• Title/Summary/Keyword: Cell current

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Development of Inexpensive High Energetic Electrodes Ni-Cu and Ni-CeO2-Cu for Renewable Energy through Direct Ethanol Fuel Cell

  • Guchhait, Sujit Kumar;Paul, Subir
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.190-198
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    • 2016
  • Application of fuel cell to produce renewable energy for commercial purpose is limited by the high cost of Pt based electrode materials. Development of inexpensive, high energetic electrode is the need of the hour to produce pollution free energy using bio-fuel through a fuel cell. Ni-Cu and Ni-CeO2-Cu electrode materials, electro synthesized by pulse current have been developed. The surface morphology of the electrode materials is controlled by different deposition parameters in order to produce a high current from the electro-oxidation of the fuel, the ethanol. The developed materials are electrochemically characterized by Cyclic Voltammetry (CV), Chronoamperometry (CA) and Potentiodynamic polarization tests. The results confirm that the high current is due to their enhanced catalytic properties viz. high exchange current density (i0), low polarization resistance (Rp) and low impedance. It is worthwhile to mention here that the addition of CeO2 to Ni-Cu has outperformed Pt as far as the high electro catalytic properties are concerned; the exchange current density is about eight times higher than the same on Pt surface. The morphology of the electrode surface examined by SEM and FESEM exhibits that the grains are narrow and sub spherical with 3D surface, containing vacancies in between the elongated grains. The fact has enhanced more surface area for electro oxidation of the fuel, giving rise to an increase in current. Presence of Ni, CeO2, and Cu is confirmed by the XRD and EDXS. Fuel cell fabricated with Ni-CeO2-Cu material electrode is expected to produce clean electrical energy at cheaper rates than conventional one, using bio fuel the derived from biomass.

The Effect of Tyrosine Kinase Inhibitors on the L-type Calcium Current in Rat Basilar Smooth Muscle Cells

  • Bai, Guang-Yi;Yang, Tae-Ki;Gwak, Yong-Geun;Kim, Chul-Jin
    • Journal of Korean Neurosurgical Society
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    • v.39 no.3
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    • pp.215-220
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    • 2006
  • Objective : Tyrosine kinase inhibitors may be useful in the management of cerebral vasospasm. It has not yet been reported whether L-type $Ca^{2+}$ channels playa role in tyrosine kinase inhibitors-induced vascular relaxation of cerebral artery. This study was undertaken to clarify the role of L-type $Ca^{2+}$ channels in tyrosine kinase inhibitors-induced vascular relaxation, and to investigate the effect of tyrosine kinase inhibitors on L-type $Ca^{2+}$ channels currents in freshly isolated smooth muscle cells from rat basilar artery. Methods : The isolation of rat basilar smooth muscle cells was performed by special techniques. The whole cell currents were recorded by whole cell patch clamp technique in freshly isolated smooth muscle cells from rat basilar artery. Results : Patch clamp studies revealed a whole-cell current which resembles the L-type $Ca^{2+}$ current reported by others. The amplitude of this current was decreased by nimodipine and increased by Bay K 8644. Genistein[n=5], tyrphostin A-23[n=3]. A-25[n=6] $30{\mu}M$ reduced the amplitude of the L -type $Ca^{2+}$ channel current in whole cell mode. In contrast, diadzein $30{\mu}M$ [n=3]. inactive analogue of genistein, did not decrease the amplitude of the L-type $Ca^{2+}$ channels current. Conclusion : These results suggest that tyrosine kinase inhibitors such as genistein, tyrphostin A-23, A-25 may relax cerebral vessel through decreasing level of intracellular calcium, [$Ca^{2+}$]i, by inhibition of L-type $Ca^{2+}$ channel.

Current Technologies and Related Issues for Mushroom Transformation

  • Kim, Sinil;Ha, Byeong-Suk;Ro, Hyeon-Su
    • Mycobiology
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    • v.43 no.1
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    • pp.1-8
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    • 2015
  • Mushroom transformation requires a series of experimental steps, including generation of host strains with a desirable selective marker, design of vector DNA, removal of host cell wall, introduction of foreign DNA across the cell membrane, and integration into host genomic DNA or maintenance of an autonomous vector DNA inside the host cell. This review introduces limitations and obstacles related to transformation technologies along with possible solutions. Current methods for cell wall removal and cell membrane permeabilization are summarized together with details of two popular technologies, Agrobacterium tumefaciens-mediated transformation and restriction enzyme-mediated integration.

proposals for enhancing the current HS-DSCH serving cell change procedure for UE mobility (향상된 HS-DSCH serving cell change procedure 제안)

  • Cheong, Young-Hoon
    • Proceedings of the IEEK Conference
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    • 2008.06a
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    • pp.273-274
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    • 2008
  • According to current RRC procedures, network does not know either how long it will take the RRC reconfiguration message (such as Physical Channel Reconfiguration (PCR)/Transport Channel Reconfiguration (TCR)/Radio Bearer Reconfiguration (RBR)) to be transmitted over the source cell or how long the UE will take to reconfigure on receiving the message, it has to assume the worst-case. Thus, it typically indicates a conservative activation time, leading to potentially large interruption for voice traffic, particularly if the source cell signal strength has degraded. This proposals allow the UE to receive the serving cell related information (carried today in PCR/RBR/TCR message) in an Active Set Update message.

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A Noval High Efficiency Grid Connected 1kW PCS for Fuel Cell (새로운 고효율 계통연계 1kW 연료전지용 PCS)

  • Kim, Tae-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.5
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    • pp.417-422
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    • 2008
  • In this paper, a novel DC/DC low-voltage high-current converter circuit is proposed to improve the efficiency of power converter used in the grid-connected fuel-cell generator system. We proposed a novel high efficiency grid-connected power conditioning system for RPG fuel cell. On the result of that, the loss of system was decreased rapidly by driving stack within the condition of maximum efficiency. The peak currents of the current-type inductor and the transformer's coil are reduced by synchronizing switching frequency of Buck-type converter is increased twice as the Push-Pull converter's switching frequency. The novel structure of DC/DC converter is able to realize ZVS-ZCS in fuel-cell system is proposed. The proposed switching component of Push-Pull converter has the ZVS and ZCS function by using the circuit of new passive clamp.

Electrical Characteristics for the Cu/Zn Chemical Cell using NaCl Electrolytes (NaCl 전해질을 사용한 Cu/Zn 화학전지의 전기적 특성)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.7
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    • pp.1259-1264
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    • 2010
  • This paper was researched about effectiveness of the electrochemical cell which is composed of the sea water and the Cu/Zn electrode. The electric potential difference between copper and zinc finally reached 0.51 volts. Short current decreased with time. It might depend on the electromotive force decreasing. Confirmed the load resistance and electrode affect in electromotive force and electric current. The resistance which shows a maximum output power was 20[$\Omega$], and the maximum output power from this resistance was evaluated as 0.736mW. In order to calculate the energy which creates from electrochemical cell, charging voltage of the capacitor with various capacitance was investigated. It was found that energy harvesting possibility of the cell which is made of a sea water electrolyte and the copper/the zinc.

Boost Converter for High Performance Operating of Fuel Cell System (연료전지 시스템의 고효율운전을 위한 6상 BOOST CONVERTER)

  • Park, S.S.;Yoon, H.J.;Goo, T.H.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.867-869
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    • 1993
  • In generally Boost Converter is used for Fuel Cell System. Because the output voltage of fuel cell is too small and greatly depends on the load condition, Boost Converter are required to boost and regulate the Fuel Cell voltage for per conversion efficiency. In this Paper, 6-phase Boost Converter is used to boost the Fuel Cell Voltage and regulate the output voltage. Multi phase converter hag some advantages such as low ripple and filter sine. About the Peak Current Control and compare of the Ripple Current of Boost Converter, we have studied.

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Plating of Permalloy Using Flow Cell

  • Jeon, S.H.;Ahn, J.H.;Kang, T.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.423-427
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    • 1999
  • Electroplating of 80%Ni permalloy thin plate for magnetic core materials. was studied The convected flow of electrolyte was used for stirring methode. The current density could be increased up to 250mA/$\textrm{cm}^2$ by flow cell. The composition of electroplated layer with vespect to current density and flow rate was investigated and experimental equation to predict the composition was made. How cell yielded more uniform thickness distribution than paddle cell did. The composition distribution was also studied. The thickness was the most important factor to the permeability. The permeability of 5$\mu\textrm{m}$plated permalloy was over 2000 at 1 MHz.

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Study of changes in the kinetic parameters of corrosion on the macrocell current induced by the repair of reinforced concrete structures - Results of numerical simulation

  • Mostafa Haghtalab;Vahed Ghiasi;Aliakbar Shirzadi Javid
    • Computers and Concrete
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    • v.32 no.3
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    • pp.287-302
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    • 2023
  • Corrosion of reinforcing bars in reinforced concrete structures due to chloride attack in environments containing chloride ions is one of the most important factors in the destruction of concrete structures. According to the abundant reports that the corrosion rate around the repair area has increased due to the macro-cell current known as the incipient anode, it is necessary to understand the effective parameters. The main objective of this paper is to investigate the effect of the kinetic parameters of corrosion including the cathodic Tafel slope, exchange current density, and equilibrium potential in repair materials on the total corrosion rate and maximum corrosion rate in the patch repair system. With the numerical simulation of the patch repair system and concerning the effect of parameters such as electromotive force (substrate concrete activity level), length of repair area, and resistivity of substrate and repair concrete, and with constant other parameters, the sensitivity of the macro-cell current caused by changes in the kinetic parameters of corrosion of the repairing materials has been investigated. The results show that the maximum effect on the macro-cell current values occurred with the change of cathodic Tafel slope, and the effect change of exchange current density and the equilibrium potential is almost the same. In the low repair extant and low resistivity of the repairing materials, with the increase in the electromotive force (degree of substrate concrete activity) of the patch repair system, the sensitivity of the total corrosion current reduces with the reduction in the cathode Tafel slope. The overall corrosion current will be very sensitive to changes in the kinetic parameters of corrosion. The change in the cathodic Tafel slope from 0.16 to 0.12 V/dec and in 300 mV the electromotive force will translate into an increase of 200% of the total corrosion current. While the percentage of this change in currency density and equilibrium potential is 53 and 43 percent, respectively. Moreover, by increasing the electro-motive force, the sensitivity of the total corrosion current decreases or becomes constant. The maximum corrosion does not change significantly based on the modification of the corrosion kinetic parameters and the modification will not affect the maximum corrosion in the repair system. Given that the macro-cell current in addition to the repair geometry is influenced by the sections of reactions of cathodic, anodic, and ohmic drop in repair and base concrete materials, in different parameters depending on the dominance of each section, the sensitivity of the total current and maximum corrosion in each scenario will be different.