• 제목/요약/키워드: Cell performance

검색결과 5,021건 처리시간 0.033초

PEMFC Characterization Study by in-situ Analysis Method (In-Situ 분석법에 의한 연료전지 특성 연구)

  • Kim, Young-Min;Lee, Jong-Hyun;Im, Se-Joon;Ahn, Byung-Ki;Lim, Tae-Won
    • Transactions of the Korean hydrogen and new energy society
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    • 제20권3호
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    • pp.208-215
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    • 2009
  • PEMFC stack power output is needed to be around 100 kW to meet the requirements of automotive application and scaling-up the active area of the stack cells will allow a higher power. In the case of scaling-up the active area of cells, it is difficult to obtain uniform in-plane internal conditions such as temperature, relative humidity and stoichiometry of the feed gas. These ununiformity with the location in the cell would affect both the performance and durability of the stack, so it is important to understand phenomena in the cell for improving them. In this study, the current density, electrochemical resistance and performance distribution measurement was performed to understand the ununiformity in a single cell using in-situ method; (1) Current Density Distribution (CDD) Device and (2) Segmented Cell Fixture. The influence of location of feed gas on the performance of a single cell was experimentally measured and discussed by using a segmented single cell which was composed of 8 compartments. The correlation between the location and performance in a single cell was discussed by these two tools and it was extended between the local characterization and the durability in a MEA by comparing the used cell with a fresh one. It was also studied in terms of electrochemistry by Electrochemical Impedance Spectroscopy.

Effect of the LDC Buffer Layer in LSGM-based Anode-supported SOFCs (LSGM계 음극지지형 고체산화물 연료전지에 적용된 LDC 완충층의 효과)

  • Song, Eun-Hwa;Chung, Tai-Joo;Kim, Hae-Ryoung;Son, Ji-Won;Kim, Byung-Kook;Lee, Jong-Ho;Lee, Hae-Weon
    • Journal of the Korean Ceramic Society
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    • 제44권12호
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    • pp.710-714
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    • 2007
  • LSGM$(La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.2}O_{3-{\delta}})$ is the very promising electrolyte material for lower-temperature operation of SOFCs, especially when realized in anode-supported cells. But it is notorious for reacting with other cell components and resulting in the highly resistive reaction phases detrimental to cell performance. LDC$(La_{0.4}Ce_{0.6}O_{1.8})$, which is known to keep the interfacial stability between LSGM electrolyte and anode, was adopted in the anode-supported cell, and its effect on the interfacial reactivity and electrochemical performance of the cell was investigated. No severe interfacial reaction and corresponding resistive secondary phase was found in the cell with LDC buffer layer, and this is due to its ability to sustain the La chemical potential in LSGM. The cell exhibited the open circuit voltage of 0.64V, the maximum power density of 223 $mW/cm^2$, and the ohmic resistance of $0.17{\Omega}cm^2$ at $700^{\circ}C$. These values were much improved compared with those from the cell without any buffer layer, which implies that formation of the resistive reaction phases in LSGM and then deterioration of the cell performance is resulted mainly from the La diffusion from LSGM electrolyte to anode.

Performance of Unified Inter-Cell Interference Avoidance and Cancellation in OFDM Mobile Cellular Systems (OFDM 이동 셀룰러 시스템에서 셀간간섭 회피 및 제거의 결합 성능 분석)

  • Kwon, Jae-Kyun;Lee, Hee-Soo;Ahn, Jae-Young
    • The Journal of Korean Institute of Communications and Information Sciences
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    • 제33권4A호
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    • pp.371-376
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    • 2008
  • In this paper, we explain the unified inter-cell interference avoidance and cancellation in OFDM mobile cellular systems. Interference avoidance is used for cell-interior or two-cell-edge users, and interference cancellation is applied to three-cell-edge users. The performance of the unified scheme is evaluated by simplified system simulation. Link simulation results are used in the interpretation of system simulation output. We compare three schemes which are "no interference management," "only interference avoidance," "both avoidance and cancellation." Primary performance measures are the data rate of the 5th percentile user and the mean data rate. Simulation results show that interference management schemes greatly improve the cell edge performance, but slightly reduce the mean data rate. Use of both avoidance and cancelaltion is better than that of only avoidance in terms of the cell edge throughput and the mean data rate.

Performance Analysis with Various Amounts of Electrolyte in a Molten Carbonate Fuel Cell

  • Kim, Yu-Jeong;Kim, Tae-Kyun;Lee, Ki-Jeong;Lee, Choong-Gon
    • Journal of Electrochemical Science and Technology
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    • 제7권3호
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    • pp.234-240
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    • 2016
  • The effect of initial electrolyte loading (IEL) on cell performance in a coin-type molten carbonate fuel cell (MCFC) was investigated in this work. Since the material of MCFC depends on the manufacturer, optimisation requires experimental investigation. In total, four IEL values, 1.5, 2.0, 3.0, and 4.0 g, were used, corresponding to a pore filling ratio (PFR) of 38, 51, 77, and 102%, respectively. The cell performance with respect to the PFR was analysed via steady-state polarisation, step-chronopotentiomtery, and impedance methods. The electrochemical analyses revealed that internal resistance and overpotential of the cell decreased with increasing PFR, and a large overpotential was observed when the PFR was 102%, probably due to the flooding phenomenon. After operation, cross-section of the cell was analysed via surface analysis of SEM and EDS methods, and the remaining electrolyte was estimated by dissolution of the cell in 10 wt% acetic acid. A linear relationship between IEL and the weight reduction ratio by dissolution was obtained. Thus, the remaining amount of electrolyte could be measured after operation. The results of SEM and EDS showed that a PFR of 38 and 102% showed a lack and flooding of electrolytes at the cell, respectively, which led to a large overpotential. This work reports that MCFC performance is allowed only in the narrow range of PFR.

Performance Analysis of PCM Cell Search Algorithm for Fast Cell Search in WCDMA Systems (WCDMA. 시스템에서 빠른 셀 탐색을 위한 극성 변조 셀 탐색 알고리즘의 성능 분석)

  • 배성오;임재성
    • The Journal of Korean Institute of Communications and Information Sciences
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    • 제28권8A호
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    • pp.598-606
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    • 2003
  • In this paper, we analyze the performance of the PCM cell search algorithm proposed for fast cell search of WCDMA systems. In order to improve both performance and complexity of the cell search algorithm standardized for WCDMA systems the PCM scheme uses a group of the polarization codes produced by a Gold code generator. The PCM scheme only uses one synchronization channel since the polarization codes modulated on P-SCH can replace the RS codes of S-SCH. Thus, the PCM reduces the BS's transmission power since only one synchronization channel can be used, and it can also reduce the complexity of receiver as compared with the conventional one. In this paper, by defining a numerical model, we analyze the performance of the PCM cell search algorithm in terms of detection probability and mean acquisition time. Consequently, we could demonstrate that the PCM cell search algorithm is superior to the standard WCDMA cell search algorithm.

Experimental Analyses of Cell Voltages for a Two-cell PEM Stack Under Various Operating Conditions

  • Park, Sang-Kyun;Choi, Jae-Hyuk
    • Journal of Advanced Marine Engineering and Technology
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    • 제35권7호
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    • pp.881-890
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    • 2011
  • Analyses of performance and behavior of the individual PEM fuel cells (PEMFC) under different operating conditions are of importance optimally to design and efficiently to operate the stack. The paper focuses on experimental analyses of a two-cell stack under different operating conditions, which performance and behavior are measured by the voltage of a cell as well as the stack. Experimental parameters include stoichiometric ratio, temperature of the air supplied under different working stack temperatures and loads. Results showed that the cell voltages are dominantly influenced by the temperature of the air supplied among others. In addition, an inherent difference between the first and the second cell voltage exists because of the tolerances of the cell components and the resulting different over-potentials at different equilibrium states. Furthermore, it is shown that the proton conductivity in the membranes conditioned by the humidity in the cathode channel highly affects the voltage differences of the two cells.

Dual Virtual Cell: a New Concept of Virtual Cell in Distributed Wireless Communication System (분산무선시스템 기반의 새로운 Dual Virtual Cell 개념 및 운용방안)

  • Yang, Joo-Young;Kim, Jeong-Ho
    • Proceedings of the IEEK Conference
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    • 대한전자공학회 2005년도 추계종합학술대회
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    • pp.19-22
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    • 2005
  • In order to achieve high capacity and reliable link quality in user communication, this paper proposes a new concept of virtual cell: the Dual Virtual Cell(DVC), and DVC employment strategy based on DWCS. The proposed system uses two kinds of virtual cell. One is the AVC(Active Virtual Cell) which exists for actual traffic and the other is the CVC(Candidate Virtual Cell) which contains a set of candidate antennas to protect user's link quality from performance degradation or interruption. And also this system aims to reduce MT's overloads and acheive a prompt link change successfuly by introducing DVC structure which makes it possible for network to monitor real-time channel and to conrol communication links. The proposed system constructs DVC by using antenna selection method and improves frame error performance with employing Space-Time Trellis Code(STTC).

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Performance Analysis of Solid Oxide Fuel Cell/Gas Turbine Hybrid Systems for Different Cell Inlet Preheating Methods (셀 입구 예열방법에 따른 고체산화물 연료전지/가스터빈 하이브리드 시스템의 성능해석)

  • Yang, Won-Jun;Kim, Tong-Seop;Kim, Jae-Hwan
    • Proceedings of the KSME Conference
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1664-1669
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    • 2004
  • Design analysis of the solid oxide fuel cell and gas turbine combined power system is performed considering different methods for preheating cell inlet air. The purpose of air preheating is to keep the temperature difference between cell inlet and outlet within a practical design range. Three different methods are considered such as a burner in front of the cell, a preheater in front of the cell and recirculation of the cathode exit gas. Analyses are carried out for two maximum cell temperature differences. The greater temperature difference ensures higher efficiency. The cathode exit gas recirculation exhibits better performance than other methods.

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200hrs Operational Characteristics of the Single Cell in Phosphoric Acid Fuel Cell (인산형 연료전지 단위전지 200시간 운전특성 연구)

  • Song, R.H.;Kim, C.S.;Choi, B.W.;Han, S.O.;Choi, S.H.
    • Proceedings of the KIEE Conference
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    • 대한전기학회 1991년도 하계학술대회 논문집
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    • pp.73-77
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    • 1991
  • 200hrs operational characteristics of the single cell in phosphoric acid fuel cell was studied. The initial performance of single cells was examined as a function of PTFE content of electrode in the range of 30 to 60 wt.%. The cell with the electrode of 40wt.% PTFE was chosen for the 200hrs operation. The cell voltage decay was found to be about 0.5mV/hr for 200hrs operation. These results of cell performance were discussed as related to the internal resistance and the exchange current density of the cell.

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Modeling and Analysis of the Air Supply System for Vehicular PEM Fuel Cell (PEM 연료전지 자동차의 급기 시스템의 모델링 및 분석)

  • Jang, Hyuntak;Kang, Esak
    • Transactions of the Korean hydrogen and new energy society
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    • 제14권3호
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    • pp.236-246
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    • 2003
  • This paper focuses on developing a model of a PEM fuel cell stack and to integrate it with realistic model of the air supply system for fuel cell vehicle application. The fuel cell system model is realistically and accurately simulated air supply operation and its effect on the system power and efficiency using simulation tool Matlab/Simulink. The Peak performance found at a pressure ratio of 3, and it give a 15mV increase per cell. The limit imposed is a minimum SR(Stoichiometric Ratio) of 2 at low fuel cell load and 2.5 at high fuel cell load.