• Title/Summary/Keyword: CNF

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Effect of the redox flow battery and electrode characteristics according to the heat treatment temperature of a carbon felt (탄소펠트의 열처리 온도에 따른 레독스흐름전지와 전극 특성에 미치는 영향)

  • Yoo, Hyosung;You, Hyunjin;Yu, Kihyun;Kang, Junyoung;Park, Hongsik;Choi, Woonghwi;Yoo, Dong Jin
    • Journal of Energy Engineering
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    • v.24 no.3
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    • pp.89-95
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    • 2015
  • Carbon felts manufactured by (Co)CNF were subjected to heat treatment under different temperatures to use for the electrode of a redox-flow battery. BET and weight loss were tested to investigate the physical properties of the carbon felt according to the heat treatment conditions. SEM and XPS were also analyzed to characterize their surface area. In addition, electrical resistance, CV (cyclic voltammetry) and RFB charge on the electrode properties were examined in accordance with the heat treatment conditions with the discharge performance. The changes of physical properties on the carbon felt surface was confirmed via SEM and BET analysis, The most addition of oxygen functional groups on the carbon felt surface was obtained when one hour heat treatment at $550^{\circ}C$ and it was confirmed by XPS analysis. After resulting the CV tests, the active area of the electrode was the largest at $550^{\circ}C$ heat treatment. The heat treatment experiment of vanadium redox flow battery using the carbon felts were tested at $400^{\circ}C$, $500^{\circ}C$ and $550^{\circ}C$. As a result, the charge-discharge energy efficiency of the heat treatment electrode was 72.9% and 79.8%, at $400^{\circ}C$ and $500^{\circ}C$, respectively. The efficiency of the heat treatment electrode at $550^{\circ}C$ was the best as 79.8% at $550^{\circ}C$.

Proof of Conclusion in Syllogism with DNA Computing (DNA컴퓨팅을 이용한 삼단논증의 결론 증명)

  • 박의준;이인희;장병탁
    • Proceedings of the Korean Information Science Society Conference
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    • 2002.10d
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    • pp.382-384
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    • 2002
  • 본 논문에서는 논리학에서 전통적으로 다루어 온 패턴인 삼단논증의 결론을 DNA 컴퓨팅을 이용해 증명해 내는 방법을 제시한다. 연역 장치로 진리나무 방법의 하나(resolution refutation)를 사용하기 위해서, 삼단논증의 전제들과 결론의 부정을 예화시킨 후 CNF 형태로 바꾸어 준다. 그리고 이것을 이중 가닥의 DNA 분자로 디자인한 후, 해소 반응을 통해 모순, 즉 닐(nil)을 발견하게 되면, 증명은 완료된다.

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Efficient Application to SAT Using DNF (DNF를 이용한 SAT의 효율적 적용)

  • 남명진;최진영
    • Proceedings of the Korean Information Science Society Conference
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    • 2003.04a
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    • pp.881-883
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    • 2003
  • 하드웨어 검증과 모델 체킹 등의 분야에서, SAT(satisfiability problem)나 항진 명제 검사(tautology checking)는 매우 중요한 문제이다. 그러나 이들은 모두 NP-complete 문제이므로 그 복잡도가 매우 크다. 이를 해결하기 위해 여러 가지 연구가 이루어져 왔으며, 여러 효율적인 알고리즘이 존재한다. 이러한 알고리즘은 대부분 일반 표현식을 CNF(conjunctive normal form)로 바꾸어 입력 형식으로 사용한다. 이 논문에서는 일반 표현식을 입력으로 받아 DNF로 변환한 뒤 DNF의 특성을 이용하여 SAT를 검사하는 효율적인 방법을 제시한다.

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Fabrication and Characterization of Transparent Piezoresistors Using Carbon Nanotube Film (탄소나노튜브 필름을 이용한 투명 압저항체의 제작 및 특성 연구)

  • Lee, Kang-Won;Lee, Jung-A;Lee, Kwang-Cheol;Lee, Seung-Seob
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.12
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    • pp.1857-1863
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    • 2010
  • We present the fabrication and characterization of transparent carbon nanotube film (CNF) piezoresistors. CNFs were fabricated by vacuum filtration methods with 65?92% transmittance and patterned on Au-deposited silicon wafer by photolithography and dry etching. The patterned CNFs were transferred onto poly-dimethysiloxane (PDMS) using the weak adhesion property between the silicon wafer and the Au layer. The transferred CNFs were confirmed to be piezoresistors using the equation of concentrated-force-derived resistance change. The gauge factor of the CNFs was measured to range from 10 to 20 as the resistance of the CNFs increased with applied pressure. In polymer microelectromechanical systems, CNF piezoresistors are the promising materials because of their high sensitivity and low-temperature process.

A Morpheme-unit Korean Feature-Based Brammer (KFG) with the X-bar Theoretic Notion of Headedness (X-바 이론의 중심어 개념을 도입한 형태소 단위의 한국어 자질 기반 문법)

  • Park, So-Yeong;Hwang, Yeong-Suk;Im, Hae-Chang
    • Journal of KIISE:Software and Applications
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    • v.26 no.10
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    • pp.1247-1259
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    • 1999
  • 본 논문에서는 한국어 문장형성원리를 간결하게 제시할 수 있도록 X-바 이론의 중심어 개념을 도입한 한국어 자질기반 문법을 제안한다. 제안하는 문법은 어절에 관계없이 나타나는 한국어의 문법현상을 명확히 설명할 수 있도록 어절 대신 형태소를 기본단위로 한다. 그리고, 한국어의 구문범주가 지닌 의미정보와 기능정보를 자질을 이용하여 독립적으로 표현하며, 구문범주간의 결합관계를 바탕으로 하는 자질연산을 수행하여 문장을 분석한다. 또한, 한국어의 부분자유어순과 생략현상에 대해 견고하게 분석할 수 있도록 자질연산을 이진결합중심의 CNF(Chomsky Normal Form)로 제한한다. 이렇게 구성된 한국어 자질기반 문법은 규칙을 직관적이고도 간단하게 기술하며, 한국어의 다양한 문장들을 견고하게 분석한다. SERI Test Suites 97과 신문기사에서 746문장을 추출하여 실험한 결과 94%~99%의 적용율을 보였다.Abstract In this paper, we propose a Korean feature-based grammar(KFG) which adopts the X-bar theoretic notion of headedness for a precise representation of Korean syntactic structure. In order to explain various language phenomena in a given sentence, we use not the word but the morpheme as a constituent unit of KFG. We use features manifesting both the syntactic information and the semantic information of Korean syntactic categories, and feature operations based on the association relationship between two categories. In addition, we restrict feature operations to CNF(Chomsky Normal Form) binary form, which provides a robust representation for properties in Korean such as the frequent ellipsis and the partial free-order. The KFG is intuitive, simple, and versatile in representing most Korean sentences. The experimental result shows 94%~99% coverage on 746 sentences extracted from SERI Test Suites 97 and newspaper sentences.

Spindle-shaped Fe2O3 Nanoparticle Coated Carbon Nanofiber Composites for Low-cost Dye-sensitized Solar Cells (저비용 염료감응 태양전지를 위한 방추형 Fe2O3 나노입자가 코팅된 탄소나노섬유 복합체)

  • Oh, Dong-Hyeun;An, HyeLan;Koo, Bon-Ryul;Ahn, Hyo-Jin
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.95-101
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    • 2016
  • Carbon nanofiber (CNF) composites coated with spindle-shaped $Fe_2O_3$ nanoparticles (NPs) are fabricated by a combination of an electrospinning method and a hydrothermal method, and their morphological, structural, and chemical properties are measured by field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. For comparison, CNFs and spindle-shaped $Fe_2O_3$ NPs are prepared by either an electrospinning method or a hydrothermal method, respectively. Dye-sensitized solar cells (DSSCs) fabricated with the composites exhibit enhanced open circuit voltage (0.70 V), short-circuit current density ($12.82mA/cm^2$), fill factor (61.30%), and power conversion efficiency (5.52%) compared to those of the CNFs (0.66 V, $11.61mA/cm^2$, 51.96%, and 3.97%) and spindle-shaped $Fe_2O_3$ NPs (0.67 V, $11.45mA/cm^2$, 50.17%, and 3.86%). This performance improvement can be attributed to a synergistic effect of a superb catalytic reaction of spindle-shaped $Fe_2O_3$ NPs and efficient charge transfer relative to the one-dimensional nanostructure of the CNFs. Therefore, spindle-shaped $Fe_2O_3$-NP-coated CNF composites may be proposed as a potential alternative material for low-cost counter electrodes in DSSCs.

Preparation and Characterization of Carbon Nanofiber Composite Coated Fabric-Heating Elements (탄소나노섬유복합체를 이용한 의류용 직물발열체의 제조 및 특성)

  • Kang, Hyunsuk;Lee, Sunhee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.39 no.2
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    • pp.247-256
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    • 2015
  • This study prepared fabric-heating elements of carbon nanofiber composite to characterize morphologies and electrical properties. Carbon nanofiber composite was prepared with 15wt% PVDF-HFP/acetone solution, and 0, 1, 2, 4, 8, and 16wt% carbon nanofiber. Dispersion of solution was conducted with stirring for a week, sonification for 24 hours, and storage for a month, until coating. Carbon nanofiber composite coated fabrics were prepared by knife-edge coating on nylon fabrics with a thickness of 0.1mm. The morphologies of carbon nanofiber composite coated fabrics were measured by FE-SEM. Surface resistance was determined by KS K0555 and worksurface tester. A heating-pad clamping device connected to a variable AC/DC power supply was used for the electric heating characteristics of the samples and multi-layer fabrics. An infrared camera applied voltages to samples while maintaining a certain distance from fabric surfaces. The results of morphologies indicated that the CNF content increased specifically to the visibility and presence of carbon nanofiber. The surface resistance test results revealed that an increased CNF content improved the performance of coated fabrics. The results of electric heating properties, surface temperatures and current of 16wt% carbon nanofiber composite coated fabrics were $80^{\circ}C$ and 0.35A in the application of a 20V current. Carbon nanofiber composite coated fabrics have excellent electrical characteristics as fabric-heating elements.

Electrochemical Characteristics of all solid supercapacitor based on DAAQ(1,5-diaminoanthraquinone) and SPEEK(sulfonated polyether ether ketone) (DAAQ와 SPEEK를 이용한 전고상 슈퍼커패시터의 전기화학적 특성)

  • Kim, Jin-Yong;Kim, Hong-Il;Kim, Han-Joo;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.371-372
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    • 2005
  • Supercapacitors are promising devices for delivering high power density. Digital communications, electric vehicles and other devices that require electrical energy at high power levels in relatively short pulses have prompted considerable research on supercapacitors. In recent years, solid electrolytes have been investigated for supercapacitors. Solid electrolytes are advantageous over liquid electrolytes in respect of easy handling and reliability without electrolyte leakage. In this preliminary study, an electrochemical supercapacitor in all solid configuration has been fabricated using CNF-DAAQ and poly-vinylidenefluoride(PVdF). A new type of Supercapacitor was constructed by using carbon nanofibers(CNFs) and DAAQ(l,5-diaminoanthraquinone) monomer. DAAQ was deposited on the carbon nanofibers by chemical polymerization with $(NH_4)_2S_2O_8$ as oxidant in the 0.1M $H_2SO_4$. Dried SPEEK powder was mixed with N-methyl pyrrolidone to make 10 wt.% solution in an ultrasonic bath, the slurry was cast over a glass substrate heated to $70^{\circ}C$ for solvent evaporation. And then we used solid electrolyte of SPEEK. The unit cell consist of DAAQ-CNF/electrolyte/Pt. From the analysis, it is clear that surface of carbon nanofibers was quite uniformly coated with DAAQ. The performance characteristics of the supercapacitors have been evaluated using Cyclic Voltammetry.

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Nondestructive Damage Sensitivity of Carbon Nanotube and Nanofiber/Epoxy Composites using Electro- Micromechanical Technique and Acoustic Emission (전기적-미세역학 시험법과 음향 방출을 이용한 탄소 나노튜브와 나노섬유 강화 에폭시 복합재료의 비파괴 손상 감지능)

  • 김대식;박종만;김태욱
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.285-290
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    • 2004
  • Nondestructive damage sensitivity of carbon nanotube(CNT) and nanofiber (CNF)/epoxy composites with their adding contents was investigated using electro-micromechanical technique. Carbon black (CB) was used only for the comparison with CNT and CNF. The fracture of carbon fiber was detected by acoustic emission (AE), which was correlated to the change in electrical resistance, ΔR under double-matrix composites (DMC) test. Stress sensing on carbon nanocomposites was performed by electro-pullout test under uniform cyclic loading. At the same volume fraction, the damage sensitivity for fiber fracture, matrix deformation and stress sensing were highest for CNT/epoxy composite, whereas for CB/epoxy composite they were the lowest among three carbon nanomaterials (CNMs). Damage sensitivity was correlated with morphological observation of carbon nanocomposites. Homogeneous dispersion among CNMs could be keying parameters for better damage monitoring. In this study, damage sensing of carbon nanocomposites could be evaluated well nondestructively by the electrical resistance measurement with AE.