• Title/Summary/Keyword: Character formula

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Determination of Dissociation Constant of Hydrogen Cupferrate in Methanol-Water and 2-Propanol-Water Solution (Methanol-물 및 2-Propanol-물의 混合溶媒에서의 Hydrogen Cupferrate의 酸解離常數의 決定)

  • Si-Joong Kim;Chang-Ju Yoon;In-Soon Chang
    • Journal of the Korean Chemical Society
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    • v.10 no.3
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    • pp.119-128
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    • 1966
  • The glass electrode was empirically calibrated in methanol-and 2-propanol-water mixed solvents, by means of which the pH-meter reading could be converted to stoichiometric hydrogen ion concentration. The thermodynamic dissociation constants of hydrogen cupferrate in methanol-and 2-propanol-water solution were potentiometrically determined with the changes in composition of organic solvents at 0.01 and 0.05 of the ionic strength and 25$^{\circ}C$. The empirical formula of the constants with mole fraction (n) of the organic solvent are as follow: methanol-water solution $pK_a$= 2.24n + 4.29 at ${\mu}$ = 0.01 n = 0.0476∼0.642 $pK_a$ = 2.35n + 4.38 at ${\mu}$ = 0.05 n= 0.0446~0.642 2-propanol-water solution $pK_a$= 5.50n + 4.48 at ${\mu}$ = 0.05 n = 0.0253~0.259 The relationships between $pK_a$ of acetic acid, propionic acid and HCup and dielectric constant of some mixed solvents were discussed. It would be considered that the factors effecting $pK_a$ value of weak acid in mixed-solvent are not only dielectric constants but acid-base character and solvation effect of the solvent, etc.

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A Study of the Voltage drops computation program on multi-distributed random loads (다중 분산부하 전압강하산정 프로그램 연구)

  • Kang, Cha-Nyeong;Kwon, Sae-Hyuk;Cho, Sung-Pil
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2006.05a
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    • pp.37-42
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    • 2006
  • The voltage drop in electrical circuits causes a heat accumulation of wiring. This heat could change the specific character of an insulator and deteriorate the dielectric strength so that it could affect an electric leakage, an electric ant a power failure and a fire caused by the short circuit. Therefore optimal design for voltage drop in electrical wiring became an important factor to ensure the safety and economical efficiency of electrical facilities. So in this paper, I analyzed consequences that voltage drop affects in electrical wiring in multi-distributed system used for low electrical system such as road lights, Building, subway station which needs securities for the public society. And I proposed voltage drops computation program and optimal design to ensure the safety and economical efficiency.

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A Taxonomic Study on Sedum Section Telephium in Korea (한국산 돌나물속 Telephium 절 식물의 분류학적 연구)

  • 정영호
    • Journal of Plant Biology
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    • v.33 no.1
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    • pp.1-24
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    • 1990
  • This study was attempted to clarify the taxonomic problems that have been raised up to now in the study o section Telephium, genus, Sedum: the delimitation of taxa belong to Telephium group, their relationship, and nomenclatural confusion and the rank of Telephium group. Specimens were collected at 19 sites in Korea. The habitat, distribution, external morphological characters of habit, leaf shape, phyllotaxy, inflorescence, color of floral organs, floral formula, carpel, capsule, and micro-characters of pollen, seed coat, stigma and anther with SEM were examined. Through this study, the following results were obtained. The delimitation of taxa that belong to section Telephium in Korea and their relationship Nomenclatural errors were corrected. In S. rotundifolium Lee, species epithet“rotundifolium”is later homonym of s. rothundifolium Lamarck, so corrected to S. duckbongii Chung and Kim by article 64 of ICBN. Phyllotaxy was elucidated to meaningless, character in sect. Telephium. S. taquetii was a separate species from S. viridescens and not of its synonym. S. alboroseum Baker in Korea was S. erythrostictum sensu Master not of S. erythrostictum Miquel. By this study , taxa of sect. Telephium in Korea were arranged to 7 species. Considering interspecific relationship of sect. Telephium, S. duckbongii and S. alboroseum are considered to be more advanced forms and S. viridescens, S. taquetii, and S. viviparum to be more primitive forms among 7 species.

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Philological Analysis of Shanghan Prescriptions from the Chinese Unearthed Documents (중국 출토문헌에 보이는 상한방(傷寒方)의 문자학적 분석)

  • Lee, Kyung
    • Journal of Korean Medical classics
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    • v.32 no.3
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    • pp.17-29
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    • 2019
  • Objectives : This paper is an analysis of the name 'Shanghan(傷寒)' and its related contents in unearthed documents. "Shanghanlun" as we know it is an edited version by Wangshuhe of the Jin period, as the original text as written by Zhangzhongjing has been unavailable. Recently in China, documents of the Xian Jin and Liang Han periods are being unearthed, allowing us to look at medical texts of previous times that Zhang referenced. The aim of this paper is to look at the developmental process of the Shanghan theory based on these medical texts. Methods : Research documents include all unearthed documents that include the name 'Shanghan'. There were a total of 4 written cases, 2 in "Wuweihandaiyijian", and one each in "Dunhuanghanjian" and "Juyanhanjian". Meaning of extracted examples were analyzed in reference to the shape of the character, then compared and analyzed with existing medical texts such as "Shanghanlun", "Jibeiqianjinyaofang", and "Bencaogangmu" Conclusions : By examining the 4 examples, Bianzhenglunzi and clinical prescriptions which are characteristics of Shanghanlun could be found. There was an 'Eliminating Wind' formula that was used to eliminate Cold pathogen of the exterior which showed remarkable resemblance to that found in "Jibeiqianjinyaofang". There are also formulas that 'Communicate to Disentangle' and 'Disentangle the Stomach' which are used in progressed stages of Shanghan disease, showing that Bianzhenglunzi had already been applied to Shanghan conditions.

A case of a patient with irritable bowel syndrome diagnosed with Shanghanlun Yangmingbing Soseunggi-tang (『상한론(傷寒論)』 양명병(陽明病) 소승기탕(小承氣湯)으로 진단된 과민 대장 증후군 환자 1례)

  • Jae-young Choi;Soong-in Lee;Mi-hyun Lee;Sung-jun Lee
    • 대한상한금궤의학회지
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    • v.14 no.1
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    • pp.81-93
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    • 2022
  • Objective : This study reports on the case of a patient with irritable bowel syndrome (IBS) diagnosed by the Shanghanlun disease pattern identification diagnostic system (DPIDS). We tried to verify the therapeutic effects of Soseunggi-tang (SSGT) administration and pathological character. Methods : The patient was administered SSGT for 31 days. We observed the progression of symptoms, patient compliance, and the presence of side effects. The progression of IBS was evaluated based the on Gastrointestinal Symptom Rating Scale (GSRS). Abdominal pain, flatus, visual findings, and patient statements were also assessed. Results : According to the DPIDS, the patient was diagnosed with Yangmingbing (陽明病). As a result, his GSRS score dropped from 15 to 5, the visual analog scale (VAS) score for abdominal pain lowered from 9 to 4, and the VAS score for flatus decreased from 8 to 4. The stool type changed from diarrhea to a loose stool form. Conclusions : SSGT showed therapeutic effects on the patient diagnosed with IBS and Yangmingbing.

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Development of Intelligent OCR Technology to Utilize Document Image Data (문서 이미지 데이터 활용을 위한 지능형 OCR 기술 개발)

  • Kim, Sangjun;Yu, Donghui;Hwang, Soyoung;Kim, Minho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2022.05a
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    • pp.212-215
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    • 2022
  • In the era of so-called digital transformation today, the need for the construction and utilization of big data in various fields has increased. Today, a lot of data is produced and stored in a digital device and media-friendly manner, but the production and storage of data for a long time in the past has been dominated by print books. Therefore, the need for Optical Character Recognition (OCR) technology to utilize the vast amount of print books accumulated for a long time as big data was also required in line with the need for big data. In this study, a system for digitizing the structure and content of a document object inside a scanned book image is proposed. The proposal system largely consists of the following three steps. 1) Recognition of area information by document objects (table, equation, picture, text body) in scanned book image. 2) OCR processing for each area of the text body-table-formula module according to recognized document object areas. 3) The processed document informations gather up and returned to the JSON format. The model proposed in this study uses an open-source project that additional learning and improvement. Intelligent OCR proposed as a system in this study showed commercial OCR software-level performance in processing four types of document objects(table, equation, image, text body).

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Synthesis, Spectroscopic, and Biological Studies of Chromium(III), Manganese(II), Iron(III), Cobalt(II), Nickel(II), Copper(II), Ruthenium(III), and Zirconyl(II) Complexes of N1,N2-Bis(3-((3-hydroxynaphthalen-2-yl)methylene-amino)propyl)phthalamide (N1,N2-bis(3-((3-hydroxynaphthalen-2-yl)methylene-amino)propyl)phthalamide의 크롬(III), 망간(II), 철(III), 코발트(II), 니켈(II), 구리(II), 루테늄(III) 및 산화 지르코늄(II) 착물에 대한 합성과 분광학 및 생물학적 연구)

  • Al-Hakimi, Ahmed N.;Shakdofa, Mohamad M.E.;El-Seidy, Ahemd M.A.;El-Tabl, Abdou S.
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.418-429
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    • 2011
  • Novel chromium(III), manganese(II), iron(III), cobalt(II), nickel(II), copper(II), ruthenium(III), and zirconyl(II) complexes of $N^1,N^2$-bis(3-((3-hydroxynaphthalen-2-yl)methylene-amino)propyl)phthalamide ($H_4L$, 1) have been synthesized and characterized by elemental, physical, and spectral analyses. The spectral data showed that the ligand behaves as either neutral tridentate ligand as in complexes 2-5 with the general formula $[H_4LMX_2(H_2O)]{\cdot}nH_2O$ (M=Cu(II), Ni(II), Co(II), X = Cl or $NO_3$), neutral hexadentate ligand as in complexes 10-12 with the general formula $[H_4LM_2Cl_6]{\cdot}nH_2O$ (M=Fe(III), Cr(III) or Ru(III)), or dibasic hexadentate ligand as in complexes 6-9 with the general formula $[H_2LM_2Cl_2(H_2O)_4]{\cdot}nH_2O$ (M = Cu(II), Ni(II), Co(II) or Mn(II), and 13 with general formula $[H_4L(ZrO)_2Cl_2]{\cdot}8H_2O$. Molar conductance in DMF solution indicated the non-ionic nature of the complexes. The ESR spectra of solid copper(II) complexes 2, 5, and 6 showed $g_{\parallel}$ >g> $g_e$, indicating distorted octahedral structure and the presence of the unpaired electron in the $N^1,N^2$ orbital with significant covalent bond character. For the dimeric copper(II) complex $[H_2LCu_2Cl_2(H_2O)_4]{\cdot}3H_2O$ (6), the distance between the two copper centers was calculated using field zero splitting parameter for the parallel component that was estimated from the ESR spectrum. The antibacterial and antifungal activities of the compounds showed that, some of metal complexes exhibited a greater inhibitory effect than standard drug as tetracycline (bacteria) and Amphotricene B (fungi).

Study on the Flexible Strength of U-shape Hybrid Composite Beam (신형상 U형 하이브리드 합성보의 휨성능에 대한 연구)

  • Kim, Sung-Bae;Kim, Sang-Seup;Lee, Won-Rok;Kim, Jung-Yeon;Lee, Seung-Bae;Ryu, Deog-Su;Kim, Dae-Hoi
    • Journal of Korean Society of Steel Construction
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    • v.24 no.5
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    • pp.521-534
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    • 2012
  • In this research, we carry this study into effect on the basis of utilizing character of composite beam and developing applicable section to some of high strength steel. We evaluated flexural capacity of composite beam that is a unit member through experiments. The existing nominal strength formula of Composite Beam which is a previous method was reviewed and the experiment had been progressive by using each composite members as main variables though the result. Capacity evaluation of U-shape Hybrid Forming Beam(HyFo Beam) which is a new shape show as follow from the result. First, it is resonable to resist demand moment by couple moments which are occurred in concrete compressive-strength and steel tensile-strength. Second, the capacity was stably increased in proportion to the depth of beams and the thickness of steel plates. The last, HyFo Beam was showed as ductile behavior.

Occurrence of Chiroteuthis picteti (Teuthoidea: Chiroteuthidae) from Korea (Chiroteuthis picteti (Teuthoidea: Chiroteuthidae)의 국내출현)

  • Kang, Hyunjung;Choi, Jung Hwa;Choi, Kwang Ho;Lee, Dongwoo;Kim, Yeonghye
    • The Korean Journal of Malacology
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    • v.29 no.4
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    • pp.381-384
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    • 2013
  • One specimen (13.4 cm ML) of Chiroteuthis picteti belonging to the family Chiroteuthidae, firstly collected from Songjeong, Southeast coastal water of Korea on May 18, 2013. It was identified as C. picteti based on the following combination of morphological character: mantle slenderly cylindrical; fin oval shape, both lobes having no anterior free lobe, FL 58.2% of ML; arms long with a formula IV > III > II > I. We propose a new Korean name, "Kin-pal-o-jing-eo-gua", "Kin-pal-o-jing-eo-sok", and "Kin-pal-o-jing-eo" for the family, genus and species, respectively.

Correlation between Compressive Strength and Unit Weight of Lightweight Foamed Controlled Low Strength Material (CLSM) Using Coal Ash (석탄회를 활용한 경량기포 CLSM의 압축강도와 단위중량의 상관관계)

  • Lee, Jong-Hwi;Lee, Hye-Jin;Chun, Byung-Sik
    • Journal of the Korean Geotechnical Society
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    • v.29 no.1
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    • pp.39-47
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    • 2013
  • With the increase in the application of CLSM using coal ash, we performed a basic research on CLSM material, laying focus on the correlation between compressive strength and unit weight of lightweight foamed CLSM. The unconfined compression strength is a criterion for the judgment of the possibility of re-excavation and an important factor determining the economy, efficiency, and excavation character. However, to know the quantitative compression strength value takes a certain amount of time, because the applicability of unconfined compression strength of CLSM is judged by the standard of 28days. Therefore, in this study the relation between compressive strength and unit weight (foam slurry unit weight, apparent unit weight) is analyzed focusing on lightweight foamed CLSM. We also suggested a formula which can easily predict the 28-day compressive strength only using unit weight value without the need to cure the slurry for 28 days.