• Title/Summary/Keyword: Carbon Content Analysis

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Synthesis and Temperature Profile Analysis of ZrC by SHS Method (SHS법에 의한 ZrC 합성 및 온도 Profile 분석)

  • Lee, Hyung-Bock;Cho, Kurn;Lee, Jea-Won
    • Journal of the Korean Ceramic Society
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    • v.32 no.6
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    • pp.659-668
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    • 1995
  • Zirconium carbide was prepared from the mixture of metal zirconium and carbon powders in argon atmosphere by Self-propagating High-temperature Synthesis (SHS) in order to obtain the best carbon source and dilution contents. The most exellent result was obtained in the case that active carbon was added as a starting material, 20~30 wt% dilution content. From thermal profile analysis an apparent activation energy of 118 KJ/mol was calculated. The maximum heating rate achieved during 15 wt% ZrC reaction by product dilution method was approximately 1.54$\times$105 K/s. Coupling this value with the measured wave velocity of 1.026cm/s yielded a maximum thermal gradient fo $1.5\times$105 K/cm. Using the definition of t* and the measured wave velocity, the effective thermal diffusivity, $\alpha$, was calculated to be 0.62$\times$102 $\textrm{cm}^2$/s.

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Stabilization, Carbonization, and Characterization of PAN Precursor Webs Processed by Electrospinning Technique

  • Cho, Chae-Wook;Cho, Dong-Hwan;Ko, Young-Gwang;Kwon, Oh-Hyeong;Kang, Inn-Kyu
    • Carbon letters
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    • v.8 no.4
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    • pp.313-320
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    • 2007
  • In the present study, electrospun PAN precursor webs and the stabilized and carbonized nanofiber webs processed under different heat-treatment conditions were characterized by means of weight loss measurement, elemental analysis, scanning electron microscopy (SEM), attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), thermogravimentric analysis (TGA), and X-ray diffraction (XRD) analysis. The result indicated that stabilization and carbonization processes with different temperatures and heating rates significantly influenced the chemical and morphological characteristics as well as the thermal properties of the stabilized and then subsequently carbonized nanofiber webs from PAN precursor webs. It was noted that the filament diameter and the carbon content of a carbonized nanofiber web as well as its weight change may be effectively monitored by controlling both stabilization and carbonization processes.

A Study on Space Representation of Kid Theme Park using Green Contents (그린콘텐츠를 적용한 키즈 테마파크 공간연출에 관한 연구)

  • Ryu, Hyo-Jin;Moon, Jeong-Min
    • Korean Institute of Interior Design Journal
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    • v.21 no.4
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    • pp.106-113
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    • 2012
  • As environmental pollution and resource exhaustion have been considered as social issues, interest in green content industries which lead low-carbon green growth is increasing. In various areas, green content products and programs have been presented. Of them, kid theme parks are designed to recognize fun and advantages eco-friendly consumption with green contents has and lead children to recognize the problems of environmental pollution and the importance of environment. This study aims to analyse kid theme parks using green contents and characteristics of their space representation. The analysis frame was made through theoretical examination for bibliographical data and a direct interview in terms of factors of green contents. For the analysis frame, visitors were directly interviewed from June to July, 2012. Cases of introduction were analysed to identify realization and characteristics of green contents. As a result of the analysis, it was discovered that kid theme parks using green contents pursued green stories, but they did not consider environment seriously in terms of content materials and methods of realization. To develop successful kid theme parks using green contents, multi-dimensional research is needed in various aspects and various contents such as media should be introduced. The parks should provide fun space for children and propagate green ideas. Its success can lead in green entertainment. The study will be helpful for design of future kid theme parks.

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Plasma Resistance and Etch Mechanism of High Purity SiC under Fluorocarbon Plasma

  • Jang, Mi-Ran;Paek, Yeong-Kyeun;Lee, Sung-Min
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.328-332
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    • 2012
  • Etch rates of Si and high purity SiC have been compared for various fluorocarbon plasmas. The relative plasma resistance of SiC, which is defined as the etch rate ratio of Si to SiC, varied between 1.4 and 4.1, showing generally higher plasma resistance of SiC. High resolution X-ray photoelectron analysis revealed that etched SiC has a surface carbon content higher than that of etched Si, resulting in a thicker fluorocarbon polymer layer on the SiC surface. The plasma resistance of SiC was correlated with this thick fluorocarbon polymer layer, which reduced the reaction probability of fluorine-containing species in the plasma with silicon from the SiC substrate. The remnant carbon after the removal of Si as volatile etch products augments the surface carbon, and seems to be the origin of the higher plasma resistance of SiC.

Isolation and Identification of Carbon Monxide Utilzing Anaerobe, Eubacterium limosum KIST612 (일산화탄소를 이용하는 혐기성 세균 Eubacterium limosum KIST612의 분리 및 동정)

  • Chang, In-Seop;Kim, Do Hee;Kim, Byung Hong;Shin, Pyong Kyun;Yoon, Jung Hoon;Lee, Jung Sook;Park, Yong Ha
    • Microbiology and Biotechnology Letters
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    • v.25 no.1
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    • pp.1-8
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    • 1997
  • Carbon monoxide (CO)-utilizing acetogens were enriched and KIST612 isolated from anaerobic digester fluid was selected for its abilities to tolerate high CO and acetate concentration. The isolate KIST612 was identified as Eubacterium limosum based on the morphological and biochemical characteristics, G+C content of DNA and 16S rRNA sequence analysis. E. limosum KIST612 produced acetate and butyrate from CO. The optimum temperature and pH for the growth and acids formations were 37$\cdot $C and 7.0, respectively. The growth rate and acids productivity of E. limosum KIST612 were higher than those of any other known acetogens when CO was used as the sole energy and carbon source.

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Preparation and Characterization of Crystalline Carbon Nitride (결정질 질화탄소 박막의 합성과 그 특성 해석)

  • 김종일;배선기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.10
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    • pp.835-844
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    • 2001
  • In this paper, we report the successful growth of crystalline carbon nitride films in Si(100) by a laser-electric discharge method. The laser ablation of the target leads to vapor plume plasma expending into the ambient nitrogen arc discharge area. X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy(AES) were used to identify the binding structure and the content of the nitrogen species in the deposited films. The surface morphology of the films with a deposition time of 2 hours is studied using a scanning electron microscopy (SEM). In order to determine the structural crystalline parameters, X-ray diffraction (XRD) was used to analysis the grown films.

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Electrochemical Behaviors of PAN/Ag-based Carbon Nanofibers by Electrospinning

  • Park, Soo-Jin;Im, Se-Hyuk
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.777-781
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    • 2008
  • In this work, silver nanoparticles-containing polyacrylonitrile (PAN) solutions in N,N-dimethylformamide (DMF) were electrospun to be webs consisting of nanofibers. The inputted voltage and PAN content in the solution were fixed at 15 kV and 10 wt.% in DMF with 10 cm of tip-to-collector distance (TCD). The PAN/Ag nanofiber webs were stabilized by oxidation at 250 ${^{\circ}C}$ for 2 h in air and carbonized at 1000 ${^{\circ}C}$ for 2 h in $N_2$. The resultant diameter distribution and morphologies of the nanofibers were evaluated by scanning electron microscope analysis. The electrochemical behaviors of the nanofiber webs were also observed by cyclic voltammetry tests. It was found that the presence of silver nanoparticles in carbon nanofiber webs led to the increase of specific capacitance and the decrease of fiber diameters.

Effect of Fluorination on Electrical Behaviors of Carbon Blacks-filled HDPE Polymeric Switch

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1337-1340
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    • 2009
  • Electrical properties of a fluorinated carbon black (CB)-filled high-density polyethylene (HDPE) polymeric switch were investigated as a function of fluorination pressure at 0.1 ~ 0.4 MPa. From the FT-IR results, the absorption spectra of the fluorinated CB show an absorption band at 1400 ~ 1000 $cm^{-1}\;for\;{\nu}_{C-F}$ and the peak intensity increased with increasing fluorination pressure. Also, the analysis of XPS spectra of the fluorinated CB indicated that fluorine content increased with increasing fluorination pressure. Meanwhile, the surface free energy of the fluorinated CB decreased with increasing fluorination pressure. Consequently, the increase of fluorine contents of CB made a disappearance of negative temperature coefficient (NTC) behavior of the polymeric switch, which was probably due to the reduction of CB reaggregation after melting point of the HDPE, resulted from the decreasing of London dispersive component of the surface free energy for CB particles.

A Study on the Thermal Properties of CNT Reinforced Semiconductive Shield Materials for Power Cables (CNT를 첨가한 전력케이블용 반도전 재료의 열적특성에 관한 연구)

  • Yang, Hoon;Kook, Jeong-Ho;Bang, Jeong-Hwan;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.12
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    • pp.1062-1067
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    • 2007
  • In this paper, we have investigated thermal properties of semiconductive shield materials for power cables. EEA (Ethylene Ethyl Acrylate) was used for base polymer and TGA (Thermal Gravimetric Analysis) and AFM (Atomic Force Microscope) were investigated with various carbon black and CNT (carbon nanotube) contents. When CNT reinforced composites and conventional composite were investigated with TGA, we knew that thermal properties of CNT reinforced composite were better than them of conventional composite. To investigate roughness, we used AFM. Before and after aging, AFM was applied and after aging, roughness was increased. As a result, suitable CNT and CB(carbon black) content is CNT:CB=50:50.

Effect of Carbon Dioxide Adsorption on LDPE/Zeolite 4A Composite Film

  • Jung, Bich Nam;Shim, Jin Kie;Hwang, Sung Wook
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.24 no.3
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    • pp.149-157
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    • 2018
  • Low density polyethylene (LDPE) has been researched in many industrial applications, and LDPE/zeolite 4A composites has been extensively studied for many applications such as microporous, breathable film and so on. LDPE/zeolite composite have a great potential for carbon dioxide adsorption film due to its high adsorption ability. In this study, LDPE/zeolite 4A composites with various contents were prepared by melt mixing process, and co-extrusion process was applied to develop a $CO_2$ adsorption conventional film and foamed film. The thermal, rheological, mechanical, physical and morphological properties of composite films has been characterized, and $CO_2$ adsorption of the composite films evaluated by thermogravimetric analysis (TGA) and the performance was found to be about 18 cc/g at 30.9 wt% of the zeolite content.