 7.8배 가량 증가하였다. Co-solvent에 citric acid를 농도별로 첨가한 결과 첨가량 1%까지는 추출수율이 농도 비례적으로 증가하는 경향을 나타내어 대조구에 비해 대략 luteolin이 14.64mg/100g, quercetin이 10.17mg/100g, apigenin이 2.4mg/100g의 유의적인 증가율을 보였으나 그 이상의 농도에서는 소량 감소하는 경향을 보였다. 한편 산을 첨가한 모든 조건에서 대조구보다 높은 수율을 얻을 수 있었다. 추출수율이 가장 우수하였던 citric acid가 1% 첨가된 60% aqueous methanol을 co-solvent로 초임계상태에 첨가하였을 때 공정압력이 100bar에서 200ber로 증가함에 따라 추출수율이 비례적으로 증가하였으나 250bar 이상에서는 감소하는 경향을 나타내었다. 온도에 따라서는 $40^{\circ}C$에서 $50^{\circ}C$까지는 증가하는 경향을 보이다 이상의 온도에서는 오히려 감소하였다. 추출 시간의 증가와 더불어 추출 수율은 유의적으로 증가하다가 60분일 때 최대값을 보였으며 90분 이상의 추출시간에서는 추출수율이 거의 일정해졌다. $CO_{2}$ 대비 cosolvent를 15(0.3mL/min)% 첨가하였을 때 최대 추출수율을 보였으며 25% 이상의 첨가구에서는 첨가량은 증가하였으나 수율은 감소하는 경향을 보였다. 것으로 나타났다. 그러므로 감마선 조사 및 저온저장($10^{\circ}C$)은 김밥재료 뿐만 아니라 김밥의 미생물 제어에 효과적인 것으로 확인되었다.와 비례하는 경향을 나타내었다. 또한 FA-swelling mica의 중금속 이온의 선택성은 Pb>Cu>Cd$\geq$Zn 순으로 나타났다.지 않았다.l years and a new type of transfer crane has been developed. Design concepts and control methods of a new crane will be introduced in this paper.and momentum balance was applied to the fluid field of bundle. while the movement of′ individual material was taken into account. The constitutive model relating the surface force and the deformation of bundle was introduced by considering a representative prodedure that stands for the bundle movement. Then a fundamental equations system could be simplified considering a steady state of the process. On the basis of the simplified model, the simulation was performed and the results could be confirmed by the experiments under various conditions.뢰, 결속 등 다차원의 개념에 대한 심도 깊은 연구와 최근 제기되고 있는 이론의 확대도 필요하다. 마지막으로 신뢰와 결속에 영향을

길경(桔梗)의 추출조건에 따른 사포닌 함량의 변화 (Variation of Saponin Content in the Decoctions of Platycodi Radix)

  • 최재석;유대석;최연희;연규환;홍경식;이병회;김혜진;김현기;김은주;노성환;정영철;김영섭;유시용
    • 생약학회지
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    • 제38권2호통권149호
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    • pp.128-132
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    • 2007
  • We investigated the contents of crude saponin in the decoctions of Platycodi Radix prepared by the different extraction processes. Each lyophilized decoctions prepared by the different protocol were suspended in water and partitioned with ethylacetate (EtOAc) and n-butanol (BuOH), which gave the EtOAc fraction, BuOH fraction and the remaining water fraction, respectively. The content of crude saponin, which was estimated as the amount of BuOH fraction, and the HPLC profiles of the BuOH fraction were analyzed, and compared each others. The crude saponin content in the decoctions were increased proportionally to the increment of the extraction time, amount of water, extraction temperature and the number of repetition for extraction. Consequently, the optimized conditions were deduced to be suitable and recommendable for the preparation of Platycodi Radix ; the water amount needed for the extraction be 15-20 volumes to crude material, temperature for extraction be optimal at $85{\sim}100^{\circ}C$, extraction time be more than 5 hours and the repetition of extraction was 2 times.

The Extraction of Co-PET from Non-Woven Fabrics of Nylon/Co-PET Sea-island Type Composite Microfiber

  • Park, Myung-Soo;Yoon, Jong-Ho;Cho, Dae-Hyun
    • 한국의류산업학회지
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    • 제3권5호
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    • pp.466-472
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    • 2001
  • To find a suitable condition in this process examined, we investigated the main control factors, such as, the NaOH concentrations, such as, the NaOH concentrations, the heat treating times, and the heating temperatures. The resulting mechanical properties of the fabrics also studied. The samples used were Nylon/Co-PET sea-island type composite microfiber (Co-PET content: 35%) non-woven fabric. The conclusions obtained were as follows. 1. For the complete extraction of Co-PET from the sample non-woven fabric in the dry hot air process, $160^{\circ}C$ of air temperature, 15 min. of treatment time, and around 30% of NaOH concentration were required. On the other hand, in the wet hot air process, $140^{\circ}C$ of air temperature, 3.5 min. of treatment time, and around 30% of NaOH concentration were required. 2. The mechanical properties of the continuous processed samples showed that the WT, B, and WC increased with increasing the weight reduction ratio. However, the G, decreased with increasing the weight loss ratio. Note that, particularly in B, it increased drastically when the weight deduction ratios exceeded 30%. 3. As increasing the wet hot air temperature from 130 to $140^{\circ}C$, B appeared to increase, however, WT, G, and WC appeared to decrease. 4. The best condition found in this continuous process to extract Co-PET is the wet hot air temperature of 140, NaOH concentration of 28% or above, and the treatment time 2-4 min.

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