• Journal of Soil and Groundwater Environment
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• v.29 no.4
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• pp.44-57
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• 2024

Calcium chloride (CaCl₂) and industrial sodium chloride (NaCl) are commonly used as deicing agents in Korea, which are expected to release dissolved chloride ions into the road surfaces following their application. This study aimed to comprehensively assess the usage of deicing agents and variations in groundwater quality between 2016 and 2022 by analyzing public data provided by various domestic institutions. Additionally, the study sought to identify factors contributing to deteriorating road conditions by comparing the amount of CaCl₂ appied and the incidence of potholes. Pothole occurrences during the study period were primarily reported during heavy rainfall periods without application of deicing agents. In 2022, chloride ion concentrations in groundwater in the southeastern Korean Peninsula were significantly higher than in previous years, coinciding with severe cold waves and heavy snowfall that resulted in increased deicing agent use. However, further data collection and verification are needed to distinguish between the effects of seawater intrusion and deicing agents. Despite limitations in the completeness and consistency of public data, the research highlighted the urgent need for improved data quality and further field verification to fully understand and mitigate the environmental impacts of deicing agents.

• Journal of the Korea Organic Resources Recycling Association
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• v.13 no.3
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• pp.82-88
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• 2005

This study was carried out to investigate on the change of NaCl content during the food waste composting and on the safety of food waste compost(FWC) manufactured by the non-stirrer sealed fermenter. Plant culture test with pepper crop was also performed to see the effect of FWC, which was produced by the G co. ltd., on the growth of peper and migration of NaCl in soil. The culture test was performed at the farmland in Chungnam National University. The results were as follows; the NaCl content was gradually accumulated during food waste composting process, probably through water evaporation. Sodium concentration was, however, remarkably decreased at the final stage due to the desalting effect by water which was concentrated on the ceil of the fermentor. The analysis of chemical properties and humidity parameters on the food waste compost revealed that the product is quite a good qualified one. More than 0.5 tons of FWC application on red pepper cultivation caused diminished effect on the yield and the accumulation of salts on soil.

• Journal of Food Hygiene and Safety
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• v.33 no.3
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• pp.157-161
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• 2018

The objective of this study was to develop software to predict the kinetic behavior and the probability of foodborne bacterial growth on processed meat products. It is designed for rapid application by non-specialists in predictive microbiology. The software, named Foodborne bacteria Animal product Modeling Equipment (FAME), was developed using Javascript and HTML. FAME consists of a kinetic model and a probabilistic model, and it can be used to predict bacterial growth pattern and probability. In addition, validation and editing of model equation are available in FAME. The data used by the software were constructed with 5,400 frankfurter samples for the kinetic model and 345,600 samples for the probabilistic model using a variety of combinations including atmospheric conditions, temperature, NaCl concentrations and $NaNO_2$ concentrations. Using FAME, users can select the concentrations of NaCl and $NaNO_2$ meat products as well as storage conditions (atmosphere and temperature). The software displays bacterial growth patterns and growth probabilities, which facilitate the determination of optimal safety conditions for meat products. FAME is useful in predicting bacterial kinetic behavior and growth probability, especially for quick application, and is designed for use by non-specialists in predictive microbiology.

• Journal of the Korean Chemical Society
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• v.54 no.5
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• pp.515-522
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• 2010

A relation between antimicrobial activities and the formation constants of solid complexes of Cu(II), Ni(II), Co(II), Mn(II) and Fe(III) with tridentate Schiff base ligand, 4-hydroxy-3(1-{2-(benzylideneamino)-phenylimino}-ethyl)-6-methyl-2Hpyran-2-one (HL) derived from o-phenylene diamines, dehydroacetic acid (DHA) and p-chloro benzaldehyde have been studied. The ligand and metal complexes were characterized by elemental analysis, conductivity, magnetic susceptibility, thermal analysis, X-ray diffraction, IR, $^1H$-NMR, UV-vis and mass spectra. From the analytical data, the stiochiometry of the complexes was found to be 1:2 (metal:ligand) with octahedral geometry. The molar conductance values suggest the nonelectrolytic nature of metal complexes. The X-ray diffraction data suggests monoclinic crystal system for Ni(II) and orthorhombic crystal system for Cu(II) and Co(II) complexes. The IR spectral data suggest that the ligand behaves as tridentate ligand with ONN donor atoms sequence towards central metal ion. Thermal behavior (TG/DTA) and kinetic parameters calculated by Coats-Redfern method suggests more ordered activated state in complex formation. The protonation constants of the complexes were determined potentiometrically in THF:water (60:40) medium at $25^{\circ}C$ and ionic strength ${\mu}=0.1\;M$ ($NaClO_4$). Antibacterial activities in vitro were performed against Staphylococcus aureu and Escherichia coli. Antifungal activities were studied against Aspergillus Niger and Trichoderma. The effect of the metal ions and stabilities of complexes on antimicrobial activities are discussed.

• Journal of the Korean Chemical Society
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• v.53 no.1
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• pp.17-26
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• 2009

Hydrazones of isonicotinic acid hydrazide, viz., N-isonicotinamido-furfuralaldimine (INH-FFL), N-isonicotnamido-cinnamalidine (INH-CIN) and N-isonicotnamido-3',4',5'-trimethoxybenzaldimine (INH-TMB) were prepared by reacting isonicotinic acid hydrazide with respective aromatic aldehydes, i.e., furfural, cinnamaldehyde or 3,4,5-trimethoxy-benzaldehyde. A new series of fifteen complexes of cobalt(II) with these new hydrazones, INH-FFL, INH-CIN and INH-TMB, were synthesized by their reaction with cobalt(II) salts. The infrared spectral data reveal that hydrazone ligands behave as a bidentate ligand with N, O donor sequence towards the $Co^{2+}$ ion. The complexes were characterized on the basis of elemental analysis, magnetic susceptibility, conductivity, infrared and electronic spectral measurements. Analytical data reveal that the complexes have general composition [Co($L)_2X_2]\;and\;[Co(L)_3](ClO_4)_2$ where L= INH-FFL, INH-CIN or INH-TMB and X = $Cl^-,{NO_3}-,\;NCS^-\;or\;CH_3COO^-.$ The thermal behaviour of the complexes were studied using thermogravimetrictechnique. Electronic spectral results and magnetic susceptibility measurements are consistent with the adoption of a six-coordinate geometry for the cobalt(II) chelates. The antimicrobial properties of cobalt(II) complexes and few standard drugs have revealed that the complexes have very moderate antibacterial activities.

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.465-469
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• 2009

Characteristics of oxidation reaction of four lanthanide chlorides(Ce, Nd, Pr and $EuCl_3$) in a oxygen-eutectic(LiCl-KCl) salt bubble column was investigated. From the results obtained from the thermochemical calculations by HSC chemistry software, the most stable lanthanide compounds in the oxygen-used rare earth chlorides system were oxychlorides(EuOCl, NdOCl, PrOCl) and oxides($CeO_2$, $PrO_2$), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides for Eu, Nd and Pr and oxides for Ce and Pr were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes : small cubic(oxide) and large tetragonal (oxychloride) structures. The conversion efficiencies of the lanthanide elements to their molten salt-insoluble precipitates(or compound) were increased with the sparging time and temperature, and Ce showed the best reactivity. In the conditions of $650^{\circ}C$ of the molten salt temperature and 420 min of the sparging time, the conversion efficiencies were over 99% for all the investigated lanthanide chlorides.

• Particle and aerosol research
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• v.12 no.3
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• pp.95-102
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• 2016

Controlling exposures to occupational hazards is important for protecting workers. Certified facepiece respirators are recommended when engineering controls do not adequately prevent exposures to airborne nanomaterials. The objective of this study is to carry out the experimental performance test to investigate the fractional efficiencies of the filter media for two grades of facepiece respirators. Experimental performance evaluations were carried out for the test NaCl particles and silver nanoparticles. For media of respirator filter, the penetration of NaCl particles was less than 5% and the most penetrating particle size occurred at about 40 nm. For silver nanoparticles, the most penetrating particle size was about 20nm with higher efficiency than those of NaCl particles. Charge characteristics of airborne nanoparticles is important because the media of respirator filter is made by the electret filter media.

• Horticultural Science & Technology
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• v.31 no.6
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• pp.748-755
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• 2013

This study was conducted to find a salt tolerance gene in Brassica rapa. In order to meet this objective, we analyzed data from a KBGP-24K oligo chip [BrEMD (Brassica rapa EST and microarray database)] of the B. rapa ssp. pekinensis 'Chiifu' under salt stress (250 mM NaCl). From the B. rapa KBGP-24K microarray chip analysis, 202 salt-responsive unigenes were primarily selected under salt stress. Of these, a gene with unknown function but known full-length sequence was chosen to closely investigate the gene function. The selected gene was named BrSSR (B. rapa salt stress resistance). BrSSR contains a 285 bp open reading frame encoding a putative 94-amino acid protein, and a DUF581 domain. The pSL94 vector was designed to over-express BrSSR, and was used to transform tobacco plants for salt tolerance analysis. T1 transgenic tobacco plants that over-expressed BrSSR were selected by PCR and DNA blot analyses. Quantitative real-time RT PCR revealed that the expression of BrSSR in transgenic tobacco plants increased by approximately 3.8-fold. Similar results were obtained by RNA blot analysis. Phenotypic characteristics analysis showed that transgenic tobacco plants with over-expressed BrSSR were more salt-tolerant than the wild type control under 250 mM NaCl for 5 days. Based on these results, we hypothesized that the over-expression of BrSSR may be closely related to the enhancement of salt tolerance.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.15 no.3
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• pp.53-58
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• 2006

This study deals with the method of post-processing in the automatic tool path generation for 5-axis NC machining. The 5-axis NC machining cannot only cope with the manufacturing of complicated shapes, but also offers numerous advantages such as reasonable tool employment, great reduction of set-up process and so on. Thus 5-axis NC machining has been used for aircraft parts, mold and die as well as for complicated shapes such as impeller, propeller and rotor. However, most of the present CAM systems for 5-axis NC machining have limited functions in terms of tool collision, machine limits and post-processing. Especially 5-axis machine configurations are various according to the method which the rotational axes are adapted with the table and spindle. For that reason, In many cases the optimal numerical control (NC) data cannot be obtained or considerable time is consumed. To solve this problem, we applied a general post-processor for 5-axis NC machining. The validity of this post-processor should be experimentally confirmed by successfully milling to a helix shaped workpiece.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.295-295
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• 2015

강우의 시 공간적 불균형이 심한 우리나라는 수자원 확보 및 관리가 어려움에 따라 신규 수자원 확보와 기존 수자원 관리의 중요성에 대한 인식이 높아지고 있다. 최근 대체수자원으로서 대두되고 있는 지하수는 지표수에 비해 이용지점에서 바로 취수하여 사용이 가능하다는 장점이 있으나, 오염이 진행되면 복구에 상당한 기간과 비용이 소요됨에 따라 철저한 관리가 필요하다. 특히 해안지역 수자원의 경우, 내륙지역에 비해 하천이 발달해 있지 않아 지하수에 대한 높은 의존도에 따른 수량적 문제와 해수와 접해있는 면적이 많음에 따라 지하수와 해수간의 유동으로 인한 수질적 문제로 지하수 관리가 더욱 어렵다. 이에 본 연구는 지하수유동해석프로그램인 Visual MODFLOW의 SEAWAT model을 이용하여 지하수위 변화에 따른 해수침투의 영향을 판단하고자 하였다. 연구지역은 태안지역의 근흥1, 근흥2 관측소의 지하수위 데이터를 사용하였으며, 2008 ~ 2014년 까지 매년 지하수위 변동에 따라 해수침투 영향을 분석하였다. 이와 함께 해수침투 영향 판단 인자인 EC, TDS는 각 관측소 데이터를 통한 환산 및 분석 진행하고, $Cl/HCO_3$ 몰비는 참고문헌을 인용하여 모델링에 의한 해수침투 영향과 관측자료 및 이온분석을 통한 영향을 비교하였다.