• Title/Summary/Keyword: Chemical/Mechanical degradation

Search Result 214, Processing Time 0.023 seconds

Conjugate Heat Transfer Analysis of an Ethylene Furnace (에틸렌 반응로에 대한 복합 열전달 해석)

  • Ahn, Joon;Park, Jin Woo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.27 no.10
    • /
    • pp.515-519
    • /
    • 2015
  • Conjugate heat transfer analysis for an ethylene furnace was carried out based on numerical simulation. Detailed distributions of velocity vectors, chemical species, and temperature inside the furnace are presented and discussed. Von Mises stress and heat flux at the tube surface were also evaluated to elucidate mechanisms regarding failure of the tube. Maximum stress was found at the upstream elbow of the tube, which did not coincide with the location of maximum heat flux. This implies that thermal stress at a steady state would not be a dominant component of the stress. Degradation of the material, as well as the system arrangement, should be considered in order to accurately predict the lifetime of the tube material in the furnace.

Effect of hygrothermal aging on GFRP composites in marine environment

  • Garg, Mohit;Sharma, Shruti;Sharma, Sandeep;Mehta, Rajeev
    • Steel and Composite Structures
    • /
    • v.25 no.1
    • /
    • pp.93-104
    • /
    • 2017
  • In the present work, the effect of hygrothermal aging on the glass fibre and epoxy matrix interface has been investigated by destructive and non-destructive techniques. The glass fiber reinforced polymer (GFRP) composite laminates were prepared using Vacuum Assisted Resin Infusion Molding (VARIM) technique and the specimens were immersed in simulated seawater, followed by quantitative measurement. Besides this, the tensile tests of GFRP specimens revealed a general decrease in the properties with increasing aging time. Also, exposed specimens were characterized by a non-destructive ultrasonic guided Lamb wave propagation technique. The experimental results demonstrate a correlation between the drop in ultrasonic voltage amplitude and fall in tensile strength with increasing time of immersion. Hence, the comparison of the transmitted guided wave signal of healthy vis-a-vis specimens subjected to different extents of hygrothermal aging facilitated performance evaluation of GFRP composites.

A study on dielectric characteristics of gamma irradiated LDPE (방사선 조사에 따른 저밀도 폴리에틸렌의 유전특성에 관한 연구)

  • kim, Ki-Yup;Lee, Chung;Lim, Kee-Joe;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.07a
    • /
    • pp.169-172
    • /
    • 2000
  • In this paper, we evaluated the mechanical and dielectric properties of LDPE depend on $Co_{60}$${\gamma}$-irradiation doses. The chemical analyses for FT-IR, gel content, the mechanical properties for elongation at break and the dielectric parameters for permittivity, tan$\delta$ were discussed as a function of irradiation doses. Test result presented that elongation at break of irradiated LDPE was inversely proportional to gel content. For dielectric analyses, permittivity showed a salient characteristic for various irradiation doses, it was related to polar groups caused radiation degradation and tan$\delta$ of irradiated LDPE increased with irradiation doses.

  • PDF

Outlook for Wood Plastic Composite in aspect of Market and Technology (신 목질 복합재료인 합성목재의 전망 - 시장과 기술의 측면에서 -)

  • Han, You-Soo
    • Composites Research
    • /
    • v.19 no.6
    • /
    • pp.38-42
    • /
    • 2006
  • Wood Plastic Composite(WPC) has been introduced as a new constructional material in Europe and North America. The maintenance-free durability against weather was accepted by customers and the environment-friendly merits ignited the abrupt increase of market size. Domestic major companies have kicked off the WPC business at the market of outdoor constructional materials. Due to the high contents of natural wood fiber, the production equipments should be modified to remove the moisture, to prevent thermal degradation and to promote output rates. Materials including functional fillers play a critical role in rheological properties, which affects the physical and mechanical properties of the last products. More research might be performed for synergy effects combined by various academic fields from mechanical and chemical engineering to polymer process and material science.

Effects of Degradation according to Enzyme and pH changes of PVA/chitosan blend films (PVA/Chitosan 블랜드필름의 효소와 pH 변화에 따른 분해효과)

  • Jo, Hyung-Jae;Kim, Jong-Woan;Hwang, Sung-Kwy;Lee, Ki-Chang;Jeong, Duck-Chae
    • Journal of the Korean Applied Science and Technology
    • /
    • v.15 no.3
    • /
    • pp.21-26
    • /
    • 1998
  • Polyvinyl alcohol[PVA] is useful for the production of water-soluble packaging, paper, textile sizes. PVA and Chitosan are known as biodegradable polymers. PVA/chitosan blend films were prepared by solution blends method in the weight ratio of chitosan for the purpose of useful biodegradable films. Thermal and mechanical properties of PVA/chitosan blend films such as DSC, impact strength, tensile strength and morphology by SEM were determined. As a result, The ratio of 10.0wt% PVA/chitosan blend films were similar to PVA. Blend films were completely degraded pH 4.0 better than 7.0, 10.0 in the buffer solution. Also, Blend films were rapidly degraded enzyme(${\beta}-glucosidase$) solution better than pH solution by Enzymolysis.

Review on sodium corrosion evolution of nuclear-grade 316 stainless steel for sodium-cooled fast reactor applications

  • Dai, Yaonan;Zheng, Xiaotao;Ding, Peishan
    • Nuclear Engineering and Technology
    • /
    • v.53 no.11
    • /
    • pp.3474-3490
    • /
    • 2021
  • Sodium-cooled fast reactor (SFR) is the preferred technology of the generation-IV fast neutron reactor, and its core body mainly uses nuclear-grade 316 stainless steel. In order to prolong the design life of SFRs to 60 years and more, it is necessary to summarize and analyze the anti-corrosion effect of nuclear grade 316 stainless steel in high temperature sodium environment. The research on sodium corrosion of nuclear grade 316 stainless steel is mainly composed of several important factors, including the microstructure of stainless steel (ferrite layer, degradation layer, etc.), the trace chemical elements of stainless steel (Cr, Ni and Mo, etc) and liquid impurity elements in sodium (O, C and N, etc), carburization and mechanical properties of stainless steel, etc. Through summarizing and constructing the sodium corrosion rate equations of nuclear grade 316 stainless steel, the stainless steel loss of thickness can be predicted. By analyzing the effects of temperature, oxygen content in sodium and velocity of sodium on corrosion rate, the basis for establishing integrity evaluation standard of SFR core components with sodium corrosion is provided.

Effect of damage on permeability and hygro-thermal behaviour of HPCs at elevated temperatures: Part 2. Numerical analysis

  • Gawin, D.;Majorana, C.E.;Pesavento, F.;Schrelfer, B.A.
    • Computers and Concrete
    • /
    • v.2 no.3
    • /
    • pp.203-214
    • /
    • 2005
  • In the Part 1 paper (Gawin, et al. 2005) some experimental results concerning micro-structural tests, permeability measurements and stress-strain tests of four types of High Performance Concrete, exposed to elevated temperatures (up to $700^{\circ}C$) are presented and discussed. On the basis of these experimental results parameters of the constitutive relationships describing influence of damage and temperature upon material intrinsic permeability at high temperature were determined. In this paper the effects of various formulations of damage-permeability coupling on results of computer simulations are analysed and compared with the results obtained by means of the previously proposed approach, that does not take into account the thermo-chemical concrete damage directly. Numerical solutions are obtained using the recently developed fully coupled model of hygro-thermal and damage phenomena in concrete at elevated temperatures. High temperature effects are considered by means of temperature and pressure dependence of several material parameters. Based on the mathematical model, the computer code HITECOSP was developed. Material parameters of the model were measured by several European laboratories, which participated in the "HITECO" research project. A model problem, concerning hygro-thermal behaviour and degradation of a HPC structure during fire, is solved. The influence of two different constitutive descriptions of the concrete permeability changes at high temperature, including thermo-chemical and mechanical damage effects, upon the results of computer simulations is analysed and discussed.

Mechanical Properties on Poly Lactic Acid based Graft Copolymer with Polyethylene Glycol Acrylate (Polyethylene Glycol Acrylate를 이식 공중합 기반의 Poly Lactic Acid에 관한 기계적 특성)

  • Kim, Ki-Jun;Sung, Wan-Mo;Kim, Joo-Han;Jung, Hyung-Hak
    • Journal of the Korean Applied Science and Technology
    • /
    • v.34 no.3
    • /
    • pp.643-649
    • /
    • 2017
  • Biodegradable enzymes such as lipase and proteinase can hydrolyze not only fatty acid esters and triglycerides, but also aliphatic polyesters. We measured the biodegradability that biodegradable enzymes have an important role in the degradation of natural aliphatic poly material such as PLA, corn starch, and polyethylene glycol in the natural environment. However, we investigated on the biodegradability of PLA, PLA and Polyethylene acrylate blended, and PLAcoPolyethylene polymerized with PLA graft copolymer Polyethylene glycol acrylate. When prepared biodegradable polymers. the Mechanical properties of them were measured on Biodegradability, thermal properties, real time in-situ electrical monitoring of polymers resin. Therefore BOD and biodegradation of PLAcoPolyethylene was graft copolymerized with PLA and polyethylene acrylate were measured at a lower rate than the other samples.

Decrosslinking of Cross-linked Polyethylene using Supercritical Methanol (초임계 메탄올을 이용한 가교 폴리에틸렌의 탈가교화)

  • Hong, Soon Man;Cho, Hang-kyu;Koo, Chong Min;Lee, Jang Hoon;Park, Wan Yong;Lee, Hong-Shik;Lee, Youn-Woo
    • Korean Chemical Engineering Research
    • /
    • v.46 no.1
    • /
    • pp.63-68
    • /
    • 2008
  • We investigated the recycling method to re-plasticize cross-linked polyethylene by using supercritical methanol. The cross-linked polyethylene is successfully fragmented to thermoplasticized polyethylene with little degradation reactions in supercritical fluids. The thermo-plasticization reaction was accelerated with increase in temperature in the range from $360^{\circ}C$ to $400^{\circ}C$, resulting in decrease in crosslinking density, molecular weight and mechanical properties. However, the thermoplasticized polyethylene at $360^{\circ}C$ showed comparable tensile strength and impact strength with a raw resin of crosslinked polyethylene. Chemical structure of main chain of polyethylene was not affected by reaction condition.

An Experimental Analysis of the Ripple Current Applied Variable Frequency Characteristic in a Polymer Electrolyte Membrane Fuel Cell

  • Kim, Jong-Hoon;Jang, Min-Ho;Choe, Jun-Seok;Kim, Do-Young;Tak, Yong-Sug;Cho, Bo-Hyung
    • Journal of Power Electronics
    • /
    • v.11 no.1
    • /
    • pp.82-89
    • /
    • 2011
  • Differences in the frequency characteristic applied to a ripple current may shorten fuel cell life span and worsen the fuel efficiency. Therefore, this paper presents an experimental analysis of the ripple current applied variable frequency characteristic in a polymer electrolyte membrane fuel cell (PEMFC). This paper provides the first attempt to examine the impact of ripple current through immediate measurements on a single cell test. After cycling for hours at three frequencies, each polarization and impedance curve is obtained and compared with those of a fuel cell. Through experimental results, it can be absolutely concluded that low frequency ripple current leads to long-term degradation of a fuel cell. Three different PEMFC failures such as membrane dehydration, flooding and carbon monoxide (CO) poisoning that lead to an increase in the impedance magnitude at low frequencies are simply introduced.