• 설비공학논문집
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• 제18권4호
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• pp.320-327
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• 2006

Numerical analysis and experimental study are performed to investigate the effect of heat load and operating temperature on the thermal performance of several variable conductance heat pipe (VCHP) with screen meshed wick. The heat pipe is designed in 200 screen meshes, 500 mm length and 12.7 mm outer diameter tube of copper, water (4.8 g) is used as working fluid and nitrogen as non-condensible gas (NCG). Heat pipe used in this study has evaporator, condenser and adiabatic section, respectively. Analysis values and experimental data of wall temperature distribution along axial length are presented for heat transport capacity, condenser cooling water temperature change, degrees of an inclination angle and operating temperature. These analysis and experiment give the follow findings: For the same charging mass of working fluid, the operating temperature of heat pipe becomes to be high with the increasing of charging mass of NCG. When the heat flux at the evaporator section increases, the vapor pressure in the pipe rises and consequently compresses the NCG to the condenser end part and increases the active length of the condenser. From previous process, it is found out we can control the operating temperature effectively and also the analysis and experimental results are relatively coincided well.

• Electronic Materials Letters
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• 제14권6호
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• pp.755-765
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• 2018

In situ nitrogen doped hard carbon nanotubes (NHCNT) were fabricated by pyrolyzing tubular nitrogen doped conjugated microporous polymer. KOH activated NHCNT (K-NHCNT) were also prepared to improve their porous structure. XRD, SEM, TEM, EDS, XPS, Raman spectra, $N_2$ adsorption-desorption, galvanostatic charging-discharge, cyclic voltammetry and EIS were used to characterize the structure and performance of NHCNT and K-NHCNT. XRD and Raman spectra reveal K-NHCNT own a more disorder carbon. SEM indicate that the diameters of K-NHCNT are smaller than that of NHCNT. TEM and EDS further indicate that K-NHCNT are hollow carbon nanotubes with nitrogen uniformly distributed. $N_2$ adsorption-desorption analysis reveals that K-NHCNT have an ultra high specific surface area of $1787.37m^2g^{-1}$, which is much larger than that of NHCNT ($531.98m^2g^{-1}$). K-NHCNT delivers a high reversible capacity of $918mAh\;g^{-1}$ at $0.6A\;g^{-1}$. Even after 350 times cycling, the capacity of K-NHCNT cycled after 350 cycles at $0.6A\;g^{-1}$ is still as high as $591.6mAh\;g^{-1}$. Such outstanding electrochemical performance of the K-NHCNT are clearly attributed by its superior characters, which have great advantages over those commercial available carbon nanotubes ($200-450mAh\;g^{-1}$) not only for its desired electrochemical performance but also for its easily and scaling-up preparation.

• 한국수소및신에너지학회논문집
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• 제32권4호
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• pp.256-262
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• 2021

A carbon felt electrode was prepared using ozone and ammonia sequential treatment and applied as an electrode for a vanadium redox flow battery (VRFB). The physical and electrochemical analyses demonstrate that the oxygen groups facilitate nitrogen doping in the carbon felt. Carbon felt (J5O3+NH3), which was subjected to ammonia heat treatment after ozone treatment, showed higher oxygen and nitrogen contents than carbon felt (J5NH3+O3), which was subjected to ammonia heat treatment first and then ozone treatment. From the charging/discharging of VRFB, the J5O3+NH3 carbon felt electrode showed 14.4 Ah/L discharge capacity at a current density of 150 mA /cm², which was 15% and 33% higher than that of J5NH3+O3 and non-activated carbon felt (J5), respectively. These results show that ozone and ammonia sequential treatment is an effective carbon felt activation method to increase the performance of the vanadium redox flow battery.

• International Journal of Air-Conditioning and Refrigeration
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• 제14권4호
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• pp.125-130
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• 2006

This study has been performed to investigate the thermal performance of variable conductance heat pipe (VCHP) with screen meshed wick. The active length of condenser section in a VCHP is varied by non-condensible gas, which controls the operating temperature, and the heat capacity of VCHP is controlled by the operating temperature. In this study, numerical analysis of the VCHP based on the diffusion model of non-condensible gas is done for the thermal control performance of VCHP. Water is used as a working fluid and nitrogen as a control non-condensible gas in the copper tube. As a result, the thermal conductance of VCHP has been compared with that of constant conductance heat pipe (CCHP) corresponding to the variation of operating temperature.

• Journal of Electrochemical Science and Technology
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• 제12권4호
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• pp.458-464
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• 2021

Lithium ion batteries (LIBs) is a kind of rechargeable secondary battery, developed from lithium battery, lithium ions move between the positive and negative electrodes to realize the charging and discharging of external circuits. Zeolitic imidazolate frameworks (ZIFs) are porous crystalline materials in which organic imidazole esters are cross-linked to transition metals to form a framework structure. In this article, ZIF-67 is used as a sacrificial template to prepare nano porous carbon (NPC) coated cobalt nanoparticles. The final product Co/NPC composites with complete structure, regular morphology and uniform size were obtained by this method. The conductive network of cobalt and nitrogen doped carbon can shorten the lithium ion transport path and present high conductivity. In addition, amorphous carbon has more pores that can be fully in contact with the electrolyte during charging and discharging. At the same time, it also reduces the volume expansion during the cycle and slows down the rate of capacity attenuation caused by structure collapse. Co/NPC composites first discharge specific capacity up to 3115 mA h/g, under the current density of 200 mA/g, circular 200 reversible capacity as high as 751.1 mA h/g, and the excellent rate and resistance performance. The experimental results show that the Co/NPC composite material improves the electrical conductivity and electrochemical properties of the electrode. The cobalt based ZIF-67 as the precursor has opened the way for the design of highly performance electrodes for energy storage and electrochemical catalysis.

• 한국가스학회지
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• 제26권6호
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• pp.16-23
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• 2022

본 연구에서는 디스크와 인장시험 등을 통해 수소취성에 대한 재료 특성을 평가하고자 하였다. 이를 위해 니켈 당량이 28.5 이상인 합금 조성과, 이와 유사한 상용 합금 조성 2종에 대해 합금을 제조하였고, 각 합금은 진공유도용해로(Vacuum Induction Melting, VIM)에서 개발 합금(이하 #1)과 상용 배관(이하 각각 #2, #3)을 재용해하여 주조재로 제조하였고, 주조 합금은 단조 및 압연하여 판재로 제조하였다. 디스크형태의 시편은 0.1~1000 bar/min의 속도로 수소와 헬륨으로 가압하여 파열압력을 측정하여 수소에 대한 특성을 평가하였고, 전기화학적 방법으로 수소처리한 인장시편과 비교군에 대해 항복강도, 인장강도, 연신률, 단면적 감소율을 확인하였다. 또한 인장시편은 주사전사현미경을 통해 파단면을 확인하였다. 디스크파열시험과 수소처리 한 시편의 인장시험을 통해, 본 연구를 통해 개발된 강종의 경우 상용 강종과 비교하여 유사한 수소취성 특성을 갖고 있음을 확인하였고, 파단면 또한 미세한 두께의 벽개파괴 특성을 보였지만 기계적 강도에 큰 영향을 미치지 않음에 따라 개발된 고질소 스테인리스강은 내수소취성이 우수한 것으로 평가 할 수 있었다.

• 한국자동차공학회논문집
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• 제15권2호
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• pp.151-158
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• 2007

Filtration studies, using simulated test nanoparticles or diesel nanoparticles, have been performed about Inconel foam filters for DPF combined with electrostatic precipitation. The simulated test particles were synthesized by laser ablation in the nitrogen atmosphere at the standard condition. The diesel particles were exhausted from the diesel engine driven on the condition of idle or load mode. Filtration efficiency of the metal foam filter is very low because most of particles are penetrated through the large pores of filter. However, the efficiency was considerably improved by applying the electric field to the filter and/or charging the nanoparticles. Nevertheless, the pressure drop of filter hardly increased because the filter-pores were not clogged by deposited particles and kept open.

• 설비공학논문집
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• 제17권12호
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• pp.1139-1144
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• 2005

This study has been performed to investigate the thermal performance of variable conductance heat pipe (VCHP) with meshed wick. The length of condenser portion in a VCHP is varied by the expansion of inert gas with the operation temperature, and the heat transport capacity is thus varied with the operating temperature. In this study, numerical evaluation of the VCHP is made for the thermal performance of VCHP, based on the diffusion model of inert gas. Water is used as a working fluid and nitrogen as a control inert gas in the copper tube. As a result, the thermal performance of VCHP has been compared with that of constant conductance heat pipe (CCHP) according to the variation of operation temperature. Maximum heat transport capacity of VCHP is mainly presented for operation temperature and the variation of operation temperature is also presented for heat transfer rate of VCHP.

• 한국자기학회지
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• 제17권2호
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• pp.65-70
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• 2007

재사용이 가능한 리튬 이온 전지의 대체 양극 후보 물질인 $LiFePO_4$를 합성하고 질소 분위기 하에서 소결온도 $675^{\circ}C,\;750^{\circ}C$ 와 $800^{\circ}C$로 30시간 유지하여 합성한 시료에 대한 결정 구조의 양질성 여부를 확인하였고, SEM 사진을 통하여 입자의 크기를 조사하였으며, Mossbauer 분광법으로 소결온도 변화와 1 V 160 mA, 3 V, 40 mA로 3시간 동안 충전한 후 $Fe^{+3}$ 함유량의 변화를 조사하였다. 소결온도의 증가에 따라 완전 방전 상태에서 $Fe^{+3}$의 함량은 증가하였고, $675^{\circ}C$ 소결온도의 시료에서만 충전 전하량의 증가에 따라 $Fe^{+3}$ 이온의 비율이 증가를 관찰하였다. 소결온도가 $800^{\circ}C$인 시료에서의 충전 후 $Fe^{+3}$ 이온의 변화는 관찰할 수 없었다.

• 한국유체기계학회 논문집
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• 제17권6호
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• pp.104-108
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• 2014

The recent Fukushima nuclear power plant accidents shows that the core make up at high RCS pressure condition is very important to prevent core melting. The core make up flow at high pressure condition should be driven by gravity force or passive forces because the AC-powered safety features are not available during a Station Black Out (SBO) accident. The reactor Coolant System (RCS) mass inventory is continuously decreased by releasing steam through the pressurizer safety valves after reactor trip during a SBO accident. The core will be melted down within 2~3 hours without core make up action by active or passive mode. In the new design concept of a Hybrid Safety Injection Tank (Hybrid SIT) both for low and high RCS pressure conditions, the low pressure nitrogen gas serves as a charging pressure for a LBLOCA injection mode, while the PZR high pressure steam provides an equalizing pressure for a high pressure injection mode such as a SBO accident. After the pressure equalizing process by battery driven initiation valve at a high pressure SBO condition, the Hybrid SIT injection water will be passively injected into the reactor downcomer by gravity head. The SBO simulation by MARS code show that the core makeup injection flow through the Hybrid SIT continued up to the SIT empty condition, and the core heatup is delayed as much.