• Title/Summary/Keyword: Calorimeter method

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A Study for the Fire Retardant-Characteristics of Expandable Graphite Composite Materials (팽창흑연을 사용한 복합재료의 난연 특성에 관한 연구)

  • Chun, Kwan-Ok;Rie, Dong-Ho
    • Journal of the Korean Society of Safety
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    • v.32 no.3
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    • pp.28-33
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    • 2017
  • In this study, the composite material of expandable graphite was made to the material development for improving such as a composite material of the sandwich panels or material properties of a fire door and was tested by the ISO 1182, ISO 5660-1(Cone calorimeter Method). For the test, the composite material of expandable graphite, what the expandable graphite ratio was increased by respectively 0g~30g, was classified A1,A2, A3, A4, and made to the test specimens. Through cone calorimeter test, peak heat release rate(HRR) and total heat release(THR), expanded thickness and expansion rate of each composite material of expandable graphite, and fire prone crack and mass loss rate after burning was measured. Thus, the effect of the addition of the expandable graphite and whether is suitable for reference as a fire retardant, was analyzed. Consequently the correlation of THR and fire retardant performance rate was confirmed.

Analysis on the Reaction-to-fire's Performance of Sandwich Panel Systems by using ISO 5660-1 and EN 13823 Fire Tests (중소형 화재시험(ISO 5660-1 및 EN 13823)을 이용한 샌드위치패널 연소성능 분석)

  • Park, Kye-Won;Im, Hong-Soon;Jeong, Jae-Gun;Kim, Woon-Hyung
    • Fire Science and Engineering
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    • v.23 no.1
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    • pp.33-39
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    • 2009
  • In this study, the combustion properties, which are called the reaction-to-fire's performance, of sandwich panels were tested and analyzed according to both ISO 5660 (cone calorimeter method) and EN 13823 (SBI). Several variables including ignition time, mass loss, heat release rate, smoke production rate and $O_2$ density about four sandwich panels and four core materials (thermal insulation material) were evaluated. Combustion properties' similarity and difference of sandwich panels and core materials were compared by materials and test methods respectively. Finally test results were evaluated by Japanese standard building code, National Building code of Canada and EN 13501-1 as well.

HTPB Propellant Ageing Property and HFC Base Shelf-Life Evaluation Method (HTPB 추진제 노화 특성 및 HFC 기반 수명 평가 기법)

  • Cho, Wonho;Westerlund, M.;Ryoo, Baek-Neung;Jung, Gyoo-Dong;Yoo, Ji-Chang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.148-153
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    • 2017
  • During natural ageing of HTPB propellant undergoes a series of slow physico-chemical degradation reactions. By using accelerated ageing conditions it is possible to simulate the material behaviour at different time-temperature conditions especially focused on the in-service conditions. Ageing behaviour of HTPB propellant were investigated using HFC(Micro-Heat Flow Calorimeter) is universal technique for measuring the rate of slow chemical and physical processes in long-term storage.

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HTPB Propellant Ageing Property and HFC Base Shelf-life Evaluation Method (HTPB 추진제 노화 특성 및 HFC 기반 수명 평가 기법)

  • Cho, Wonho;Westerlund, M.;Ryoo, Baekneung;Jung, Gyoodong;Yoo, Jichang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.59-65
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    • 2018
  • During natural aging, hydroxyl-terminated polybutadiene(HTPB) propellant undergoes a series of slow physico-chemical degradation reactions. By using accelerated ageing conditions it is possible to simulate the material behavior at different time-temperatures focusing on in-service conditions. Aging behaviors of HTPB propellant are investigated using HFC(heat flow calorimeter), a universal technique for measuring the rate of slow chemical and physical processes in long-term storage.

An Experimental Study on the Influence of the Spread of Firebrand on Building Exterior Materials and Roofing Materials in Urban Areas (도심지 인접 산불의 불티 확산이 건축물 외장재와 지붕재에 미치는 영향에 관한 실험적 연구)

  • Min, Jeong-Ki
    • Journal of the Society of Disaster Information
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    • v.17 no.3
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    • pp.617-626
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    • 2021
  • Purpose: The purpose of this study is to evaluate the fire srpead risk of building exterior and roofing materials due to the firebrand of forest fire occurring in the urban areas. Method: In order to achieve this research purpose, by selecting building materials used for exterior and roofing materials of buildings, the time to ignition, total heat release, and heat release rate were investigated, and a forest fire firebrand system was established to the possibility of fire spread was confirmed. Result: As a result of the cone calorimeter test, the roofing material had a similar or faster ignition time due to radiant heat compared to the exterior material with the steel plate exposed to the outside, and showed a higher heat release rate and total heat release than the exterior material. Although it was affected by the flammable material, it was confirmed that it did not spread easily due to the limited amount of combustible material, and carbonization marks appeared inside. Conclusion: The cone calorimeter test method has been shown to be useful in understanding the combustion characteristics of building materials by radiant heat, but the fire spread due to a firebrand in a forest fire is directly affected by the flame due to the ignition of surrounding combustibles, so finding a direct correlation with the cone calorimeter method is difficult. It is judged that the roof material may be more vulnerable to the spread of fire due to the fire than the exterior material.

Estimation of Energy Expenditure using Unfixed Accelerometer during Exercise (비고정식 가속도계를 이용한 운동 중 에너지소비 추정)

  • Kim, Joo-Han;Lee, Jeon;Lee, Hee-Young;Kim, Young-Ho;Lee, Kyoung-Joung
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.48 no.4
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    • pp.63-70
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    • 2011
  • In this paper, we proposed a method for estimating energy expenditure using the unfixed axis of the accelerometer. Most studies adopted waist-placement because of the fact that the waist is close to the center of mass of a whole human body. But we adopted pocket-placement, which is capable of using unfixed axis of sensor, that is more convenient than conventional methods. To evaluate the proposed method, 28 male subjects performed walking and running on a motor driven treadmill. All of subject put on the indirect calorimeter and fixed accelerometer, then data were simultaneously measured during exercise. The regression analysis was performed using the test group(n=20) and the regression equation was applied to the control group(n=8). A strong linear relationship between energy expenditure and unfixed accelerometer signal was found. Futhermore, the coefficient of determination was significantly reliable($R^2$=0.98) and showed zero of p-value. The error of energy expenditure estimation between indirect calorimeter and two types of accelerometer was 15.0%(fixed) and 17.0%(unfixed) respectively. These results show the possibilities that the unfixed accelerometer can be used in estimating the energy expenditure during exercise.

Thermophysical Properties of $UO_2$ Fuel Materials

  • Lee, Hung-Joo;Kim, Chul-Whan
    • Nuclear Engineering and Technology
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    • v.8 no.2
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    • pp.81-88
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    • 1976
  • A flash method for measuring the unknown thermal property (the density, specific heat, or thermal diffusivity could be chosen as unknown) is described. The thermal diffusivity of UO$_2$ fuel samples is obtained from room temperature (300 K) to high temperature (1400 K). The specific heat is measured using a commercially available differential scanning calorimeter from room temperature to 500 K. The thermal conductivity of UO$_2$ fuel samples is calculated from the density, thermal diffusivity, and specific heat at constant pressure. The present results are in complete agreement with the usual trends for the thermal conductivity of dielectric materials, in which impurity levels are very important at low temperatures but become relatively unimportant at high temperatures. In addition, the thermal diffusivity values at room temperature are reexamined by measuring the thermal diffusivity of several UO$_2$ fuel samples with same level of doped Gd$_2$O$_3$.

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A Study on Thermal Decomposition of RDX According to the Size using TGA (TGA를 이용한 RDX의 입자 크기에 따른 열적 분해 특성 연구)

  • Bum, Kil-Ho;Kim, Seung-Hee;Kim, Jin-Seuk
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.1
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    • pp.81-85
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    • 2012
  • This work is related to study the thermal decomposition of 1,3,5-trinitro-1,3,5-triazacylohexane(RDX) by differential scanning calorimeter and thermo-gravimetry with Kissinger's & Iso-conversional method under nonisothermal conditions, with heating rate from 2 to $8^{\circ}C$/min or given heating rate. We calculated and compared activation energy with these two methods. Iso-conversional method is better than Kissinger's method to study decomposition mechanism. We also investigated activation energy and frequency factor by Kissinger's & Iso-conversional method with the influence of particle size. In case of single crystal, Cl-3(large crystal) has better thermal stability than Cl-5(small crystal). The activation energy increased according to the size of the particle size.

Comparison of the Heat Release Rate between the results of Cone-Calorimeter and flame spread tester (콘칼로리미터법과 화염전파 시험법의 발열량 평가 비교)

  • Lee Duck-Hee;Jung Woo-Sung;Lee Cheul Kyu;Cho Hee-Ki;Lee Dong-Woo
    • Proceedings of the KSR Conference
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    • 2005.11a
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    • pp.935-940
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    • 2005
  • We generally get the Heat Release Rate by two other method. One is the calculation method from the Oxygen consumption rate and another is the calibration curve method of Temperature rising rate. In this study we compare the results of both test methods with five same specimens. From the test result we get the difference of reproducibility and checked some reasons of the difference. This paper includes some points to be careful for more creditable results for each test method.

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The Thermal Diffusivity of Standard Pieces for Spark Test (불꽃試驗용 標準試片 의 熱擴散 係數)

  • 차경옥;이관수;이흥주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.3
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    • pp.319-327
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    • 1983
  • The thermal diffusivity one of the series of standard pieces for spark test are determined by the flash method. The standard pieces are composed with carbon steels, structural carbon steels, alloy steels and high speed tool steels. In order to compute the thermal conductivity of the standard pieces, their specific heats are measured by a differential scanning calorimeter. The thermal conductivities are calculated from the data of specific heat, density and thermal diffusivity. To increase the accuracy of data for the thermal diffusivity by data reduction excursion method in the flash method, the governing heat diffusion equation, which is closely described experimental conditions with the finite pulse and the heat loss from the sample surfaces, is solved. In this analysis an integral transform is used.