• 제목/요약/키워드: Carbon flow

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총 유기탄소의 수문학적 플럭스와 총 일차생산량 사이의 관계분석 (Relationship between Hydrologic Flux of Total Organic Carbon and Gross Primary Production)

  • 박윤경;조선주;최대규;김상단
    • 한국습지학회지
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    • 제14권4호
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    • pp.503-518
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    • 2012
  • 지면에서 탄소수지를 모의하는 모형들은 주로 수직적인 탄소 플럭스에 주된 관심을 두어왔다. 반면에 수평 적인 탄소 플럭스에 관한 연구는 부족한 실정이다. 따라서 수평적인 탄소 플럭스의 흐름에 대해 연구하고자 유역 내 식생에 의해 생산되는 총 일차생산량(Gross primary production, GPP)과 유역에서 배출되는 총 유기탄소(Total Organic Carbon, TOC)의 교차상관분석을 실시하였다. 분석결과, GPP와 유역에서 배출되는 TOC의 유량가중 평균 농도는 서로 지체시간이 없을 경우에 가장 큰 상관관계를 보여주고 있음을 확인하였다. 또한 주기성이 고려된 상관구조를 살펴본 결과, 여름철의 TOC와 GPP 사이의 상관관계가 주기성이 고려되지 않았을 경우의 상관관계와 유사하게 나타났다. 이로부터 GPP와 TOC의 상관관계는 여름철에 맺어지는 GPP와 TOC 상관관계에 의해서 대부분이 규정되고 있음을 살펴볼 수 있었다. 이에 따라 식생에 의해 생산된 탄소와 유역에서 배출되는 유기탄소의 관계가 계절적으로도 긴밀한 관계가 있을 것이라 추측된다. 따라서 향후 연구는 계절에 따른 식생변수와 GPP와 TOC의 관계를 분석함으로서 조금 더 정량적으로 수평적인 탄소 플럭스 흐름에 대해 이해 할 수 있을 것으로 기대된다.

미분탄 입자들의 배열에 따른 연소특성 (Combustion Characteristics of Coal Particle Array)

  • 조종표;김호영;정진택
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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    • pp.117-123
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    • 2004
  • The burning characteristics of interacting coal particles in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged particles, both the fixed particle distances of 5 radii to 20 radii horizontally and 3 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis reveal that the transient flame configuration and retardation of particle temperature augmentation with the horizontal or vertical particle spacing substantially influence devolatilization process and carbon conversion ratio of interacting particles. Volatile release and carbon conversion ratio of the second particle with decreasing horizontal and vertical particle spacing decrease gradually, whereas those of the first particle with decreasing vertical particle spacing increases due to flow acceleration. When the vertical particle spacing is smaller than $6R_{o}$, volatile release and carbon conversion ratio of the second particle decrease greatly due to reduction of flame penetration depth.

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질소와 암모니아 분위기에서 알루미늄(III)의 호박산 및 아디프산 착물의 AlN으로의 변환 (Conversion of Succinate-and Adipate-Coordinated Al(III) Complexes to AlN in $N_2$ and $NH_3$ Atmospheres)

  • 안상경;오창우;정우식
    • 한국세라믹학회지
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    • 제33권4호
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    • pp.455-463
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    • 1996
  • Aluminium nitride (AlN) powder was prepared by using aluminium (III) complexes with dibasic carboxylate ligands(adipato)(hydroxo) aluminium(III) and (hydroxo)(succinato)aluminium (III) as a precursor. The AlN pow-der was obtained by calcining the complexes without mixing any carbon source under a flow of ammonia at 120$0^{\circ}C$ Contary to the conventional carbothermal reduction and nitridiation the process of decarboniza-tion of the residual carbon was not required because of the reaction of ammonia with carbon at temperature >100$0^{\circ}C$. Fine AlN powder was also prepared by calcining a mixture of an (adipato)(hydroxo)aluminium(III) complex and carbon under a flow of nitrogen at 140$0^{\circ}C$ The AlN powders prepared were ultrafine and their morphology was almost the same as that of powders of two precursors.

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Observation of carbon sedimentation effect and soot concentration in diesel engine after intake valve modification

  • ;조행묵
    • 에너지공학
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    • 제21권4호
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    • pp.378-384
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    • 2012
  • Higher compression ratio is required in diesel engine to ignite the fuel that leads to better efficiency. For complete combustion inside the cylinder it is important to ensure the clean air flow with free of debris and as cool as possible. In this manner, modification of intake valve arrangements is taken in to consideration importantly. In this paper, the intake valve arrangements are modified with newly designed valve mixer. It causes swirl flow of air through the intake port that mixing with the fuel followed by complete combustion. The use of valve mixer reduces the carbon sediment formation on valve fillet and its face area as the carbon particles gradually take place on it after certain running period. It therefore, helps to increase the valve lifetime. And at the same time it reduces the exhaust elements i.e. soot from the automobiles to a significant level.

기존 정수처리방법으로 제거가 어려운 유기물에 대한 실험적 연구 (Retrospect on Refractories in Water Treatment)

  • 우달식;남상호
    • 한국환경보건학회지
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    • 제21권4호
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    • pp.17-23
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    • 1995
  • As a basic experiment to develope biological pretreatment proces~ in water treatment, the experiments on biodegradability and isothermal adsorption of activated carbon were performed on refractories such as humic acid, $NH_3-N$, phenol and ABS which caused the problems in drinking water treatment. Also, the treatabilities on humic acid were examined in the continuous flow type reactors. The removal efficiencies of humic acid, $NH_3-N$, phenol and ABS in the biodegradable experiments for 5 days were 20.1%, 73.4%, 91.7% and 97.5%, respectively. In the isothermal adsorption test of refractories on activated carbon to be used as a media in the continuous flow type reactors, ABS and phenol are adsorbed easily, but humic acid and $NH_3-N$ are difficult to be done. The removal efficiencies of humic acid in granular activated carbon(GAC) reactor were about 7-8% higher than in biological activated carbon(BAC) reactor. The removal efficiencies of humic acid in biological fluidized bed(BFB) reactor were about 30% in GAC media, but were almost zero in sea sand media.

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RE-PECVD법에 의해 증착된 DLC박막의 결합 특성 (Bonding structure of the DLC films deposited by RE-PECVD)

  • 최봉근;신재혁;안종일;심광보
    • 한국결정성장학회지
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    • 제14권1호
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    • pp.27-32
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    • 2004
  • RF-PECVD 방법을 이용하여 DLC(diamond-like carbon)박막을 메탄-수소 가스 혼합비 및 바이어스 전압에 따라 실리콘 웨이퍼 위에 증착하였다. DLC 박막의 결합구조적 특성 및 기계적 성질은 FT-IR, Raman, 그리고 nano-indenter를 이용하여 평가하였다. 혼합가스내 메탄의 유량과 바이어스 전압이 증가함에 따라 증착속도가 증가하였다. 박막내 탄소의 $sp^3/sp^2$ 결합비와 경도는 반응가스내 수소의 유량 및 바이어스 전압이 증가함에 따라 증가하였다.

Constitutive Relation of Alloy Steels at High Temperatures

  • Lee, Young-Seog
    • International Journal of Precision Engineering and Manufacturing
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    • 제6권4호
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    • pp.55-59
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    • 2005
  • This paper presents a feasibility study whether Shida's constitutive equation being widely used for plain carbon steel in steel manufacturing industry can be extended to alloy steels with a due carbon equivalent model. T,he constitutive relation of the alloy steels (SAE9254, AISI52100 and AISI4140) is measured using hot deformation simulator (GLEEBLE 3500C) at high temperatures ($800^{\circ}C{\~}1000^{\circ}C$) within strain rates of $0.05{\~}40\;s^{-1}$. It has been found the predicted flow stress behavior (constitutive relation) of AISI52100 steel is in agreement with the measured one. On the other hand, the measured flow stress behavior of SAE9254 and AISI4140 steel partly concords with the predicted one when material experiences relatively high strain rate ($10{\~}40\;s^{-1}$) deformation at low temperature ($800^{\circ}C$). It can be deduced that, for AISI52100 steel, Shida's equation with the carbon equivalent model can be applicable directly to the roughing and intermediate finishing stand in hot rolling process for calculating the roll force and torque.

Regeneration of Spent Carbon by a Novel Oxidative Thermal Process

  • 류건상;Shybender Kapila
    • Bulletin of the Korean Chemical Society
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    • 제18권8호
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    • pp.811-814
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    • 1997
  • An oxidative thermal regeneration process was developed and evaluated for its potential applicability in several environmental areas. The feasibility of the process is affected strongly by the gradual carbon loss, energy consumption, physical changes of carbon, and effective destruction efficiency of adsorbed materials during the regeneration. The aim of the study is to determine the optimum conditions to maintain acceptable destruction efficiency for adsorbed organics, controlling oxidant flow rate. Prior to its applications, various preliminary tests were carried out to determine the effects of experimental parameters on the process. The tests performed were reaction temperature, carbon loss, surface area, surface structure, and adsorptive property. The results of these tests show that the parameters are dependent on oxidant flow rate, and suggest that the process is comparable and, in some ways, possibly superior to conventional regeneration techniques because the oxidative process is a single step and less energy intensive.

Thin CNTs nanoliquid film development over a rough rotating disk

  • Swatilekha Nag;Susanta Maity;Sanjeev K. Metya
    • Advances in nano research
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    • 제15권2호
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    • pp.91-104
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    • 2023
  • Development of thin carbon nanotubes (CNTs) nanoliquid film over the rough surface of a horizontal rotating disk is investigated by considering symmetric roughness either along the azimuthal or radial directions. The disk surface is either heated or cooled axisymmetrically from below. The effects of single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNTs) are analyzed on the film thinning process with different types of base liquids. Closed form solutions for velocity and temperature field are obtained for small values of Reynolds number whereas the numerical solution is derived for moderate values of Reynolds number. It is found that fluid retention / depletion takes place when the roughness is symmetric along the azimuthal / radial directions. It is also seen that the film thinning rate enhances for MWCNTs compare to SWCNTs. Further it is found that two different heat transfer regions exits within the flow domain depending on the fact that heat is transferred from disk to liquid film and vice-versa.

Batch and Flow-Through Column Studies for Cr(VI) Sorption to Activated Carbon Fiber

  • Lee, In;Park, Jeong-Ann;Kang, Jin-Kyu;Kim, Jae-Hyun;Son, Jeong-Woo;Yi, In-Geol;Kim, Song-Bae
    • Environmental Engineering Research
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    • 제19권2호
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    • pp.157-163
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    • 2014
  • The adsorption of Cr(VI) from aqueous solutions to activated carbon fiber (ACF) was investigated using both batch and flow-through column experiments. The batch experiments (adsorbent dose, 10 g/L; initial Cr(VI) concentration, 5-500 mg/L) showed that the maximum adsorption capacity of Cr(VI) to ACF was determined to 20.54 mg/g. The adsorption of Cr(VI) to ACF was sensitive to solution pH, decreasing from 9.09 to 0.66 mg/g with increasing pH from 2.6 to 9.9; the adsorption capacity was the highest at the highly acidic solution pHs. Kinetic model analysis showed that the Elovich model was the most suitable for describing the kinetic data among three (pseudo-first-order, pseudo-second-order, and Elovich) models. From the nonlinear regression analysis, the Elovich model parameter values were determined to be ${\alpha}$ = 162.65 mg/g/h and ${\beta}$ = 2.10 g/mg. Equilibrium isotherm model analysis demonstrated that among three (Langmuir, Freundlich, Redlich-Peterson) models, both Freundlich and Redlich-Peterson models were suitable for describing the equilibrium data. In the model analysis, the Redlich-Peterson model fit was superimposed on the Freundlich fit. The Freundlich model parameter values were determined to be $K_F$ = 0.52 L/g and 1/n = 0.56. The flow-through column experiments showed that the adsorption capacities of ACF in the given experimental conditions (column length, 10 cm; inner diameter, 1.5 cm; flow rate, 0.5 and 1.0 mL/min; influent Cr(VI) concentration, 10 mg/L) were in the range of 2.35-4.20 mg/g. This study demonstrated that activated carbon fiber was effective for the removal of Cr(VI) from aqueous solutions.