• 제목/요약/키워드: Chemical Reactor

검색결과 1,551건 처리시간 0.032초

튜브형 가열로 반응기를 이용한 초미립 $SiO_2$ 입자의 제조 및 증착에 대한 수치모사 (The Numerical Simulation of Ultrafine $SiO_2$ Particle Fabrication and Deposition by Using the Tube Furnace Reactor)

  • 김교선;현봉수
    • 한국세라믹학회지
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    • 제32권11호
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    • pp.1246-1254
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    • 1995
  • A numerical model for fabrication and deposition of ultrafine SiO2 particles were proposed in the simplified horizontal MCVD apparatus using tube furnace reactor. The model equations such as energy and mass balance equations and the 0th, 1st and 2nd moment balance equations of aerosols were considered in the reactor. The phenomena of SiCl4 chemical reaction, SiO2 particle formation and coagulation, diffusion and thermophoresis of SiO2 particles were included in the aerosol dynamic equation. The profiles of gas temperature, SiCl4 concentration and SiO2 particle volume were calculated for standard conditions. The concentrations, sizes and deposition efficiencies of SiO2 particles were calculated, changing the process conditions such as tube furnace setting temperature, total gas flow rate and inlet SiCl4 concentration.

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Camelina oil transesterification using mixed catalyst of tetra methyl amonium hydroxide and potassium hydroxide on the tubular reactor

  • Hyun, Young-Jin
    • 한국응용과학기술학회지
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    • 제28권2호
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    • pp.178-184
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    • 2011
  • The analysis of reaction kinetics provided that the reaction order was the $1^{st}$ of triglyceride and the rate constant was 0.067 $min^{-1}$. The transesterification of camelina oil using 0.6 wt% mixed catalyst which consists of 40 v/v% of potassium hydroxide (1 wt%) and 60 v/v% of tetra methyl ammonium hydroxide (0.8 wt%), was carried out at $65^{\circ}C$ on the tubular reactor packed with static mixer. The conversion was shown to be 95.5% at the 6:1 molar ratio of methanol to oil, flow rate of feed of 3.0 mL/min and 24 of element of static mixer. The volume of washing water emitted by 0.6 wt% mixed catalyst was the half of the volume emitted by 1 wt% potassium hydroxide.

원자로급 흑연의 산화거동 및 산화에 따른 물성변화 (Oxidation Behavior and Property Changes of Nuclear Graphite)

  • 조광연;김경자;임연수;정윤중;지세환
    • 한국세라믹학회지
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    • 제43권12호
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    • pp.833-838
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    • 2006
  • Graphite is suitable for high temperature structural materials because of chemical stability as well as unique crystal structure. Especially, graphite can be used as a part of a nuclear reactor due to high tolerance at the extreme conditions of high temperature and neutron irradiations. Although study of oxidation properties or behaviors of graphite are very important and essential for the life and stability of the nuclear reactor, most of studies treat this theme lightly. This work focuses on the oxidation characteristics of several grade isotropic graphite of the nuclear reactor.

Lad-Scale Sequencing Batch Reactor for the optimum treatment of Ship sewage

  • Park, Sang-Ho;Kim, In-Soo
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2006년도 International Symposium on GPS/GNSS Vol.1
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    • pp.315-320
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    • 2006
  • There have been several problems in treating shipboard sewage due to special environmental conditions of ship, such as limited space, rolling and pitching, change of temperature and so on. It was suggested that Sequence Batch Reactor (SBR) might be suitable process for overcome these problems in terms of small size, high capacity of treating wastewater and full automation. In this study a SBR process was employed for biological treatment of organic wastes in the shipboard sewage. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. A disturbance operation caused by the treatment of Methylene Blue Active Substances(MBAS) was not observed.

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세라믹 멤브레인의 나노구조 제어 및 응용 (Control of Nano-Structure of Ceramic Membrane and Its Application)

  • 이혜련;서봉국;최용진
    • 멤브레인
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    • 제22권2호
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    • pp.77-94
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    • 2012
  • 내열성, 용매 저항성의 특징을 갖는 다공성 세라믹 소재를 이용한 무기 멤브레인이 기체분리(수소 분리, 이산화탄소 분리 등), 액체 분리(수처리, 폐수처리, 유기용매 분리 등) 등 여러 가지 분야로 그 응용이 확대되고 있다. 본 논문에서는 다공성 세라믹 멤브레인의 소재, 제조 방법에 따른 멤브레인의 구조 제어 및 성능 평가에 관한 연구를 소개하고, 멤브레인의 세공 크기에 따른 구조, 멤브레인의 특성을 이용한 여러 가지 기체 분리 및 액체 분리에 관한 연구 동향을 정리하였다.

Application of Biofilter Using Fibril-form Matrix for Odor Gas Removal

  • Lee, Gwang-Yeon;Jeong, Gwi-Taek;Lee, Kyoung-Min;Snuwoo, Chang-Shin;Lee, Woo-Tae;Cha, Jin-Myoung;Jang, Young-Seon;Park, Don-Hee
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2005년도 생물공학의 동향(XVI)
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    • pp.247-251
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    • 2005
  • This research was performed for developing of biological treatment process of odor gas such as MEK, $H_{2}S$, and toluene, which is generated from the food waste recycling process. To establish the operational conditions of odor gas removal by small-scale biofiltration equipment, it was continuously operated by using toluene as a treating odor object. When the odor treating microorganisms were adhered to fibril form biofilter, high removal efficiency over 93% was obtained by biofilm formation. At 400 ppm of inlet odor gas concentration and 10 sec of retention time, the removal efficiency was 76% and 93% in 1st stage reactor and 2nd stage reactor, respectively. However, the removal efficiency remained over 97% at the operational conditions above 15 sec of retention time.

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케미컬루핑 연소를 위한 산소전달입자의 최소유동화속도 및 고속유동층 전이유속에 미치는 압력의 영향 (Effect of Pressure on Minimum Fluidization Velocity and Transition Velocity to Fast Fluidization of Oxygen Carrier for Chemical Looping Combustor)

  • 김정환;배달희;백점인;박영성;류호정
    • 한국수소및신에너지학회논문집
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    • 제28권1호
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    • pp.85-91
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    • 2017
  • To develop a pressurized chemical looping combustor, effect of pressure on minimum fluidization velocity and transition velocity to fast fluidization was investigated in a two-interconnected pressurized fluidized bed system using oxygen carrier particle. The minimum fluidization velocity was measured by bed pressure drop measurement with variation of gas velocity. The measured minimum fluidization velocity decreased as the pressure increased. The transition velocity to fast fluidization was measured by emptying time method and decreased as the pressure increased. Gas velocity in the fuel reactor should be greater than the minimum fluidization velocity and gas velocity in the air reactor should be greater than the transition velocity to fast fluidization to ensure proper operation of two interconnected fluidized bed system.

유동층 반응기에서 Candida tropicalis 균에 의한 페놀함유 폐수처리에 관한 연구 (The Phenol Wastewater Treatment by Candida tropicalis in Fluidized Bed Biofilm Reactor)

  • 김우식;염경호;김응식
    • 한국미생물·생명공학회지
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    • 제13권1호
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    • pp.33-39
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    • 1985
  • The effects of initial concentration, flow rate, and recycle ratio on the removal efficiency of phenol were studied in a tapered fluidized bed reactor packed with activated carbon which was attached with Candida tropicalis. The optimum conditions of Candida tropicalis were showed that pH was 7.0 and temperature was $30^{\circ}C$, and the specific growth rate of Candida tropicalis was satisfied with the Monod equation up to 500 mg/L of phenol, and beyond it the inhibition of substrate was found. According to the increases of initial concentration and flow rate, the removal efficiency was decreased, as the recycle ratio was increased, the removal efficiency was increased. In the case of flow rate of 10mL/sec and the recycle ratio of 2, the removal efficiency was 90% above for the all of initial concentration. The removal rate of phenol was the first order reaction in this system, and the rate equation of reaction was as follows.

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유입.유출구 크기 변화에 따른 CNT용 CVD 장비 내의 열 및 유동해석 (Flow and heat transfer in a thermal CVD for carbon nanotubes according to variation of the inlet and outlet areas)

  • 하다솜;장영운;김종석;윤석범;임익태
    • 반도체디스플레이기술학회지
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    • 제10권4호
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    • pp.119-124
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    • 2011
  • Flow and temperature field in reactors are important factors for design of thermal chemical vapor deposition system to grow carbon nanotubes. In this study, effects of the variations of the inlet and outlet areas of the CVD reactor to the flow characteristics and temperature field are numerically analyzed. High temperature of the gas in the entrance region is obtained with slow gas speed resulted from the enlarged inlet area. Variation of the exit area has little effects on the flow field and temperature in the reactor. However the largest area among considered cases gives the highest gas temperature though the differences are small.

실험 계획법 및 열역학 계산법을 이용한 초고온가스로용 니켈계 초합금 설계 방법론 (Methodology of Ni-base Superalloy Development for VHTR using Design of Experiments and Thermodynamic Calculation)

  • 김성우;김동진
    • Corrosion Science and Technology
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    • 제12권3호
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    • pp.132-141
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    • 2013
  • This work is concerning a methodology of Ni-base superalloy development for a very high temperature gas-cooled reactor(VHTR) using design of experiments(DOE) and thermodynamic calculations. Total 32 sets of the Ni-base superalloys with various chemical compositions were formulated based on a fractional factorial design of DOE, and the thermodynamic stability of topologically close-packed(TCP) phases of those alloys was calculated by using the THERMO-CALC software. From the statistical evaluation of the effect of the chemical composition on the formation of TCP phase up to a temperature of 950 oC, which should be suppressed for prolonged service life when it used as the structural components of VHTR, 16 sets were selected for further calculation of the mechanical properties. Considering the yield and ultimate tensile strengths of the selected alloys estimated by using the JMATPRO software, the optimized chemical composition of the alloys for VHTR application, especially intermediate heat exchanger, was proposed for a succeeding experimental study.