• Title/Summary/Keyword: Chemical response

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Chemical Accidents Response Information System(CARIS) for the Response of Atmospheric Dispersion Accidents in association with Hazardous Chemicals (유해화학물질 관련 대기오염사고 대응을 위한 화학물질사고대응정보시스템 (CARIS))

  • Kim, Cheol-Hee;Park, C.J.;Park, J.H.;Im, C.S.;Kim, M.S.;Park, C.H.;Chun, K.S.;Na, J.G.
    • Journal of Environmental Impact Assessment
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    • v.12 no.1
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    • pp.23-34
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    • 2003
  • The emergency response modeling system CARIS has been developed at CCSM (Center for Chemical Safety Management), NIER (National Institute of Environmental Research) to track and predict dispersion of hazardous chemicals for the environmental decision support in case of accidents at chemical or petroleum companies in Korea. The main objective of CARIS is to support making decision by rapidly providing the key information on the efficient emergency response of hazardous chemical accidents for effective approaches to risk management. In particular, the integrated modeling system in CARIS consisting of a real-time numerical weather forecasting model and air pollution dispersion model is supplemented for the diffusion forecasts of hazardous chemicals, covering a wide range of scales and applications for atmospheric information. In this paper, we introduced the overview of components of CARIS and described the operational modeling system and its configurations of coupling/integration in CARIS. Some examples of the operational modeling system is presented and discussed for the real-time risk assessments of hazardous chemicals.

Study on Improvement Measures for Prevention and Countermeasure of Chemical Accident (화학사고 예방 및 대책에 대한 개선방안에 관한 연구)

  • Lee, Deok-Jae;Lee, Tae-Hyung;Shin, Chang-Hyun
    • Fire Science and Engineering
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    • v.30 no.5
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    • pp.137-143
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    • 2016
  • The use of chemicals is increasing due to industrial advancement and diversification. In addition, the number of chemical accidents are increasing at the same time. A multifaceted effort in chemical accidents is needed for efficient prevention and countermeasures. This paper presents, under the current Act, a chemical accident case, including the material safety data sheet (MSDS) through the chemical accident prevention and measures for improvement with regard to research.

Statistical Analysis of Chemical Substance Transporting Accidents (화학물질 운송 화학사고의 통계 특성 분석에 관한 연구)

  • Lee, Tae-Hyung;Lee, Sang-Jae;Shin, Chang-Hyun
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.23-30
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    • 2016
  • This study analyzed the characteristics of chemical accidents, including the accidents occurring each year according to status, type of accident, accident cause for chemical substance transporting accidents. The major aim of this study was to provide information on the chemical accidents that occurred involving chemical substance transporting accidents from 2013 to July - 2016. The total incidence of chemical transporting accidents was 77 cases; 74 cases occurred by the spill & leakage type. The main cause of the accidents analyzed was traffic accidents (41 cases). Forty-six accidents were related to hazardous chemical substances. Among the 46 hazardous chemical substances involved in transporting chemical accidents, 46% of the accident substances were hydrogen chloride. For the prevention and response to accidents occurring during the transportation of chemicals, it is necessary to complement the precautions for chemical accidents caused by transportation accidents and chemical spills and leaks of chemicals. In addition, when the chemical transport of an accident occurs, it is necessary to apply a chemical transport safety system for chemical transfer.

Response Surface-Optimized Isolation of Essential Fatty Acids via Castor Oil Dehydration

  • Suratno, Lourentius;Imanuel, Anugerahwan;Brama, Andika;Adriana Anteng, Anggorowati;Ery Susiany, Retnoningtyas;Kiky Corneliasari, Sembiring;Wiyanti Fransisca, Simanullang
    • Journal of the Korean Chemical Society
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    • v.67 no.1
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    • pp.28-32
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    • 2023
  • The reaction conditions optimization, including the temperature of the reaction, amount of catalyst required, and reaction time for the linoleic acids (LAs) and conjugated linoleic acids (CLAs) production by catalytic dehydration of castor oil via saponification was investigated by response surface methodology (RSM). It was confirmed that all three parameters (temperature, time, and amount of catalyst) were influential factors in isolating LAs and CLAs. When the temperature was increased, the iodine value increased, and the reaction time and catalyst amount increased. The optimal reaction conditions were: 240 ℃, 2.2 h reaction time, and 7 wt% catalyst amount. The maximum iodine value reached 156.25 with 91.69% conversion to the essential fatty acids.

A Comparative Analysis on the Education Contents of Domestic and Foreign Training Institutions in Response to Marine Chemical Incidents (국내외 기관별 해상화학사고 대응 교육내용에 관한 비교분석)

  • Kim, Kwang-Soo;Lee, Moonjin;Park, Jinhyung
    • Proceedings of KOSOMES biannual meeting
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    • 2017.11a
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    • pp.165-165
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    • 2017
  • As marine chemical spill incidents increase, and damages caused by chemical spills become bigger and bigger, it is required to educate and train professional personnel for response to chemical spill incidents at sea. In this study, the education contents of domestic and foreign institutions for the training of specialists in response to marine chemical accidents were examined, and a comparative analysis of education and training contents was carried out in order to utilize it in the development of domestic education and training materials for HNS response personnel in Republic of Korea.

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A Study on Improvement of Damage Impact Range Assessment for Field-Based Response Against Chemical Terrorism and Accidents (현장 중심의 화학테러·사고 대응을 위한 피해 영향 범위 평가 개선 방안 연구)

  • Lee, Deok-Jae;Song, Chang Geun
    • Journal of Convergence for Information Technology
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    • v.10 no.8
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    • pp.127-136
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    • 2020
  • Chemical terrorism and accidents using chemicals are continuously occurring and attempted in and out of the country. In Korea, the National Institute of Chemical Safety affiliated with Ministry of Environment employs the CARIS(Ver. 2018) to assess the damage impact range for field-based response against chemical terrorism and accidents. However, the current version of CARIS can not consider the effects of closed space such as indoor and underground, so it is difficult to provide accurate evaluation results for damage impact range required for field response, on top of the limited information available. The limitations and directions for improvement were studied by comparing and reviewing the evaluation results of the damage impact range obtained by driving CARIS (Ver. 2018) and the domestic and foreign literature. Proposed improvements also included the direction of information provided to residents, including the need to build modeling for special points, such as underground, indoor, etc., and on-site response personnel. It is expected that through the continuous supplementation and correction of CARIS, chemical terrorism and accident response capability system will be advanced further.

The Research on the Real-time Emergency Response Plan for the Company based on Consequence Analysis for Chemical Accidents (화학사고 발생 시 피해예측 모델과 연계된 사업장의 실시간 비상대응 체계에 관한 연구)

  • Jun Ho Ha;Chang Jun Lee
    • Journal of the Korean Society of Safety
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    • v.39 no.2
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    • pp.28-37
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    • 2024
  • The recent surge in the production and handling of hazardous materials in Korea necessitates developing and implementing robust emergency response plans. These plans are crucial in safeguarding the well-being of workers and residents in the event of an incident. The consequence analysis methodology outlined in the KOSHA guidelines provides a foundation for designing emergency response plans in the event of chemical accidents. However, the consequence analysis is evaluated based on assumed accident cases or worst-case scenarios. Consequently, the emergency response plan based on the consequence analysis may overestimate the damage area, complicating rescue efforts and unnecessarily increasing costs. More information and parameters become available after an accident, enabling more accurate consequence analysis. This implies that the results of consequence analysis based on this detailed information provide more realistic results than those based on assumed accidents. This study attempts to optimize the resource allocation and cost-effectiveness of emergency response plans for chemical accidents. Existing procedures and manuals are revised to elucidate the proposed model and conduct real-time consequence analysis. The existing emergency response plan is compared to verify the proposed model's efficacy. The obtained results indicate that the proposed model can exhibit better performance.

Optimization of Anthraquinone Dyes Decolorization Conditions with Response Surface Methodology by Aspergillus

  • Ge, Yufeng;Wei, Bin;Wang, Siyu;Guo, Zhiguo;Xu, Xiaolin
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.327-332
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    • 2015
  • A large amount of dye wastewater poses a threat to environmental safety. Disperse blue, an anthraquinone dye that is widely used in textile dyes, is difficult to degrade in wastewater. In this work, one fungus was screened according to the decolorization rate of disperse blue. The fungus was identified and named Aspergillus XJ-2 on the basis of its morphological characteristics and 18s rDNA. Response surface method was used to optimize culture conditions for A. XJ-2. The optimum values of obtained responses were as follows: temperature, $35^{\circ}C$; pH, 5.2; carbon-to-nitrogen ratio, 30:5.5; and rotation ratio, $175r{\cdot}min^{-1}$. Under optimized conditions, the decolorization rate of A. XJ-2 was up to 94.8% in 48 h.

Nonlinear Response of Classical Dynamical Systems to Short Pulses

  • Dellago, Christoph;Mukamel, Shaul
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1107-1110
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    • 2003
  • Valuable insight into the nonlinear dynamics of a system can be gleaned from its response to a single intense short pulse. We derive expressions for the corresponding nonlinear response functions and show that the fluctuation-dissipation theorem may be extended beyond the linear response limit to an arbitrary pulse intensity. As an illustrative example, we calculate response functions up to 11th order for the regular Lorentz gas in two dimensions.

Study of the Improvement of Hazardous Chemical Management for Chemical Accident Prevention (화학사고 예방을 위한 유해화학물질 관리 개선 연구)

  • Lee, Deok-Jae;Lee, Tae-Hyung;Shin, Chang-Hyun
    • Fire Science and Engineering
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    • v.31 no.1
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    • pp.74-80
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    • 2017
  • Chemicals are convenient for humans but the damage caused by hazardous chemicals can be widespread if they are not managed properly. The Chemical Substance Management Act strengthened the management of hazardous chemicals and the management of handling facilities. On the other hand, an analysis of chemical accidents occurring in the past 4 years showed that chemical accidents occurring at the handling facilities are increasing, and additional preventive measures are needed. In this study, to prevent chemical accidents of hazardous chemicals, the causes and problems of accidents were analyzed through the case study of chemical accidents and measures for improvement are proposed.