• Title/Summary/Keyword: Carbon ratio

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Optimized Mixing Design of Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar by Response Surface Analysis (반응표면분석법에 의한 탄소포집 활성 고로슬래그 모르타르의 최적배합 도출에 관한 연구)

  • Jang, Bong Jin;Park, Cheol woo;Kim, Seung Won;Ju, Min Kwan;Park, Ki Tae;Lee, Sang Yoon
    • International Journal of Highway Engineering
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    • v.15 no.6
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    • pp.69-78
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    • 2013
  • PURPOSES : In this study blast furnace slag, an industrial byproduct, was used with an activating chemicals, $Ca(OH)_2$ and $Na_2SiO_3$ for carbon capture and sequestration as well as strength development. METHODS : This paper presents the optimized mixing design of Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar. Design of experiments in order to the optimized mixing design was applied and commercial program (MINITAB) was used. Statistical analysis was used to Box-Behnken (B-B) method in response surface analysis. RESULTS : The influencing factors of experimental are water ratio, Chemical admixture ratio and Curing temperature. In the results of response surface analysis, to obtain goal performance, the optimized mixing design for Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar were water ratio 40%, Chemical admixture ratio 58.78% and Curing temperature of $60^{\circ}C$. CONCLUSIONS : Compared with previous studies of this experiment is to some extent the optimal combination is expected to be reliable.

Influence of carbon type and carbon to nitrogen ratio on the biochemical methane potential, pH, and ammonia nitrogen in anaerobic digestion

  • Choi, Yongjun;Ryu, Jeongwon;Lee, Sang Rak
    • Journal of Animal Science and Technology
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    • v.62 no.1
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    • pp.74-83
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    • 2020
  • Organic waste used as a feedstock in the anaerobic digestion (AD), it includes carbon and nitrogen. Carbon and nitrogen have an effect on the various digestive characteristics during AD, however, the study is rare about those of the interaction. This study investigates the influence of carbon type and carbon to nitrogens (C/N ratios) on the AD characteristics of organic waste. Experimental treatments involved a combination of three carbon types with three C/N ratios. The AD tests were carried out using a 125-mL serum bottle at a constant temperature of 37℃ and moisture 95% for 18 days. Degradation pattern shows the difference among three-carbon treatments, the starch group was faster than other groups. Maximum methane production date was similar between starch (9.96 ± 0.05 day) and xylan group (10.0 ± 0.52 day), those of the cellulose group (14.6 ± 1.80 day) was slower than other groups (p < 0.05). The lag phase was only affected by the carbon type (p < 0.05). Ammonia nitrogen was mainly affected by nitrogen concentration regardless of carbon type (p < 0.05). This study showed that xylan is useful as feedstock in order to decrease the lag phase, and it showed that ammonia was independently affected by the nitrogen concentration.

Estimation of Aboveground Biomass Carbon Stock Using Landsat TM and Ratio Images - $k$NN algorithm and Regression Model Priority (Landsat TM 위성영상과 비율영상을 적용한 지상부 탄소 저장량 추정 - $k$NN 알고리즘 및 회귀 모델을 중점적으로)

  • Yoo, Su-Hong;Heo, Joon;Jung, Jae-Hoon;Han, Soo-Hee;Kim, Kyoung-Min
    • Journal of Korean Society for Geospatial Information Science
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    • v.19 no.2
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    • pp.39-48
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    • 2011
  • Global warming causes the climate change and makes severe damage to ecosystem and civilization Carbon dioxide greatly contributes to global warming, thus many studies have been conducted to estimate the forest biomass carbon stock as an important carbon storage. However, more studies are required for the selection and use of technique and remotely sensed data suitable for the carbon stock estimation in Korea In this study, the aboveground forest biomass carbon stocks of Danyang-Gun in South Korea was estimated using $k$NN($k$-Nearest Neighbor) algorithm and regression model, then the results were compared. The Landsat TM and 5th NFI(National Forest Inventory) data were prepared, and ratio images, which are effective in topographic effect correction and distinction of forest biomass, were also used. Consequently, it was found that $k$NN algorithm was better than regression model to estimate the forest carbon stocks in Danyang-Gun, and there was no significant improvement in terms of accuracy for the use of ratio images.

Optimization of compression ratio in closed-loop CO2 liquefaction process

  • Park, Taekyoon;Kwak, Hyungyeol;Kim, Yeonsoo;Lee, Jong Min
    • Korean Journal of Chemical Engineering
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    • v.35 no.11
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    • pp.2150-2156
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    • 2018
  • We suggest a systematic method for obtaining the optimal compression ratio in the multi-stage closed-loop compression process of carbon dioxide. Instead of adopting the compression ratio of 3 to 4 by convention, we propose a novel approach based on mathematical analysis and simulation. The mathematical analysis prescribes that the geometric mean is a better initial value than the existing empirical value in identifying the optimal compression ratio. In addition, the optimization problem considers the initial installation cost as well as the energy required for the operation. We find that it is best to use the fifth stage in the general closed-loop type carbon dioxide multi-stage compression process.

Correlation between frequency and Poisson's ratio: Study of durability of armchair SWCNTs

  • Muzamal Hussain;Mohamed A. Khadimallah;Abdelouahed Tounsi
    • Computers and Concrete
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    • v.32 no.3
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    • pp.303-311
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    • 2023
  • An analysis of the Poisson's ratios influence of single walled carbon nanotubes (SWCNTs) based on Sander's shell theory is carried out. The effect of Poisson's ratio, boundary conditions and different armchairs SWCNTs is discussed and studied. The Galerkin's method is applied to get the eigen values in matrix form. The obtained results shows that, the decrease in ratios of Poisson, the frequency increases. Poisson's ratio directly measures the deformation in the material. A high Poisson's ratio denotes that the material exhibits large elastic deformation. Due to these deformation frequencies of carbon nanotubes increases. The frequency value increases with the increase of indices of single walled carbon nanotubes. The prescribe boundary conditions used are simply supported and clamped simply supported. The Timoshenko beam model is used to compare the results. The present method should serve as bench mark results for agreeing the results of other models, with slightly different value of the natural frequencies.

Preparation and Characterization of Lignin/Chlorinated Polyvinyl Chloride Blended Fibers for Low-cost Carbon Fiber (저가 탄소섬유용 Lignin/Chlorinated Polyvinyl Chloride 블렌딩 섬유의 제조 및 특성)

  • Jo, Chaehyun;Lee, Sangoh;Kang, Dakyung;Hong, Seonghwa;Kang, Chankyu;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.32 no.2
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    • pp.111-120
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    • 2020
  • In this study, lignin/chlorinated poly(vinyl chloride)(CPVC) blended fibers have been produced for the development of low-cost carbon fiber. Carbon fiber manufacturing was accomplished through stabilization and carbonization process. The lignin/CPVC blended fibers were prepared by wet spinning method. Dimethylacetamid e(DMAc) and cychlohexanone in a ratio of 5:1(wt%) was employed as co-solvent. The ratio of lignin/CPVC was prepared at 0/10, 1/9, 2/8, 3/7, 4/6, and 5/5(wt%). The spinning solution was extruded at a rate of 0.1 to 0.4ml/min according to the blending ratio. The speed of the rollers was the same for all ratios(draw ratio=1). Analysis of fiber cross-section by scanning eletron microscopy(SEM) showed that as the lignin ratio increased in the same coagulation bath and distilled water, the pore size of the spinning fiber decreased. Therefore, the highest tensile strength of the blending fibers was 6.3±1.2MPa at the 5/5 ratio. The carbon fiber also showed the best tensile strength of 120.78±2.43MPa at 5/5 ratio.

Influence of Filler Composition Ratio on Properties of Both Silica and Carbon Black-Filled Styrene-Butadiene Rubber Compounds (실리카와 카본블랙으로 보강된 SBR 고무 배합물의 특성에 보강제 조성비가 미치는 영향)

  • Choi, Sung-Seen
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.37-43
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    • 2001
  • Influence of the filler composition ratio on cure characteristics and bound rubber content of the compounds and on physical properties of the vulcanizates were studied using both silica and carbon black-filled styrene-butadiene rubber (SBR) compounds with the total filler content of 80.0 phr. The bound rubber content increased slightly with increase of the silica content ratio. The viscosity also increased with increasing the silica content ratio, especially increased steeply after the silica content of 60.0 phr. The cure times obtained with a rheometer, t2, t40, and t90, are increased by increasing the silica content ratio and the cure rate decreased. The delta torque increased with the increased silica content ratio. Variation or the modulus with the silica content ratio showed a decreased trend though the delta torque increased. The tan ${\delta}$ at $60^{\circ}C$ decreased with increased of the silica content ratio.

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Effects of Different Coal Type on Gasification Characteristics (Pilot 규모 석탄 가스화기에서의 탄종별 가스화성능 특성)

  • Park, Se-Ik;Lee, Joon-Won;Seo, Hea-Kyung
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.470-477
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    • 2010
  • The IGCC (Integrated gasification combined cycle) is known for one of the highest efficiency and the lowest emitting coal fueled power generating technologies. As the core technology of this system is the gasifier to make the efficiency and the continuous operation time increase, the research about different coal's gasification has been conducted. Our research group had set-up the coal gasifier for the pilot test to study the effect of different coals-Shenhua and Adaro coal- on gasification characteristics. Gasification conditions like temperature and pressure were controlled at a fixed condition and coal feed rate was also controlled 30 kg/h to retain the constant experimental condition. Through this study we found effects of coal composition and $O_2$/coal ratio on the cold gas efficiency, carbon conversion rate. The compounds of coal like carbon and ash make the performance of gasifier change. And carbon conversion rate was decreased with reduced $O_2$/coal ratio. The optical $O_2$/coal ratio is 0.8 for the highest cold gas efficiency approximately. At those operating conditions, the higher coal has the C/H ratio, the lower syn-gas has the $H_2$/CO ratio.

The Influence of Carbonization Temperature and KOH Activation Ratio on the Microporosity of N-doped Activated Carbon Materials and Their Supercapacitive Behaviors

  • Son, Yeong-Rae;Heo, Young-Jung;Cho, Eun-A;Park, Soo-Jin
    • Composites Research
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    • v.31 no.5
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    • pp.267-275
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    • 2018
  • A facile method for the preparation of nitrogen-doped microporous carbon via the pyrolysis of poly(vinylidene fluoride) (PVDF) using polypyrrole (PPy) as a selective nitrogen source was developed. A PVDF/PPy-800 sample (carbonized at $800^{\circ}C$) with a 1:0.5 ratio of PVDF and PPy exhibited the highest micropore volume. The activated microporous carbon materials obtained from PVDF/PPy-800 prepared at $800^{\circ}C$ with KOH possessed a large specific surface area and narrow pore-size distribution. They were characterized using $N_2$ adsorption at 77 K and argon (Ar) adsorption at 87 K, which allowed for the characterization of the narrow microporosity of the prepared materials due to the absence of interactions between Ar and the sample surface. In addition, the activated microporous carbon material with a KOH/carbon ratio of 2:1 was found to exhibit the largest specific surface area ($1296m^2g^{-1}$ in $N_2$ at 77 K) and microporosity, and a high specific capacitance ($122.8F\;g^{-1}$).

Effect of Carbon Source on Porosity and Flexural Strength of Porous Self-Bonded Silicon Carbide Ceramics (탄소 원료가 다공질 Self-Bonded SiC (SBSC) 세라믹스의 기공율과 곡강도에 미치는 영향)

  • Lim, Kwang-Young;Kim, Young-Wook;Woo, Sang-Kuk;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.45 no.7
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    • pp.430-437
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    • 2008
  • Porous self-bonded silicon carbide (SBSC) ceramics were fabricated at temperatures ranging from 1700 to $1850^{\circ}C$ using SiC, silicon (Si), and three different carbon (C) sources, including carbon black, phenol resin, and xylene. The effects of the Si:C ratio and carbon source on porosity and strength were investigated as a function of sintering temperature. Porous SBSC ceramics fabricated from phenol resin showed higher porosity than the others. In contrast, porous SBSC ceramics fabricated from carbon black showed better strength than the others. Regardless of the carbon source, the porosity increased with decreasing the Si:C ratio whereas the strength increased with increasing the Si:C ratio.