• Title/Summary/Keyword: Charge Balance

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A Review on Electrochemical Model for Predicting the Performance of Lithium Secondary Battery (리튬이차전지 성능 모사를 위한 전기화학적 모델링)

  • Yang, Seungwon;Kim, Nayeon;Kim, Eunsae;Lim, Minhong;Park, Joonam;Song, Jihun;Park, Sunho;Appiah, Williams Agyei;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.22 no.1
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    • pp.43-52
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    • 2019
  • As the application area of lithium secondary batteries becomes wider, performance characterization becomes difficult as well as diverse. To address this issue, battery manufacturers have to evaluate many batteries for a longer period, recruit many researchers and continuously introduce expensive equipment. Simulation techniques based on battery modeling are being introduced to solve such difficulties. Various lithium secondary battery modeling techniques have been reported so far and optimal techniques have been selected and utilized according to their purpose. In this review, the electrochemical modeling based on the Newman model is described in detail. Particularly, we will explain the physical meaning of each equation included in the model; the Butler-Volmer equation, which represents the rate of electrode reaction, the material and charge balance equations for each phase (solid and liquid), and the energy balance. Moreover, simple modeling processes and results based on COMSOL Multiphysics 5.3a will be provided and discussed.

Differences in Clinical Professors' Work-Life Balance by Position in Medical Schools (의과대학 임상교수 직급에 따른 일과 삶의 균형 차이 )

  • Yu Ra Kim;Hwan Ho Lee;So Jung Yune
    • Korean Medical Education Review
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    • v.25 no.1
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    • pp.45-54
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    • 2023
  • We investigated the work-life balance of clinical professors in charge of patient care, research, and education at medical schools and the demand for work-life balance support according to position (professor, associate professor, or assistant professor). In total, 163 clinical professors completed the consent form and participated in the study. They filled out an online survey consisting of questions about essential characteristics, a work-life balance test, stress, burnout, work-life satisfaction, and work-life balance support needs. We analyzed the results by analysis of variance and cross-tabulation using IBM SPSS ver. 23.0. Differences were found in work-life balance, stress, burnout, and satisfaction with life and work by position. The requirements for support for work-life balance also varied by professional status. Professors had a higher balance between life and work than associate professors or assistant professors. The specific requirements for work-life balance support were also slightly different for each position. Overall, there was a high demand for work process simplification and efficiency for work support, flexible working hours and sabbatical years for family and leisure, and career management consulting and training support for growth. Assistant professors and associate professors had a lower level of work-life balance than professors, as well as higher levels of stress and burnout. Professors' job satisfaction was also higher than that of the other groups. Based on the results of this study, we hope that a healthy work environment can be established through work-life balance support suitable for clinical professors' positions.

관성센서 출력 측정을 위한 AF 변환기 교정기법

  • Kim, Jeong-Yong;Cho, Hyun-Chul;Roh, Woong-Rae;Choi, Hyung-Don;Cho, Gwang-Rae
    • Aerospace Engineering and Technology
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    • v.4 no.2
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    • pp.117-125
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    • 2005
  • Generally, the inertial navigation and guidance unit uses AF(Analog-to-Frequency) converters which convert analog signals into frequency signals to enhance a measurement accuracy of gyroscope and accelerometer outputs. The confidence level of AF converter is guaranteed by a prudential decision of calibration procedure and a performance of periodic calibration test. In this paper, we focus on the synchronous charge balance type AF converter which has a separate positive or negative current input and its calibration method is described. The calibration tests are classified into the scale factor error calibration and the bias calibration. These tests are automatically performed by the calibration program.

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EML에서 Ir(ppy)3와 CBP의 도핑 위치에 따른 녹색 인광 OLED 특성 변화 연구

  • Im, Gi-Won;Choe, Byeong-Deok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.229.2-229.2
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    • 2016
  • 본 연구에서는 Host와 Dopant $Ir(ppy)_3$의 도핑 위치 변화에 따른 bottom emission 인광 OLED를 제작하여 발광 효율 및 특성을 분석하였다. 소자의 EML은 $Ir(ppy)_3/CBP$$CBP/Ir(ppy)_3$ 순으로 증착하여 제작하였다. $Ir(ppy)_3/CBP$은 낮은 구동 전압에서 큰 전류밀도와 큰 luminance을 측정하였고, 반대로 $CBP/Ir(ppy)_3$은 높은 구동 전압에서 $CBP/Ir(ppy)_3$은 큰 전류밀도와 큰 luminance가 측정되었다. 이는 $Ir(ppy)_3/CBP$에서 HTL과 EML 사이에 hole direct injection이 발생으로 Hole이 증가하지만 charge balance 불일치로 roll-off가 발생하고, $CBP/Ir(ppy)_3$에서 electron direct injection에 의한 electron 증가로 charge balance가 향상된다. EL spectrum 측정에서 $Ir(ppy)_3$은 파장 512nm 발광이 일어나고, CBP와 NPB은 각각 파장 380nm, 433nm로 분석된다. 각 물질의 triplet의 전달은 energy level이 큰 곳에서 작은 곳으로 전달되는데 이러한 이유로 전압에 따른 recombination zone 변화로 각 물질에서 나오는 파장의 intensity가 달라지는 것을 확인하였다. $Ir(ppy)_3/CBP$은 낮은 전류 밀도에서는 CBP의 영향으로 380nm 파장대가 크고, 높은 전류 밀도에서는 $Ir(ppy)_3$의 영향으로 512nm 파장대가 크게 나오는 것을 확인했고, $CBP/Ir(ppy)_3$에서는 낮은 전류 밀도에서 512nm 파장대가 커지고, 큰 전류 밀도에서는 CBP에서 NPB로의 triplet 에너지 전달의 증가로 433nm 파장대가 커지는 것을 확인하였다.

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Development and Evaluation of Body Surface Electric Energy Measurement System for Oriental Medical Diagnosis (한의 진단을 위한 체표에너지 측정 시스템의 개발 및 평가)

  • Kim, Soo-Byung;Kwon, Sun-Min;Kang, Hee-Jung;Yim, Yun-Kyoung;Lee, Yong-Heum
    • Korean Journal of Acupuncture
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    • v.26 no.1
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    • pp.51-60
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    • 2009
  • Objectives : It is considered not easy to diagnose the condition of acupoints or meridians. Oriental Medical instruments have rarely complied with Oriental Medical diagnostic/therapeutic theories. The aim of this study was to develop a system which measures meridian electric potential(MEP) in proportion to bio-electric charge for the purpose of Oriental Medical diagnosis. Method : To evaluate a meridian energy measurement system(MEMS), we carried out a performance test. For significance test, we conducted a clinical trial which measured the MEP of ST36(Chok-samni) on Stomach Meridian(ST). Results & Conclusions : We could evaluate the balance or the imbalance of the MEPs on the left/right ST36. Also, through the comparison of MEPs before and after meals, we could identify the correlation between the MEP and the condition of internal organs. Namely, MEP reflects the condition of acupoints/meridians and internal organs, therefore, we propose this new method for measuring and analyzing the condition of meridians and acupoints for Oriental Medical diagnosis.

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A Study on Improvement of the Performance of Pulsed AC Ion Bar (2) (바 형태 정전기제거장치의 정전기제거성능 향상을 위한 연구 (2))

  • Lee, Dong Hoon;Choi, Dong Soo;Kim, Sang Min;Park, Jin Chul
    • Journal of the Korean Society of Safety
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    • v.29 no.6
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    • pp.40-45
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    • 2014
  • In display such as LCD, LED, and AMOLED or semiconductor related industries are required to have static ionizer in order to produce reliable goods. The most general type of ionization is called, "corona discharge" that has a slight chances to generate unequal and unstable amount of each +/- ion to the target object. Then, the ionization performance will drastically decrease and end up with quality deterioration problem. continually "A study on the improvement of the performance of pulsed AC ion bar(1)", we have studied consecutive study to improve the current issue via appling "partition wall" at air nozzle surrounding. The results were that the charge decay time and the ion balance was maintained the satisfied range that was within 5 second and ${\pm}50$ V for a 180 days period of time. In additions, the contamination status on the electrode surface was investigated for a 180 days. The little particles was deposited on the electrode surface.

Development and Validation of HAUSAT-2 Nanosatellite EPS (HAUSAT-2 위성의 전력계 개발 및 검증)

  • Kim, Dong-Un;Jang, Yeong-Geun;Mun, Byeong-Yeong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.4
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    • pp.89-101
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    • 2006
  • This paper addresses Electrical Power Subsystem(EPS) design and verification of HAUSAT-2 small satellite through energy balance analysis(EBA) depending on individual operation modes. GaAs solar cells are used for satellite power generation and digital peak power tracking is implemented for EPS architecture. One battery pack is consisted of 4 Li-Ion cells. Battery charge is accomplished by peak power tracker and battery charge regulator. Power conditioning assembly uses three DC-DC converters, and power distribution assembly which consists of commercial IC and MOSFET switch distributes power to subsystems and payloads. The altitude of 650km and sun-synchronous LEO with various local time ascending node(LTAN) are considered in EBA.

Digital CMOS Temperature Sensor Implemented using Switched-Capacitor Circuits

  • Son, Bich;Park, Byeong-Jun;Gu, Gwang-Hoe;Cho, Dae-Eun;Park, Hueon-Beom;Jeong, Hang-Geun
    • Journal of Sensor Science and Technology
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    • v.25 no.5
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    • pp.326-332
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    • 2016
  • A novel CMOS temperature sensor with binary output is implemented by using fully differential switched-capacitor circuits for resistorless implementation of the temperature sensor core. Temperature sensing is based on the temperature characteristics of the pn diodes implemented by substrate pnp transistors fabricated using standard CMOS processes. The binary outputs are generated by using the charge-balance principle that eliminates the division operation of the PTAT voltage by the bandgap reference voltage. The chip was designed in a MagnaChip $0.35-{\mu}m$ CMOS process, and the designed circuit was verified using Spectre circuit simulations. The verified circuit was laid out in an area of $950{\mu}m{\times}557 {\mu}m$ and is currently under fabrication.

A Comparative Study on the Chemicostructural Characteristics of Ecdysteroids (Ecdysteroid 화합물들의 화학구조 특성에 대한 비교연구)

  • Hwang, Gab-Soo
    • Journal of Environmental Health Sciences
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    • v.38 no.4
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    • pp.351-359
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    • 2012
  • Objectives: This study was conducted in order to investigate the specific correlation between physicochemical properties and bioactivity in ecdysteroids found in living organisms. Methods: The examined steroidal compounds were classified into three groups according to their relevance to ecdysone activity. Each compound molecule was completely drawn to automatically calculate its physicochemical parameters and docked against 20-hydroxyecdysone to calculate the total distance. Electronic charge distribution was also observed for each molecule. All procedures were conducted using a computational chemistry program. Results: Ecdysone agonists showed different ranges of parameter values, such as log P, hydrophilic-lipophilic balance (HLB), solubility parameter (SP), hydrophilic surface (HPS), hydrogen bond (HB) and Kappa 2, when compared with antagonists and steroids without ecdysone activity. They also showed a similar electronic charge distribution that is significantly different from the electron charge distribution of antagonists and steroids without ecdysone activity. The total distance values of agonists, estimated by docking them with 20-hydroxyecdysone, were relatively small but showed no correlation with binding affinity with receptor ligand. Conclusions: These results suggest that physicochemical properties such as steric and electronic effects, hydrophobicity and hydrogen bonding may operate in combination to determine the binding activity of ecdysteroids to the receptor protein.

Effect of Cathode/anode Weight Ratio in $LiCoO_2/MPCF$ Cell ($LiCoO_2/MPCF$전지에서 정$\cdot$부극 중량비의 영향)

  • Kim Sang-Pil;Cho Jeong-Soo;Kim Hee-Je;Park Jeong-Hu;Yun Mun-Soo
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.75-80
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    • 1999
  • Li-ion cells employ lithium transtion metal oxide as the cathode material and carbon as anode material. To manufacture Li-ion cell with higher capacity and better cycle life, the utilization of electrode materials should be as high as possible without lithium deposition onto the carbon surface during charging. A careful design of cell balance between cathode and anode materials as well as a proper charge method is a key factor to design Li-ion cell with long cycle life. In this study, we investigated the effect of cathode/anode weight ratio on the performance of $LiCoO_2/MPCF$ cell. First we evaluated the charge-discharge behaviours of half-cells. And cylindrical Li-ion cells were fabricated using graphitized MPCF anode and $LiCoO_2$ cathode. The voltage profiles for each half-cell in $LiCoO_2/MPCF$ cell were measured by using lithium metal as a reference electrode. Also, we evaluated the cyclic performance of $LiCoO_2/MPCF$ cells according to weight ratio. From the result of experiment $LiCoO_2$ cathode utilization was independent of weight ratio, but MPCF anode utilization was dependant on weight ratio. Also, the optimal weight ratio of $LiCoO_2/MPCF$ cell was found to be $2.0\~2.2$.