• Title/Summary/Keyword: Citric Acid

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Improving Soil Washing/flushing Process using a Mixture of Organic/inorganic Extractant for Remediation of Cadmium (Cd) and Copper (Cu) Contaminated Soil (유/무기산 혼합용출제를 이용한 중금속(카드뮴,구리)오염토양 처리공법(soil washing/flushing) 개선에 대한 연구)

  • Lee, Hong-Kyun;Kim, Dong-Hyun;Jo, Young-Hoon;Do, Si-Hyun;Lee, Jong-Yeol;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.14 no.2
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    • pp.17-25
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    • 2009
  • The applicability of soil washing/flushing to treat a contaminated soil with cadmium (Cd) and copper (Cu) using a mixture of organic/inorganic extractant was evaluated in laboratory-scale batch and column tests. Citric acid was the effective extractant to remove Cd and Cu from the soil among various organic acids except EDTA. Carbonic acid was chosen as inorganic extractant which was not only low toxicity to environment, but also increasing soil permeability. Moreover, the optimum ratio of organic and inorganic extractant to remove Cd and Cu was 10 : 1, and this ratio of organic and inorganic extractant achieved removal efficiencies of Cd (46%) and Cu (39%), respectively. The increasing flow rate of extractant could explain the phenomena of soil packing when carbonic acid was used with organic extractant (i.e. EDTA and citric acid). Therefore, a mixture of organic extractant with inorganic extractant, especially carbonic acid, could resolve a problem of soil packing when this extractant was applied to a field application to remove Cd and Cu using in-situ soil flushing process.

Extraction and Bleaching of Acid- and Pepsin-Soluble Collagens from Shark Skin and Muscle (상어 껍질과 육으로부터 산 및 Pepsin 가용성 콜라겐의 추출과 탈색조건)

  • Kim, Jae-Won;Kim, Do-Kyun;Kim, Mee-Jung;Kim, Soon-Dong
    • Food Science and Preservation
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    • v.17 no.1
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    • pp.91-99
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    • 2010
  • Extraction and bleaching of citric acid- and pepsin-soluble collagens (ASC and PSC, respectively) from shark (Isurus oxyrinchus) skin and muscle were investigated. The optimal sodium hydroxide concentration for extraction was 0.3 M and the optimal treatment time for removal of foreign material was 9 h. The optimal sodium hypochlorite level for bleaching of shark skin was 0.48% (w/v), and sodium hypochlorite was a better bleaching agent than acetone, hydrogen peroxide (10%, v/v), sodium sulfite (0.48%, w/v), sodium thiosulfate (0.48%, w/v), or sodium metabisulfite (0.48%, w/v). Optimal citric acid concentration and extraction time for ASC were 0.3 M and 72 h, respectively, whereas optimal conditions for extraction of PSC were treatment with 0.1 M citric acid containing 0.1% (w/v) pepsin for 24 h. Protein contents in ASSC (acid-soluble shark skin collagen), ASMC (acid-soluble shark meat collagen), PSSC (pepsin-soluble shark skin collagen), and PSMC (pepsin-soluble shark meat collagen) were 88.66%, 83.09%, 90.33%, and 84.81% (on a dry weight basis), respectively, similar to that of commercial marine collagen (88.86%). Net collagen contents of ASSC, ASMC, PSSC, and PSMC, calculated from hydroxyproline levels, were 70.31%, 25.70%, 83.09%, and 32.94%, respectively. The yields of freeze-dried ASSC, ASMC, PSSC,and PSMC were 57.22%, 53.85%, 23.28%, and 20.61%.

A Study for the stability of chopped garlic quality (다진 마늘의 품질안정을 위한 연구)

  • 나영아
    • Culinary science and hospitality research
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    • v.5 no.2
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    • pp.115-130
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    • 1999
  • Preservative effects of natural preservatives, citric acid and salt on chopped garlic were investigated. Citric acid was very effective for the repression of bacteria multiplying and browning of chopped garlic in 0.5%~1% concentration. Salt had an effect on the repression of bacteria multiplying and browning color of chopped garlic except for 1% NaCl. Synergy effect between citric acid and NaCl was also very good for the decreasing of bacteria multiplying and the maintaining of Hunter color of chopped garlic. Compounded effect among the GF, CA and ascorbic acid was somewhat proper in the sensory evaluation of chopped garlic. And the sensory evaluation score was best in chopping size 3mm(diameter) of chopped garlic and viscosity 4500cp. of chopped garlic.

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Effect of Electrolyzed Water and Organic Acids on the Growth Inhibition of Listeria monocytogenes on Lettuce (전해수 및 유기산처리에 의한 양상치에 오염된 Listeria monocytogenes의 생육저해)

  • Park Boo-Kil;Oh Min-Hee;Oh Deog-Hwan
    • Food Science and Preservation
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    • v.11 no.4
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    • pp.530-537
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    • 2004
  • This study was conducted to determine the inactivation effect of electrolyzed water and organic acids either alone or in combination on L. monocytogenes or natural microflora on lettuce. Acidic electrolyzed water completely inactivated L. monocytogenes in broth system within 60 sec, but alkalin electrolyzed water caused approximate 1.7 log CFU/g reduction. However, acidic electrolyzed water reduced only 2.5 log CFU/g of L. monocytogenes on lettuce, and similar antimicrobial effect was observed with alkalin electrolyzed water. In the meantime, acidic and alkaline electrolyzed water caused approximately 2 log CFU/g reduction compared to control, whereas both electrolyzed water combined with $1\%$ organic acids ranged from 2.6 to 3.7 log CFU/g reduction. Among the organic acids, both electrolyzed water combined with $1\%$ citric acid showed the strongest synergistic antimicrobial effect to reduce L. monocytogenes on lettuce as well as total counts, yeast and molds. When antimicrobials, alone or in combination were treated into L. monocytogenes inoculated lettuce at $5^{\circ}C\;and\;15^{\circ}C$ for designed periods, the combined alkalin electrolyzed water with $1\%$ citric acid showed the greatest potential to inhibit growth of the bacteria. According to Scanning Electron Microscopy(SEM), the treatment of electrolyzed alkali water in combination with $1\%$ citric acid highly reduced the growth of the L. monocytogenes compared to single treatment and resulted in causing the destruction of cell membrane.

Effect of Mild Heat and Organic Acid Treatments on the Quality of Fresh-Cut Lotus Roots (열처리 및 유기산처리가 신선편이 연근의 품질에 미치는 영향)

  • Park, Ju-Hyun;Hong, Seok-In;Jeong, Moon-Cheol;Kim, Dongman
    • Food Science and Preservation
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    • v.20 no.1
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    • pp.23-29
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    • 2013
  • To extend the shelf-life of freshly cut lotus roots, the effect of their heat treatment in water at $50^{\circ}C$ was investigated and compared with that of their treatment using 1 percent ascorbic acid and citric acid during their storage. In addition, consecutive heat and acid treatment was applied to freshly cut lotus roots to determine its synergy effect. The level of molds in the sample that was treated with $50^{\circ}C$ water for 60 minutes was the lowest among the treatments and 3.89 log CFU/g after 12-day storage, whereas the population of the control was 6.81 log CFU/g for the same number of days. During the storage, the surface color of the samples showed higher ${\Delta}E$ values and lower L values than that of the initial sample. The color with the heat treatment hardly changed, unlike in the control. The consecutive treatments with hot water and acid showed less quality loss than the simple heat treatment. The marketable quality was maintained for three days without any treatment, for nine days with the heat treatment, and for 12 days with the consecutive treatments of hot water and acid. The consecutive treatments with hot water and acid, especially with 1 percent citric acid, extended the shelf-life of the freshly cut lotus roots by inhibiting the growth of microorganisms and the browning.

The Change of Ginsenosides Composition from Decocted Ginseng with Citric Acid and Schisandrae Fructus (인삼 탕액 제조시 구연산과 오미자에 의한 진세노사이드 조성 변화)

  • Lee, Sang Myung
    • Korean Journal of Pharmacognosy
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    • v.45 no.2
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    • pp.121-126
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    • 2014
  • In order to observe the change of ginsenosides, two simplified decoctive conditions are set up aqueous citric acids (0, 12.5, 25, 50, 75, and 100 mM) with ginseng powder (3 g) and Schisandrae Fructus (0, 1, 2, 3 g) with ginseng powder (3 g). Decoctive temperature and duration are $95^{\circ}C$ and 1.5 h. The contents of major ginsenosides are decreased by increasing concentration of citric acid. But the contents of converted ginsenosides have not been a noticeable increase. In the decoctive condition with Schisandrae Fructus, the contents of major protopanaxdiol ginsenosides seriously decreases that compared with major protopanaxtriol ginsenosides. Therefore, Schisandrae Fructus provides the condition that predominantly converts protopanaxdiol ginsenosides in ginseng decoction.

Enzymatic Reactions in Citric Acid Fermentation of Mandarin Orange Peel by Aspfrgillus niger (만다린 오렌지 과피를 기질로 한 Aspergillus niger의 구연산 발효에 관련된 효소적 반응)

  • 강신권;노종수;성낙계
    • Microbiology and Biotechnology Letters
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    • v.21 no.1
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    • pp.13-17
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    • 1993
  • When mandarin orange peel was used for a substrate of citric aCid fermentation by Aspergillus niger, principal enzyme activities were investigated. Not only the activity of polygalacturonase and pectin esterase being capable of digesting pectin and crude fiber of mandarin orange peel. but also that of carboxymethyl cellulase, xylanase and amylase was high. In carbohydrate metabolism, the activity of enzymes related in HMP pathway was higher than that in EMP pathway at the orange peel medium designed hereby rather than synthetic medium. Productivity of citric acid was significantly increased when the activity of citrate synthetase was high and 5imultaneously those of aconitase and NADP-dependent dehydrogenase were low.

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Effects of Ethanol and Organic Acids on Color, Fishy Odor and in vitro Absorption Rate of Calcium of Dried Large Anchovy (자건대멸의 색택, 어취 및 in vitro 칼슘 흡수율에 미치는 주정과 유기산 처리의 효과)

  • Jo, Jin-Ho;Jang, Hae-Jin;Cho, Seung-Mock;Lee, Yang-Bong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.9
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    • pp.1471-1476
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    • 2005
  • The optimization of ethanol treatment was carried out by response surface methodology (RSM) which was expressed through change of ${\Delta}$E value for improvement of color of dried large anchovy. The optimum condition was shown as treatment with 7 volumes (v/m) of ethanol at $50^{\circ}C$ for 9 hrs. At this condition, the removal rates of trimethylamine (TMA) and fat considered as fishy odor-causing materials were 81.1 and $77.4\%$, respectively, when analyzed by solid phase microextraction (SPME)/gas chromatography and soxhlet method, respectively The effect of citric acid on the removal rate of TMA was the highest one among organic acid treatments. The removal rate of TMA was affected greatly by the concentration of organic acid rather than the temperature and time of treatment. $73\%$ of TMA was removed by treatment of $1\%$ of citric acid at $20^{\circ}C$ for 20 min. Specially, above $90\%$ of TMA could be removed by the combination of alcohol and citric acid treatment. In vitro absorption rate of calcium was also increased to $12.3\%$ by the combination of alcohol and citric acid treatment compared with $2.9\%$ of control.

The short-term storage characteristics of cut kimchi cabbages treated with Ca2+ (Ca2+처리 절단배추의 소포장 단기 저장 특성)

  • Kim, Sang-Seop;Seong, Gi-Un;Hwang, Hee-Young;Jeong, Moon-Cheol;Chung, Shin-Kyo
    • Food Science and Preservation
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    • v.21 no.2
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    • pp.157-162
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    • 2014
  • To enhance the commercialization of fresh cut kimchi cabbage, the short-term storage effect of cut kimchi cabbage treated with $Ca^{2+}$ was studied. Cut kimchi cabbages ($3{\times}3$ cm) were treated with 2% calcium chloride (Ca), ascorbic acid (As), citric acid (Ct), and calcium chloride and citric acid (Ca/Ct), were put inside LDPE bags, and stored at $5^{\circ}C$ for 6 weeks. The weights reduced about 0.13~0.72%, and the ratio was the lowest in the Ca/Ct treatment. The reduction ratios of soluble soilds were 18.85~35.00%, and were the lowest in the Ca/Ct treatment. The titratable acidity decreased in all the treatments. The L values decreased, but a and b values of Hunter colorimeter increased in all the treatments. The preference for Ca/Ct treatment was the highest among all the treatments in the sensory evaluation. The marketing shelf-life of cut kimchi cabbage can be prolonged by the combination treatment of $Ca^{2+}$ and citric acid.

A Study of Recycling Lithium-ion Battery Graphite by Eco-friendly Citric Acid Treatment Method (친환경 구연산처리를 통한 폐흑연 재활용 연구)

  • Dong-kyu Son;Won Jin Park;Jun Young Kim;Ji Hui Yun;Jung Eun Hyun
    • Korean Chemical Engineering Research
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    • v.62 no.3
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    • pp.246-252
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    • 2024
  • In this study, impurities such as Li and F were removed from waste graphite through citric acid treatment, and changes in structural properties, capacity, and cycle stability of regenerated graphite were observed accordingly. Regenerated graphite pretreated in a nitrogen atmosphere was treated with citric acid, and its structure and characteristics were analyzed through SEM (Scanning Electron Microscope), FT-IR (Fourier Transform Infrared spectroscopy), XRD (X-ray Diffraction), and XPS (X-ray Photoelectron Spectroscopy). Waste graphite that was not treated with acid had a rapid decrease in capacity before 70 cycles, but graphite that had been treated with citric acid showed a capacity of 302.9 mAh g-1 and a capacity retention rate of 93.1% at 100 cycles. In addition, despite changes in current density in rate performance, samples treated with citric acid showed 340.2 mAh g-1 performance at 1.0C without change in capacity. As a result, it was confirmed that citric acid treatment not only effectively removed impurities and showed a high capacity retention rate, but also showed stability even at high current densities.