• Title/Summary/Keyword: Calcium phosphate

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Characteristics and Mechanisms of Phosphate Sorption by Calcined Oyster Shell (소성 굴패각에 의한 인산염의 흡착특성 및 메커니즘)

  • Park, Jong-Hwan;Heo, Jae-Young;Lee, Su-Lim;Lee, Jae-Hoon;Hwang, Se-Wook;Cho, Hyeon-Ji;Kwon, Jin-Hyeuk;Chang, Young-Ho;Seo, Dong-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.40 no.1
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    • pp.40-48
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    • 2021
  • BACKGROUND: Although the calcined oyster shell can be used as a calcium-rich adsorbent for phosphate removal, information about it is limited. The purpose of this study was to evaluate the phosphate adsorption characteristics and its mechanism using calcined oyster shells. METHODS AND RESULTS: In this study, calcined oyster shell (C-OS600) was prepared by calcining oyster shells (P-OS) at 600℃ for 20 min. Phosphate adsorption by C-OS600 was performed under various environmental conditions. Phosphate adsorption by C-OS600 occurred rapidly at the beginning of the reaction, and the time to reach equilibrium was less than 1 h. The optimal isotherm and kinetic models for predicting the adsorption of phosphate by C-OS600 were the Langmuir isotherm and pseudo-second order kinetic model, respectively, and the maximum adsorption capacity derived from the Langmuir isotherm was 68.0 mg/g. The adsorption properties of phosphate by C-OS600 were dominantly influenced by the initial pH and C-OS600 dose. In addition, SEM-EDS and FTIR analysis clearly showed a difference in C-OS600 before and after phosphate adsorption, which proved that phosphate was adsorbed on the surface of C-OS600. CONCLUSION: Overall, the calcined oyster shell can be considered as an useful and effective adsorbent to treat wastewater containing phosphate.

Association between diet pattern and dental caries among preschool children (미취학 아동들의 식이섭취행태와 유치우식증과의 관련성)

  • Bin, Sung-Oh;Lee, Jeong-Hee;Jeong, Seong-Hwa;Kim, Hye-Young
    • The Journal of Korean Society for School & Community Health Education
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    • v.12 no.3
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    • pp.89-99
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    • 2011
  • Objectives: The aim of this study was to assess an association between nutrient intake and prevalence risk of deciduous dental caries among preschool children. Methods: A total of 922 children aged 3 to 5 years was selected from the database of Fourth Korean National Health and Nutrition Examination Survey(KNHAINS). Data were included socio-demographic characteristics, oral health related behaviour, nutrient intake(carbohydrate, protein, fat, calcium, phosphate, iron, sodium and potassium), and oral health status(dft index). To assess the crude and adjusted associations, logistic regression analysis were applied considering a complex sampling design. Results: Children who were more consumed protein, calcium, phosphate, iron and sodium had slightly lower prevalence risk of deciduous dental caries after adjusting for socio-demographic characteristics and oral health related behaviour. Moreover, prevalence risk of the highest intake of phosphate and sodium(3rd tertiles) was significant lower than that of the lowest intake(1st tertiles). Conclusion: The nutrient intake was slightly associated with the prevalence risk of deciduous dental caries.

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In Vitro Reaction for Calcium Phosphate Ceramics

  • Ioku, Koji;Toya, Hiroyuki;Fujimori, Hirotaka;Goto, Seishi
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.214-218
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    • 2000
  • Hydroxyapatite (HA) and $\beta$-tricalcium phosphate ($\beta$-TCP) are bio-compatible materials with bones and teeth. HA has been widely applied as bone substitutes because of chemical stability in vivo, while $\beta$-TCP has higher resorbability than HA when the material is implanted in a bone defect. In the present study, both HA and $\beta$-TCP porous ceramics were soaked in the simulated body fluid in order to investigate the reaction between the materials and the fluid. After the soaking test, carbonate hydroxyapatite was formed on HA surface at 1 week, and then the amount of precipitates increased with increasing period of the soaking test. While $\beta$-TCP was not dissolved in the fluid, carbonate hydroxyaopatite was also formed on $\beta$-TCP surface after 12 weeks, and the amount of precipitates was less than that on HA. In vitro behavior of HA was similar to that in vivo, but in vitro behavior of $\beta$-TCP was not similar to that in vivo.

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CHEMICAL EFFECTS ON PWR SUMP STRAINER BLOCKAGE AFTER A LOSS-OF-COOLANT ACCIDENT: REVIEW ON U.S. RESEARCH EFFORTS

  • Bahn, Chi Bum
    • Nuclear Engineering and Technology
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    • v.45 no.3
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    • pp.295-310
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    • 2013
  • Industry- or regulatory-sponsored research activities on the resolution of Generic Safety Issue (GSI)-191 were reviewed, especially on the chemical effects. Potential chemical effects on the head loss across the debris-loaded sump strainer under a post-accident condition were experimentally evidenced by small-scale bench tests, integrated chemical effects test (ICET), and vertical loop head loss tests. Three main chemical precipitates were identified by WCAP-16530-NP: calcium phosphate, aluminum oxyhydroxide, and sodium aluminum silicate. The former two precipitates were also identified as major chemical precipitates by the ICETs. The assumption that all released calcium would form precipitates is reasonable. CalSil insulation needs to be minimized especially in a plant using trisodium phosphate buffer. The assumption that all released aluminum would form precipitates appears highly conservative because ICETs and other studies suggest substantial solubility of aluminum at high temperature and inhibition of aluminum corrosion by silicate or phosphate. The industry-proposed chemical surrogates are quite effective in increasing the head loss across the debris-loaded bed and more effective than the prototypical aluminum hydroxide precipitates generated by in-situ aluminum corrosion. There appears to be some unresolved potential issues related to GSI-191 chemical effects as identified in NUREG/CR-6988. The United States Nuclear Regulatory Commission, however, concluded that the implications of these issues are either not generically significant or are appropriately addressed, although several issues associated with downstream in-vessel effects remain.

Effect of Dietary Protein Level on Ca Efficiency in Bone Mineral Density in Growing Rats (식이단백질량이 성장기 흰쥐가 골밀도에 대한 칼슘효율에 미치는 영향)

  • 정소형
    • Journal of Nutrition and Health
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    • v.28 no.9
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    • pp.817-824
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    • 1995
  • This study was performed to evaluate the effect of dietary protein level on Ca efficiency in bone mineral density in growing male rats. Twenty male rate were divided into two groups. The rats in one group were fed on casein 20% diet as control group and the others were fed on casein 40% diet as protein group. All rats were fed on experimental diet and deionized water ad libitum for 9 weeks. The total body, spine and femur bone mineral density and bone mineral content were measured using dual energy-x ray absorptiometry. Urinary calcium, phosphate, pyridinoline and creatinine, serum calcium, phosphate, total protein, albumin, alkaline phosphatase(ALP) and osteocalcin were measured. Urinary Ca excretion, pyridinoline and crosslinks value and serum ALP content seem to be increased in high protein group. It appears that the growing rats in high protein group had a higher bone resprption and bone formation than those in control group. Animal fad a high protein diet had a siginficantly higher Ca efficiency in BMD, BMC of total body, spine and femur. The results of this show that increasing of dietary protein level (40%) is beneficial of improvement of Ca efficiency during growing period.

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A Comparative Study on the Composition of Preterm and Fullterm Human Milk in colostrum -I. Comparison of the Lactpse, Protein and Mineral Contents in Contents in Closterum from Mothers of Premature and Fullterm Infants (조산모와 정상모의 초유성분에 관한 비교연구 -제1보 : 조산모와 정상모 초유의 당질, 단백질 및 무기질 성분에 관한 비교)

  • 이윤욱
    • Journal of Nutrition and Health
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    • v.28 no.2
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    • pp.127-136
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    • 1995
  • In this study, the nutritional composition of colostrum milk obtained from 22 mothers delivering perterm infants and 17 mothers delivering term infants was analyzed. The energy content of colostrum was yielded based on nitrogen, lactose, and lipid data. Preterm milk is more close the nutritional needs of the preterm infant than dose other breast milk. The results are as follows : 1) Protein concentration was significantly higher, but carbohydrate and lipid concentration were lower in preterm milk than fullterm milk. Energy content yielded from total nitrogen, lactose and lipid concentration was higher in the fullterm milk than preterm milk. 2) Calcium was higher in the preterm milk than fullterm colostrum. Phosphate was lower in fullterm milk than pretem milk. Calcium/Phosphate ratio were 2.61/1 in the preterm and 2.06/1 in the fullterm milk. Magnesium was higher in the preterm milk than fullterm milk. Zinc, Copper and Manganese concentrations were tended to lower in the preterm milk than fullterm milk.

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Calcium Absorption by the Fruitbody of Saesongi (Pleurotus eryngii) Mushroom

  • Lee, Nan-Hee;Im, Moo-Hyeog;Choi, Ung-Kyu
    • Food Science and Biotechnology
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    • v.15 no.2
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    • pp.308-311
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    • 2006
  • Saesongi (Pleurotus eryngii) was cultivated in both potato dextrose agar (PDA) and sawdust media supplemented with Ca salts. The addition of Ca phosphate and Ca carbonate to sawdust media did not affect the growth, whereas Ca sulfate addition suppressed the mycelial growth appreciably. The efficiencies of Ca accumulation in the fruiting were studied based on mycelial growth experiments on Ca-supplemented sawdust media. Supplementation with 0.1 to 5% Ca phosphate increased the Ca content in the fruiting body by 4.5-6.5 fold, to a level of $314.6{\pm}22.7$ to $449.7{\pm}29.3$.

Alginate-Microfibers Produced by Self-Assembly in Cell Culture Medium

  • Park, Jeong-Hui;Shin, Ueon-Sang;Kim, Hae-Won
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.431-433
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    • 2011
  • Alginate microfibers were fabricated by self assembly of alginate monomers exuded from alginate beads (~2 mm in diameter) containing calcium phosphate. Upon incubation of the beads in cell culture medium at $37^{\circ}C$ for a few days, fibers with a diameter of about $7{\mu}m$ started to sprout from the bead surface, and these grew up to about 10 mm in length, resulting in the beads being covered with fiber forests similar to chestnut bur. The combined system of the alginatebased microfiber forest and bead is considered to be useful as a novel 3-dimensional scaffold for cell culture and tisssue growth.

Lower Leg Amputation by Calciphylaxis in Diabetic Nephropathy Patient (A Case Report) (당뇨병성 신부전증 환자의 선단 궤양에 의한 하지절단(1예 보고))

  • Lee, Jun-Young;Yu, Jae-Cheol
    • Journal of Korean Foot and Ankle Society
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    • v.13 no.1
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    • pp.109-112
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    • 2009
  • Calciphylaxis is a rare disease that appear in patients with secondary hyper-parathyroidism or chronic renal failure or that show defect in calcium phosphate metabolism which is characterized by fibrin deposit or calcification of medial wall of vessels causing gradual ischemic skin necrosis. Calciphylaxis is a disease with poor prognosis as skin necrosis can progress rapidly. If left untreated, calciphylaxis will progress to sepsis with high mortality. The treatment is controversial but kidney transplantation or parathyroidectomy is suggested to recover calcium-phosphate metabolism. The authors have experienced calciphylaxis in a patient with chronic renal failure caused by DM nephropathy with characteristic skin lesion and rapid skin necrosis. We describe this case with documentary reviews.

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Bioactivity of Calcium Phosphate Ceramic Coatings on Metallic Implants

  • Kim, Cheol-Sang;Ducheyne, P.
    • Journal of Biomedical Engineering Research
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    • v.11 no.1
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    • pp.5-12
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    • 1990
  • Calcium phosphate ceramics have been applied intensively to orthopaedic and dental implants by virtue of their osteoconductive nature. In an attempt to enhance the bone implant intergrity and Eta utility, these ceramics are deposited onto the porous surface of metallic implants. The coating procedure and the ensuing phase transformations of the ceramic alter the mechanical properties and surface chemistry of the ceramic layers as well as those of the substrate. These structural and compositional differences are directly related to the interaction mechanisms at the surface-active ceramicbone interface. Material and processing induced influences on dissolution, electrokinetic behavior, ceramic-metallic substrate interface and boRe growth enhancement are presented.

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