• Title/Summary/Keyword: Caly

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Synthesis and characterization of starch$^Na+$-montmorillonite clay nanocomposites

  • Na, Seong-Ki;Park, Jong-Shin
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.67-68
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    • 2003
  • Native corn starch and montmorillonite caly nanocomposites were prepared using the glycerol as the plasticizer. These were characterized by mechanical analysis, X-ray diffraction, infrared spectroscopy, differential scanning calorimetry, and scanning electron microscopy. The tensile strength increased with the clay content to a maximum point and then decreased due to gapping between the two phases. Dispersion of the layered silicate within the starch was verified using X-ray diffraction pattern. Examination of these materials by scanning electron showed that intercalates have good wetting to the starch surface.

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Countrol of Groundwater by Clay Grouting in Undergroun Excavation of Oil Storage Caverns (원유 저장용 지하공동의 건설중 점토 그라우팅에 의한 지하수 제어)

  • 김치환;박창우;이석천
    • Tunnel and Underground Space
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    • v.3 no.1
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    • pp.24-32
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    • 1993
  • Groundwater movement is one of the most important elements in the construction and management of underground oil storage cavern. To control the groundwater flow, grouting is run in parallel with water curtains. But as traditional grouting is conducted within cavern before and after excavation, the effect of grouting is delayed and the injection sphere is limited in the rock mass. Therefore, it is desirable to introduce a more extensive and effective grouting. This article is to present the caly grouting, which was the first to be carried out in the construction of underground caverns for oil storage in Japan. After conducting the clay grouting, the effect was confirmed by ground water level and infiltration quantity to the caverns.

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STUDY ON THE DEEP LOOSENING TECHNIQUE OF SUGARCANE

  • Luo, Xiwen-;Haibo-Wen;Guofu-Huang
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1993.10a
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    • pp.994-1002
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    • 1993
  • Soil deep loosening technique can improve the soil structure and increase the air permeability and water permeability of soil. It can increase the yield of crops in a large scale, particularly the plants with deep root system. This paper introduced the study on the deep loosening technique of sugarcance in Jinpen Farm where the soil is heavy caly with high ground water table. The implement and method of deep loosing, the experiments and results are include in this paper. The experimental results showed that the yield of sugarcane increased more than 20% after deep loosing.

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Hampyong, Kyochon Clay-Its Characteristics and the Effects of Clay-organic Complexes on its. (함평, 교촌 점토의 특성과 점토-유기물 복합체에 관한 연구)

  • 정창주;백용혁;박현수
    • Journal of the Korean Ceramic Society
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    • v.14 no.2
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    • pp.95-103
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    • 1977
  • Characteristics of Ham Pyong clay and clay-organic complexes were investigated by means of geological exploration, chemical analysis, X-ray diffraction, differential thermal analysis, electron microscopy, thermal mechanical analysis, cation exchange capacity and viscosity measurement. The results are as follows; 1) This caly is a transported clay which has black and white colors, and the amounts of deposit are estimated about 1, 600, 000M/T. 2) The major mineral phases identified by X-ray diffraction are kaolinite, sericite and halloysite and the minor phases are quartz and feldspar, these mineral phases can be seperated very easily by the elutriation method. 3) It was supposed that the black colored clay involved a certain clay-organic complexs by the mechanism of intercalation as well as surface absorption. 4) The clay-organic complexes in clay seemed to improve dispersity, to increase the fluidity of clay-water slips, to decrease the firing shrinkage and to promote the thermo-chemical reaction at temperature range up to 50$0^{\circ}C$, but not to effect on the resulted firing color.

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A study on the yielding characteristics for Jangheung marine clay (장흥해성토의 항복특성 연구)

  • 장병욱;이경호;우철웅
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.575-581
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    • 1999
  • Yielding is an important feature of the stress-strain behavior of clays. This study was performed to estabilish the yielding curves and properties for a marine caly from Jangheung. Chonnam Province . A series of tests was done by means of the various stress path tests. Results of the tests are as follows ; 1) The laboratory -determined Ko is very similar to that applied to the Jaky equation. 2) The shape of yielding curve is nealry symmetrical about the p' axis like other natural clays. 3) The critical state parameters, Mc and Me are the same for compression and extension tests which contrasts with the results of the isotropically consolidated soils. 4) The state boundary suface using the critical state paratmers can resresent the normalized yielding curve obtained by various stress path experiments.

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Flocculation Behavior and properties of Montmorillonites Mixed with Organic Polymer Solutions (유기폴리머 용액에 혼합한 몬모릴로나이트의 응집 거동 및 특징)

  • 황진영
    • Economic and Environmental Geology
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    • v.32 no.3
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    • pp.307-315
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    • 1999
  • Four organic polymers were mixed with mothmorillonite. Two cationic polymers a hi로 molecular weight polyacrylamide (494C) and a low molecular weight polymer (587C).Two anionic polymers include a high molecular weight polymer (aerotil). Each clay supension series were allowed to stand for 24 hours and were centrifuged, and the clay plugs were washed and dried. The dried samples investigated by XRD, IR and CEC measurement. The suspended clay containing anionic polymers was not flocculated at any concentratuons of polymer. But the suspendions containing two cationic polymers were rapidly flocculated at almost all concentrations. the d(001) spacings of Na-montmorillonite after being with cationic polymer 587C show about 15$\AA$ suggesting the polymers may have entered the interlayer spaces. The polymer 494C-treated sample produced double peaks of about 12 and 15$\AA$ in XRD. It indicates that the high molecular weight polymer. And cationic polymer 494C may be adsorbed mainy on the outside surface of clay, and some polymers may peretrate into olny interlayers in the margin of montmorillonite particles because of its high molecular weught. CEC of polumer 587-treated sample was reduecd mmarkedly suggesting polymer blocks CEC sites. The d(001) spacings of Ca-montmorillonite after being treated with cationic polymers show about 15$\AA$ suggesting that the interlayer spaces have not been expanded. In the experiment using a dilute Ca-bearing solution, the suspended caly containinf anionic polymers was flocculated. The results indicate that the flocculation behavior of montmorillonite-polymer supension depends on not only polymer properties such as concentration, electric charge and molecular weight but also compositions of solvent.

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Studies on the Behaviors of Some Pesticides in Soils (Part I) -On the Adsorption of Herbicides Atrazine and Alachlor- (토양중에서 농약의 동태에 관한 연구 (제 1 보) -제초제 Atrazine과 Alachlor의 흡착에 대하여-)

  • Lim, Sun-Uk;Lee, Joong-Kil;Han, Ki-Hak
    • Applied Biological Chemistry
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    • v.20 no.3
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    • pp.310-316
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    • 1977
  • The adsorption of 2-Chloro-4-(ethylamino)-6-(isopropylamino)-s-trazine (Atrazine) and 2-Chloro-2' 6' diethyl-N(methoxymethyl)acetanilide(Alachlor) by 21 Korean surface soils is studied and discussed in relation to some properties of soils. 1. Adsorption of Atrazine was correlated posisively with content of clay and organic matter, but negatively with extractable potassium content and sand content. 2. Adsorption of Alachlor was correlated positively with organic matter, caly content and CEC, but negatively with sand content 3. Isothermal adsorpsion of Alachlor was confirmed to the Freundlich eguation.

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Electrical Resistivity Characteristic of Soils (흙의 전기비저항 특성)

  • Park, Sam-Gyu;Kim, Jung-Ho;Cho, Seong-Jun;Yi, Myeong-Jong;Son, Jeong-Sul
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.847-854
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    • 2004
  • The resistivity of soils depends on grains size, porosity, water saturation, pore fluid resistivity, caly contents and son on. It is very important to understand the relationship between resistivity and such physical properties of soils, in order to interpret and evaluate ground conditions by using resistivity data obtained from electrical resistivity prospecting. In this paper, to study the relationship between resistivity and physical properties of soils, the resistivity of glass beads and compacted soil samples both in saturated and unsaturated conditions is measured. As the results, the resistivity of saturated soils depends mainly on porosity and clay contents, while that of unsaturated soils is sensitive to compaction conditions, and decreases with increasing water content until the optimum water condition, that is the maximum dry density. But, the relationship between resistivity and water saturation for soils is unique, being independent of compaction energy. Also, the resistivity ratio decrease with increasing water saturation, followed by no significant change of resistivity ratio over 80 percent of water saturation (the optimum water content).

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