• Korean Journal of Metals and Materials
• /
• v.50 no.6
• /
• pp.433-438
• /
• 2012

Strength change in ultra low carbon steel carburized at $880^{\circ}C$ and $930^{\circ}C$ for 10, 30, 60 and 120 minutes was investigated. The results were analyzed by a tensile test, chemical composition analysis, optical microscopy and scanning electron microscopy. Stress in the 0.5% strain specimen in the tensile test increased as the time treated at $880^{\circ}C$ and $930^{\circ}C$ increased, because the carbon diffusion layer and the martensite of the specimen increased with increasing treatment time. Martensite was found in the ferrite region in the specimen treated at $880^{\circ}C$, which is attributed to grain boundary diffusion.

• Journal of Industrial and Engineering Chemistry
• /
• v.68
• /
• pp.146-152
• /
• 2018

Due to their excellent mechanical durability and high electrical conductivity, carbon and silicon composites are potentially suitable anode materials for Li-ion batteries with high capacity and long lifespan. Nevertheless, the limitations of the composites include their poor ionic diffusion at high current densities during cycling, which leads to low ultrafast performance. In the present study, seeking to improve the ionic diffusion using hydrothermal method, electrospinning, and carbonization, we demonstrate the unique design of excavated carbon and silicon composites (EC/Si). The outstanding energy storage performance of EC/Si electrode provides a discharge specific capacity, impressive rate performance, and ultrafast cycling stability.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 1999.11a
• /
• pp.32-35
• /
• 1999

Poly(arylene ether phosphin oxide) (PEPO), Udel$^{\circledR}$ P-1700, Ultem$^{\circledR}$ 1000. poly(hydroxy ether) (PHE), carboxy modified poly(hydroxy ether)(C-PHE) and poly(hydroxy ether ethanol amine) (PHEA) were utilized for a coating of carbon fibers. Interfacial shear strength(IFSS) of polymers to carbon fibers was also evaluated in order to understand the adhesion mechanism. IFSS was measured via micro-droplet tests, and failure surfaces were analyzed by SEM. Diffusion between polymer and vinyl ester resin was investigated as a function of styrene content; 33. 40 or 50wt.% and the solubility parameters of polymers were calculated. The results were correlated to the interfacial shear strength. The highly enhanced interfacial shear strength (IFSS) was obtained with PEPO coating, and marginally improved IFSS with PHE, Udel$^{\circledR}$ and C-PHE coatings, but no improvement with PHEA and Ultem$^{\circledR}$ coatings.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.27 no.10
• /
• pp.1480-1488
• /
• 2003

Synthesis of carbon nanomaterials on a substrate coated with metal nitrates using an ethylene fueled inverse diffusion flame was illustrated. The effects of radial distance, residence time of the substrate, and hydrocarbon composition on the synthesis of carbon nanomaterials were investigated. The effects of catalyst metal particles were also studied using SUS304 substrates coated with Fe(NO$_3$)$_3$ (ferric nitrate, nonahydrate) and Ni(NO$_3$)$_2$(nickel nitrate, hexahydrate), and Cu substrate. Carbon nanomaterials, with diameters ranging from 30 - 70 nm, were observed on the substrate for both cases of using substrates only and using them with metal nitrates. In case of using the substrate with metal nitrates, the formation and growth of carbon nanomaterials were occurred in the lower temperature region than that of using the substrates only due to the easy activation of the metal particles coated on the surface of the substrates.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.28 no.9
• /
• pp.1081-1092
• /
• 2004

The synthesis of Ni-catalyzed multi-walled carbon nanotubes and nanofibers on a catalytic metal substrate, using an ethylene fueled inverse diffusion flame as a heat source, was investigated. When the gas temperature was varied from 1,400K to 900K, approximately, carbon nanotubes with diameters of 20∼60nm were formed on the substrate. In the regions where the gas temperature was higher than 1,400K or lower than 900K, iron nanorods or carbon nanofibers were synthesized, respectively. Based on the quantitative analyses of large amount of SEM and TEM images, the nanotubes formed closer to the flame had a tendency of having larger diameters. HR-TEM images and Raman spectra revealed that carbon nanotubes synthesized had multi-walled structures with some defective graphite layers at the wall. Based on the graphite mode of the Raman spectra, it was believed that the optimal synthesis could be obtained as the substrate was positioned at between 5.5mm and 5.0mm, from the flame axis.

• The Journal of Information Systems
• /
• v.22 no.1
• /
• pp.225-248
• /
• 2013

Korean government has been implementing a smart grid testbed in Jeju Island for the low-carbon green growth. As smart grids are in the early stage of their diffusion, strategic guidelines and related measures are needed to spread them successfully. In general, the successful diffusion of new technologies or new products are mostly determined in its early stages. With the introduction of smart grids, the electricity market paradigm will be transformed into user-oriented from provider-oriented. Thus, a study on the diffusion of smart grids from the perspective of users is necessary. This paper examines factors affecting the adoption and diffusion of smart grids from users' perspectives and provide strategic guidelines for diffusing the smart grid. Researchers conducted in-depth interviews with 41 people who have been already using smart grids in the Jeju testbed. Semi-structured interviews were used to collect data. The interviews were recorded on a digital voice recorder memory and subsequently transcribed verbatim. A total of 133 pages of transcripts were obtained from about 10 hours interviews. 97 concepts, 47 sub-categories and 19 categories were identified through open coding of grounded theory. We suggested a paradigm model for diffusing smart grids and total of seven propositions as strategic guidelines.

• Journal of the Korea Concrete Institute
• /
• v.15 no.6
• /
• pp.778-784
• /
• 2003

The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion of carbon dioxide reached the steady-state within about five hours after exposure. The diffusion coefficient increases with the increase of water-cement ratio and decreases with the increase of relative humidity at the same water-cement ratio. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger than that of concrete or mortar. The experimental study of carbon dioxide diffusivity in this study will allow more realistic assessment of carbonation depth in concrete structures.

• Applied Chemistry for Engineering
• /
• v.24 no.2
• /
• pp.121-125
• /
• 2013

In this work, we prepared the carbon paper from chopped carbon fibers using a gas diffusion matrix in polymer electrolyte membrane fuel cells by wet processing. The process of making carbon paper using wet processing is consisted of the three steps involving the dispersion of chopped carbon fibers, the preparation of the carbon fiber web, the impregnating of phenol resin. This work was focused on finding the optimal surfactant to make the carbon paper with 2D orientation of carbon fibers by investigating the dispersion state of carbon fibers in different dispersion solutions. Furthermore, the effect of phenol resin and carbon black contents on properties of electric conductivity was analyzed. As a result, it is confirmed that the carbon fiber was well dispersed when using sodium dodecyl sulfate as a surfactant, and the carbon paper with 8 wt% of phenol and 5 wt% of carbon black contents showed the most excellent electrical property.

• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.1
• /
• pp.34-42
• /
• 2012

Gas diffusion layers (GDLs) of carbon composite type in polymer electrolyte fuel cells were prepared by simple and cheap manufacturing process. To obtain the carbon composite GDLs, carbon black with polymer binder was mixed in solvent, rolled to make sheet, and finally heat-treated at $340^{\circ}C$. The performance of fuel cell using composite GDLs was changed by PTFE content. The physical properties of composite GDLs for pore, conductivity and air permeability were analyzed to compare with the variation of fuel cell performance. The conductivity of composite GDLs was very similar to carbon paper as commercial GDL but pore properties and air flux were considerably different. The porosity, PTFE content and conductivity for composite GDLs did not have an influence on the cell performance much. The increase of pore diameter and air flux led to enhance cell performance.

• Journal of the Korea Convergence Society
• /
• v.12 no.2
• /
• pp.193-200
• /
• 2021

As the degree of environmental pollution caused by the use of fossil fuels intensifies, many countries continue to invest in the development of alternative energy. PEMFC, one of the alternative energies, consists of four main components: bipolor plate, electrolyte, gas diffusion layer, and electrode. Among them, bipolor plate, the gas diffusion layer, and electrode are generally manufactured using carbon materials such as carbon black and carbon fiber. These carbon materials are expensive in manufacturing process or have disadvantages such as corrosion, and research is being conducted in many fields to improve this. This paper collects several research results conducted to improve the shortcomings of these three components and examines the trends of PEMFC by grasping what problems have been and how they have improved.