• Journal of Soil and Groundwater Environment
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• v.12 no.4
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• pp.60-71
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• 2007

Groundwater from public wells was monitored during one year with two month interval for hydrogeochemical parameters and chlorofluorocarbons (CFCs) as environmental tracers in Jeju Island. Concentrations of major cations and $SiO_2$ show variation less than 10% whereas $NO_3$ and dissolved oxygen (DO) showed larger variation though DO variation did not change oxic or suboxic condition. $NO_3$ concentration has no consistent seasonal pattern with the largest variation of 35%. Groundwater ages determined by CFCs became temporarily younger by 5 years in October for groundwater with ages of 15 to 25 years, which can be attributed to infiltrating water in rainy season. Compared to air temperature, groundwater temperature has much smaller variation with no phase difference, which can be accounted for by a two-component model consisting of infiltrating water from surface and deeper groundwater with negligible temperature variation. The relatively small variation in groundwater age and temperature indicates that groundwater recharge through fast flow-paths is much smaller compared with basal groundwater in terms of aquifer storage.

• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.372-376
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• 1998

Supported Pd($Pd/AlF_3$, $Pd/{\gamma}-Al_2O_3$) catalysts and solid-acid catalysts(${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$, $AlF_3$) were used to perform dechlorination of HCFC-142b(1-chloro-1,1-difluoroethane) in the presence of excess hydrogen. In the reactions the effects of reaction temperature, the mole ratio(r) of $H_2$ to HCFC-142b and the amount of supported Pd on dechlorination of HCFC-142b into HFC-143a(1,1,1-trifluoroethane) or HFC-152a(1,1-difluoroethane) were investigated. The experimental results showed that the conversion of HCFC-142b to product gases were 60% and 92%, respectively, and the selectivity to HFC-143a in the product gases were 58% and 64% for $Pd/AlF_3$ and $Pd/{\gamma}-Al_2O_3$ catalysts, respectively. On these catalysts an optimum reaction condition was found at $200^{\circ}C$ with the space time of reactant gases as 1.05 second and the mole ratio of $H_2$ to HCFC-142b as 3. Solid-acid catalysts were also tested at the same reaction condition. The results showed that the conversions of HCFC-142b to product gases were 12%, 8% and 7%, and the selectivities to HFC-152a were 94%, 92% and 90% for ${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$ and $AlF_3$ catalysts, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.5
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• pp.499-508
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• 2010

This study proposed a life cycle impact assessment index that can indicate the environment-related information of the product in monetary value such that the national geographical, environmental, and social features are fully reflected based on a damage-oriented model. First, the estimation process was classified into characterization, damage assessment, and integration stages considering the six biggest impact categories: resource depletion, global warming, ozone depletion, acidification, eutrophication, and photochemical oxidant creation. Moreover, this study came up with the 16 category endpoints related to the 6 impact categories, and the damage function, to the 4 largest safeguard subjects. The integration indices of finally identified impact categories were KRW 21.8/kg Sb, KRW 6.19/kg$CO_2$, KRW 53,000/kg CFC-11, KRW 13,100/kg $SO_2$, KRW 2,310/kg ${PO_4}^{3-}$, and KRW 3,030/kg $C_2H_4$. Using the results of this research, environmental impacts based on the environmental load generated throughout the entire life cycle of a product can serve as a single index in monetary value; thus enhancing understanding and utilization of the results of life cycle impact assessments.

• Applied Chemistry for Engineering
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• v.16 no.3
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• pp.379-384
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• 2005

Polyurethane foams (PUFs) were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI), seven polyols with different functionalities and OH values, silicone surfactant, two catalysts, and three blowing agents. Chlorofluorocarbon (CFC-11), hydrochlorofluorocarbon (HCFC-141b) and hydrofluorocarbon (HFC-365mfc) were used as blowing agents. The effect of gelling and blowing catalysts on basic properties and cell structure of PUF with HCFC-141b was investigated. The cell size of the PUF decreased with an increase in the amount of catalyst from 0 to 2 pph (parts per hundred polyol). In the case of gelling type catalyst, the compressive strength increased from 11.9 to $12.66kg_f/cm^2$ with an increase in the amount catalyst from 0 to 2 pph but the density did not change significantly. The gelling time, density, and compressive strength of the PUF with three different blowing agents were measured. There was no detectable change in their properties. However, the cell structure of PUF with HCFC-141b was not uniform as in the other systems.

• Resources Recycling
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• v.27 no.1
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• pp.74-83
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• 2018

This study conducted the Life Cycle Assessment(LCA) on waste rubber recycling technology for recovering rubber product from the waste tires. Environmental impacts were assessed for the five categories of impacts: global warming, resource depletion, acidification, eutrophication, photochemical oxide production, and ozone layer depletion. When recycling 1ton of waste tire containing rubber, global warming impact was 1.77E+02 kg $CO_2-eq.$, resource depletion impact was 1.23E+00 kg Sb-eq., acidification impact was 5.92E-01 kg $SO_2-eq.$, eutrophication impact was 1.23E-01 kg $PO{_4}^{3-}-eq.$, photochemical oxide production impact was 3.42E-01 kg $C_2H_4-eq.$, and ozone layer depletion impact was 1.87E-04 kg CFC11-eq. In terms of overall environmental impacts, carbon, softener and electricity the greatest impact, so it is necessary to compare the environmental impacts of the raw materials to replace carbon and softener, and a method to reduce the filler usage in the process is needed. In addition, it is necessary to improve energy efficiency, change to low-energy sources, and apply renewable energy.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.5
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• pp.413-421
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• 2014

Desiccant cooling system is an air conditioning system that uses evaporative cooler to cool air and it can perform cooling by using heat energy only without electrically charged cooler. Thus, it can solve many problems of present cooling system including the destruction of ozone layer due to the use of CFC[chloro fluoro carbon] affiliated refrigerants and increase of peak power during summer season. In this study, cooling performance and exergy analysis was conducted in order to increase efficiency of desiccant cooling system. Especially, using exergy analysis based on the second law of thermodynamics can resolve the issue related to system efficiency in a more fundamental way by analyzing the cause of exergy destruction both in whole system and each component. The purpose of this study is to evaluate COP[coefficient of performance], cooling capacity and exergy performance of desiccant cooling system incorporating a regenerative evaporative cooler in various regeneration temperature and outdoor air conditions.

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.3
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• pp.191-196
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• 2017

Owing to the harmful environmental effects of HCFC and CFC refrigerants discovered in the late 20th century, the need for environmentally friendly refrigerants such as $CO_2$ in cooling systems has increased. Air-source $CO_2$ heat pumps that utilize ambient heat in cold winter are less efficient because of a higher evaporation temperature, and it is difficult to manufacture the components of the heat pump owing to a super critical pressure of over 130 bar. This research aims to overcome these disadvantages and improve energy efficiency by introducing a new lower-pressure $CO_2$ auto-cascade heat pump system. $CO_2$-R32 zeotropic refrigerants were considered for two-stage expansion and effective cooling heat exchanging system configurations of the new auto-cascade heat pump. The results indicated that the efficiency of the two-stage expansion system was higher than that of the original one-stage expansion system. Furthermore, the two-stage expansion system showed significant performance improvements when the two-stage expansion stage from highest pressure of 70bar, intermediate expansion pressure of 25bar, and final low pressure of 10bar is applied. The COP of the new two-stage auto-cascade system (2.332) was 43.15% higher than that of the present simple auto-cascade system (1.629). Refrigerants having an evaporation temperature of $-10^{\circ}C$ or lower can be obtained that can be easily evaporated in an evaporator even at a low temperature.

• Journal of Biomedical Engineering Research
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• v.25 no.2
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• pp.137-144
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• 2004

ECG signals are often contaminated with high-frequency noise such as muscle artifact, power line interference, and others. In the ECG signal processing, especially during a pre-processing stage, numerous noise removal techniques have been used to reduce these high-frequency noise without much distorting the original signal. This paper proposes a new type of digital filter with a continuously variable cutoff frequency to improve the signal quality This filter consists of a cutoff frequency controller (CFC) and variable cutoff frequency lowpass filter (VCF-LPF). From the noisy input ECG signal, CFC produces a cutoff frequency control signal using the signal slew rate. We implemented VCF-LPF based on two new filter design methods called convex combination filter (CCF) and weight interpolation fille. (WIF). These two methods allow us to change the cutoff frequency of a lowpass filter In an arbitrary fine step. VCF-LPF shows an excellent noise reduction capability for the entire time segment of ECG excluding the rising and falling edge of a very sharp QRS complex. We found VCF-LPF very useful and practical for better signal visualization and probably for better ECG interpretation. We expect this new digital filter will find its applications especially in a home health management system where the measured ECG signals are easily contaminated with high-frequency noises .

• Clinical and Experimental Pediatrics
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• v.50 no.8
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• pp.757-760
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• 2007

Purpose : Febrile convulsions (FC) were considered to be a benign seizure syndrome that is distinct from epilepsy. But it is thought that children with complex features i.e., partial or prolonged seizures or multiple episodes of FC would bear a higher risk of developing unprovoked seizures. The aim of this study is to look into the relative significance of each criteria that define complex febrile convulsions (CFC) as a predictor of subsequent epilepsy. Methods : All children were retrospectively identified for a febrile seizure through pediatric departments of the Konyang University Hospital. Information was collected from medical records and interviews with parents. Patients with abnormal neurological examinations at presentation were excluded. Results : This study was performed from March 2000 to December 2003. Sixty-three out of 314 children (20.0%) with febrile convulsion fulfilled the criteria for CFC and forty-four children of them have been followed for 12 months or more. Ten of these (23.2%) had unprovoked seizures for 14-62 months (median $34.2{\pm}11.6$ months). The patients with partial FC showed a trend toward a higher risk (57.1%) of developing epilepsy than the patients with multiple or prolonged febrile convulsions (26.7%, 24.1% respectively). Conclusion : We found that the partial feature of febrile convulsion is associated with subsequent epilepsy.

• Journal of the Korean Data and Information Science Society
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• v.26 no.6
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• pp.1409-1416
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• 2015

The change of temperature influences on the various aspect, especially human health, plant and animal's growth, economics, industry, and culture of the country. In this article, the autoregressive error (ARE) model has been considered for analyzing the monthly temperature data at the Suwon monitoring site in Korea. In the ARE model, five meteorological variables, four greenhouse gas variables and five pollution variables are used as the explanatory variables for the temperature data set. The five meteorological variables are wind speed, rainfall, radiation, amount of cloud, and relative humidity. The four greenhouse gas variables are carbon dioxide ($CO_2$), methane ($CH_4$), nitrous oxide ($N_2O$), and chlorofluorocarbon ($CFC_{11}$). And the five air pollution explanatory variables are particulate matter ($PM_{10}$), sulfur dioxide ($SO_2$), nitrogen dioxide ($NO_2$), ozone ($O_3$), and carbon monoxide (CO). Among five meteorological variables, radiation, amount of cloud, and wind speed are more influence on the temperature. The radiation influences during spring, summer and fall, whereas wind speed influences for the winter time. Also, among four greenhouse gas variables and five pollution variables, chlorofluorocarbon, methane, and ozone are more influence on the temperature. The monthly ARE model explained about 43-69% for describing the temperature.