• Title/Summary/Keyword: Carrier concentrations

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Extraction of Short Peptide Using Supported Liquid Membranes (Supported Liquid Membrane을 이용한 Short Peptide의 추출)

  • Lee, Jae-Heung;Park, Ki-Moon
    • Food Science of Animal Resources
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    • v.25 no.3
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    • pp.340-343
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    • 2005
  • The objective of this work was to study separation of short peptide (glycine-tyrosine) by using supported liquid membranes (SLMs) containing Aliquat as a cationic carrier, In the present investigation, the influence of pH of donor phase, concentrations of carrier and salt concentrations of acceptor phase on separation flux rate were investigated. Below pH 7.0 the flux rate was not affected by NaCl concentration or carrier concentration. However, the rate was increased significantly above pH 7.0. The rate with Hossain's SLM(H-SLM) containing $20\%$ Aliquat was about 3-fold higher with pH 9.0 at 0.25 M NaCl and 10-fold higher with pH 8.0 at 1.0 M NaCl than that with Duggan's SLM(D-SLM) containing $8\%$ Aliquat respectively. Furthermore, the rate with H-SLM was 10-fold higher at 1.0 M NaCl than the rate with 0.25 M NaCl, In conclusion, it would appear that the rate of separation was facilitated by using high salt concentrations together with high carrier concentrations above pH 7.0.

Facilitated Transport of Oxygen in Copolymer Membranes of Styrene and 4-Vinylpyridine Containing Cobalt Schist Base Carrier : Effect of Membrane Thickness and Carrier Concentration

  • Hong, Jae-Min;Kang, Yong-Soo
    • Macromolecular Research
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    • v.8 no.1
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    • pp.1-5
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    • 2000
  • The valiclity of the simple mathematical model for facilitated transport in a solid state membrane developed previously has been examined againsts the carrier concentration and membrane thick-ness. Membranes are prepared with copolymer of styrene and 4-vinylpyridine as a matrix and Co(salen) as a carrier. 4-Vinylpyridine is incorporated to provide the coordination site for Co(salen) carrier. Oxygen permeability through the facilitated transport membrane is linearly increased with the square of its thick-ness, as predicted by the mathematical model. However, the oxygen permeability does not increase linearly with the carrier concentration. This seems to be due to the deactivation of the carrier by dimerization at high carrier concentrations as well as the reduced chain mobility by coordination of bulky Co(salen) carrier.

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Effects $H_2$ carrier gas on the mechanical properties of poly 3C-SiC thin films ($H_2$ 캐리어가스가 다결정 3C-SiC 박막의 기계적 특성에 미치는 영향)

  • Han, Ki-Bong;Chung, Gwiy-Sang;Hong, Hoang Sy
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.89-90
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    • 2007
  • This paper presents the mechanical properties of 3C-SiC thin film according to 0, 7, and 10% carrier gas $(H_2)$ concentrations using Nano Indentation. When carrier gas $(H_2)$ concentration was 10%, it has been proved that the mechanical properties, elastic modulus and hardness, of 3C-SiC are the best of them. In the case of 10% carrier gas concentration, Young's modulus and Hardness were obtained as 367 GPa and 36 GPa, respectively. When the surface roughness according to $H_2$ concentrations was investigated by AFM (atomic force microscope), when $H_2$ concentration was 10%, the roughness of 3C-SiC thin was 9.92 nm, which is also the best of them. Therefore, in order to apply poly 3C-SiC thin film to MEMS applications, $H_2$ concentration's rate should increase to obtain better mechanical properties and surface roughness.

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Carrier Dyeing of Polyester Fabrics in Alkaline Dyebath (폴리에스테르직물의 알칼리욕에서의 Carrier염색)

  • 조은자;남성우;김인회
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.381-390
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    • 2001
  • The optimum carrier concentrations were obtained by the maxmium exhaustion ratios of polyester fabrics at 8$0^{\circ}C$ . The optimum concentrations of methylsalicylate, acetophenone, anisole, propiophenone, 2-ethyl hexyl alcohol, ethylene glycol and propylene glycol were $3g/\ell,\;12g/\ell,\;7g/\ell,\;5g/\ell,\;3g/\ell,\;35g/\ell,\;and\;40g/\ell$, respectively Azo, anthraquinone, and quinoline disperse dyes were quite stable up to PH 10.3, but nitro disperse dye were severely hydrolyzed in alkaline dyeing. The tensile strength decreased with increasing dyebath pH because the polyester fabrics were easily decomposed by alkali. The reduction cleaning could be canceled in alkaline dyeing because the carriers were solved by alkali during dyeing.

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Carrier Dyeing of Polyester Fabrics in Alkaline Dyebath (폴리에스테르직물의 알칼리욕에서의 Carrier염색)

  • Jo, Eun Ja;Nam, Seong U;Kim, In Hoe
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.23-23
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    • 2001
  • The optimum carrier concentrations were obtained by the maxmium exhaustion ratios of polyester fabrics at 80℃. The optimum concentrations of methylsalicylate, acetophenone, anisole, propiophenone, 2-ethyl hexyl alcohol, ethylene glycol and propylene glycol were 3g/ℓ, 12g/ℓ, 7g/ℓ, 5g/ℓ, 3g/ℓ, 35g/ℓ, and 40g/ℓ, respectively. Azo, anthraquinone, and quinoline disperse dyes were quite stable up to pH 10.3, but nitro disperse dye were severely hydrolyzed in alkaline dyeing. The tensile strength decreased with increasing dyebath pH because the polyester fabrics were easily decomposed by alkali. The reduction cleaning could be canceled in alkaline dyeing because the carriers were solved by alkali during dyeing.

Separation of Chromium(VI) Ion in Industrial Waste Water throunh Liquid Surfactant Membrane (산업폐수중 유화액막에 의한 크롬(VI)의 분리)

  • 초민승;강안수;우인성;이영순
    • Journal of the Korean Society of Safety
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    • v.4 no.1
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    • pp.15-24
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    • 1989
  • The transport of Chromium(Vl) ion from waste water throughl the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid parafnn oil were analyzed. Extraction euperiments were carried out to observe the effect of system variables, such as stirring speed, concentration of carrier, and NaOH in internal aqueous phase, and concentrations of H$_2$SO$_4$and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt. % and liquid parafnn oil concentration is 50 vol. %. The transport of chromium(VI) ion in bacth extractor increased with increasing carrier concentration, the volume ratio of emulsion to external aqueous phases, and initial concentration of chromium(VI) ion under the optimum stirring speed of chromium(VI) ion below 2 ppm. The theoretical equation on the transport of chromium(Vl) ion agreed well with the experimental results.

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Biological Treatment of Nutrients and Heavy Metals in Synthetic Wastewater Using a Carrier Attached to Rhodobacter blasticus

  • Kim, Deok-Won;Park, Ji-Su;Oh, Eun-Ji;Yoo, Jin;Kim, Deok-Hyeon;Chung, Keun-Yook
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.666-674
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    • 2022
  • The removal efficiencies of nutrients (N and P) and heavy metals (Cu and Ni) by Rhodobacter blasticus and R. blasticus attached to polysulfone carriers, alginate carriers, PVA carriers, and PVA + zeolite carriers in synthetic wastewater were compared. In the comparison of the nutrient removal efficiency based on varying concentrations (100, 200, 500, and 1000 mg/L), R. blasticus + polysulfone carrier treatment showed removal efficiencies of 98.9~99.84% for N and 96.92~99.21% for P. The R. blasticus + alginate carrier treatment showed removal efficiencies of 88.04~97.1% for N and 90.33~97.13% for P. The R. blasticus + PVA carrier treatment showed removal efficiencies of 18.53~44.25% for N and 14.93~43.63% for P. The R. blasticus + PVA + zeolite carrier treatment showed removal efficiencies of 26.65~64.33% for N and 23.44~64.05% for P. In addition, at the minimum inhibitory concentration of heavy metals, R. blasticus (dead cells) + polysulfone carrier treatment showed removal efficiencies of 7.77% for Cu and 12.19% for Ni. Rhodobacter blasticus (dead cells) + alginate carrier treatment showed removal efficiencies of 25.83% for Cu and 31.12% for Ni.

Tansport Rate of Chromium ion from Waste Water through the Liquid Surfactant Membrane Containing Carrier (운반체 함침 유화액막에 의한 폐수중 크롬(VI)의 이동속도)

  • Woo, In-Sung;Kim, Kyoung-Ho;Lee, Sang-Jin;Kang, An-Soo;Choi, Sei-Young
    • Elastomers and Composites
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    • v.23 no.1
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    • pp.11-17
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    • 1988
  • The transport of chromium(VI) ion from waste water through the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid paraffin oil were analyzed. Extraction experiments were carried out to observe the effect of system variables, such as concentrations of carrier, and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt.% and liquid paraffin oil concentration is 50 vol.%. The theoretical equation on the transport of chromium(VI) ion agreed well with the experimental results.

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Charge-Carrier Transport Properties and Fluorescence Behaviors Depending on Charge Transport Complex of Organic Photoconductor Containing Liquid Crystal (액정을 함유하는 유기 광도점체의 전하 수송착체에 의한 Charge-Carrier수송 특성과 형광거동)

  • Lee, Bong; Jung, Sung-Young;Moon, Doo-Dyung
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.719-727
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    • 2001
  • Recently it was found that the charge carrier transport properties are significantly enhanced due to effective intermolecular $\pi$-orbital overlapping and low disorder of hopping sites caused by self-organization of liquid crystal molecules. In this study, the xerographic properties of a double-layer photoconductor doped with nematic liquid crystal, 4-pentyl-4'-cyanoterphenyl (5CT), as a charge-carrier transport material to enhance the charge-tarrier mobility were investigated. From the results of measured surface voltage properties for the photoconductor doped with various concentrations of liquid crystal, 5CT, the initial voltage was found to increase with the concentration of 5CT and the dark decay decreased with the concentration of 5CT. The highest sensitivity was obtained at a specific concentration, 40wt% 5CT. The fluorescence behavior of the carrier transport layer (CTL) was also investigated. It was found that the charge-carrier transport properties of the organic photoconductor depend on the charge-carrier transport properties of the complex. The TNF : 5CT (40 wt%) and OXD : 5CT (40 wt%)samples showed the highest sensitivity because the greatest charge transport complex was termed between the charge-carrier transport materials in these samples.

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Characterization of Ultrathin Gate Dielectrics for Nanoscale CMOS Applications

  • Yoon, Gi-Wan;Mai, Linh;Lee, Jae-Young
    • Journal of information and communication convergence engineering
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    • v.5 no.2
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    • pp.109-111
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    • 2007
  • In this paper, MOS devices with ultrathin gate dielectrics (5.5 nm) are characterized and compared with those with conventional oxides particularly for nanoscale CMOS applications. Nitrogen concentrations and profiles in the nitride gate dielectrics were obtained that will play an important role in improving both hot-carrier lifetime and resistance to boron penetration. This approach seems very useful for future nanoscale CMOS device applications.