• Title/Summary/Keyword: C:N

Search Result 23,570, Processing Time 0.048 seconds

Measurement and Prediction of Fire and Explosion Characteristics of n-Butylacetate (초산부틸의 화재 및 폭발 특성치 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
    • /
    • v.32 no.5
    • /
    • pp.25-31
    • /
    • 2017
  • The flash point, explosion limits, autoignition temperature(AIT) are important combustible properties which need special concern in the chemical safety process that handle hazardous substances. For the evaluation of the flammable properties of n-butylacetate, this study was investigated the explosion limits of n-butylacetate in the reference data. The flash points, fire points and AIT by the ignition delay time of n-butylacetate were experimented. The lower flash points of n-butylacetate by using the Setaflash and Pensky-Martens closed-cup testers were $24^{\circ}C$ and $26^{\circ}C$, respectively. The flash points of n-butylacetate using the Tag and Cleveland open cup testers are measured $31^{\circ}C$ and $40^{\circ}C$, respectively. And the fire points of n-butylacetate by the Tag and Cleveland open cup testers were measured $32^{\circ}C$ and $41^{\circ}C$. The AIT of n-butylacetate measured by the ASTM 659E tester was measured as $411^{\circ}C$. The lower explosion limit of lower flash point $24^{\circ}C$, which was measured by the Setaflash tester, was calculated to be 1.40 vol%. Also, the upper explosion limit of upper flash point $67^{\circ}C$ the Setaflash tester was calculated to be 12.5 vol%.

Carbon and Nitrogen Distribution of Tree Components in Larix kaempferi Carriere and Quercus variabilis Blume Stands in Gyeongnam Province

  • Kim, Choonsig
    • Journal of Korean Society of Forest Science
    • /
    • v.108 no.2
    • /
    • pp.139-146
    • /
    • 2019
  • This study was conducted to determine the carbon (C) and nitrogen (N) distribution within tree components (i.e., stem, branches, leaves, and roots) of the Japanese larch (Larix kaempferi Carriere) plantation and natural oriental cork oak (Quercus variabilis Blume) stands. Fifteen Japanese larch and 15 oriental cork oak trees were destructively sampled to compare the C and N stocks in the components of the trees from three different regions-Hadong-gun, Hamyang-gun and Sancheong-gun-in Gyeongnam Province, South Korea. Species-specific allometric equations were developed to estimate the C and N contents in the tree components based on the diameter at breast height (DBH). There were differences in mean C and N concentrations between the Japanese larch and the oriental cork oak. The mean C concentrations of the tree componentswere significantly higher in Japanese larch than in oriental cork oak; whereas, the N concentration in the stems was significantly lower in Japanese larch than in oriental cork oak. The allometric equations developed for C and N content were significant (p < 0.05) with a coefficient of determination ($R^2$) of 0.76 to 0.99. The C and N stocks in the tree components do not appear to be affected by the species such as Japanese larch plantations and oriental cork oak stands. This study emphasizes the importance of C and N concentrations to estimate the C and N distribution according to tree components in different tree species.

Review on fabrication of graphitic carbon nitride based efficient nanocomposites for photodegradation of aqueous phase organic pollutants

  • Sudhaik, Anita;Raizada, Pankaj;Shandilya, Pooja;Jeong, Dae-Yong;Lim, Ji-Ho;Singh, Pardeep
    • Journal of Industrial and Engineering Chemistry
    • /
    • v.67
    • /
    • pp.28-51
    • /
    • 2018
  • Graphitic carbon nitride ($g-C_3N_4$) as a fascinating visible light active semiconductor photocatalyst has medium band gap, non-toxic nature, stable chemical structure and high thermal stability. Recently, intensive researches are focused on photocatalytic activity of $g-C_3N_4$ for wastewater treatment. This review demonstrates latest progress in fabrication of graphitic carbon nitride $C_3N_4$ incorporated nanocomposite to explore photocatalytic ability for water purification. The $g-C_3N_4$-based nanocomposites were categorized as $g-C_3N_4$ metal-free nanocomposite, noble metals/$g-C_3N_4$ heterojunction, non-metal doped $g-C_3N_4$, transition and post transition metal based $g-C_3N_4$ nanocomposite. Apart from fabrication methods, we emphasized on elaborating the mechanism of activity enhancement during photocatalytic process.

Raman Scattering Characteristics of Polycrystalline 3C-SiC Thin Films deposited on AlN Buffer Layer (AlN 버퍼층위에 증착된 다결정 3C-SiC 박막의 라만 산란 특성)

  • Chung, Gwiy-Sang;Kim, Kang-San
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.21 no.6
    • /
    • pp.493-498
    • /
    • 2008
  • This Paper describes the Raman scattering characteristics of polycrystalline (Poly) 3C-SiC thin films, in which they were deposited on AlN buffer layer by APCVD using hexamethyldisilane (MHDS) and carrier gases (Ar+$H_2$). When the Raman spectra of SiC films deposited on the AlN layer of before and after annealing were worked according to growth temperature, D and G bands of graphite were measured. It can be explained that poly 3C-SiC films admixe with nanoparticle graphite and its C/Si rate is higher than ($C/Si\;{\approx}\;3$) that of the conventional SiC, which has no D and G bands related to graphite. From the Raman shifts of 3C-SiC films deposited at $1180^{\circ}C$ on the AlN layer of after annealing, the biaxial stress of poly 3C-SiC films was obtained as 896 MPa.

Fabrication of polycrystalline 3C-SiC thin film diodes (다결정 3C-SiC 박막 다이오드의 제작)

  • Ahn, Jeong-Hak;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.06a
    • /
    • pp.348-349
    • /
    • 2007
  • This paper describes the electrical characteristics of polycrystalline (poly) 3C-SiC thin film diodes, in which poly 3C-SiC thin films on n-type and p-type Si wafers, respectively, were deposited by APCVD using HMDS, Hz, and Ar gas at $1180^{\circ}C$ for 3 hr. The schottky diode with Au/poly 3C-SiC/Si(n-type) structure was fabricated. Its threshold voltage ($V_d$), breakdown voltage, thickness of depletion layer, and doping concentration ($N_D$) values were measured as 0.84 V, over 140 V, 61nm, and $2.7\;{\times}\;10^{19}\;cm^3$, respectively. The p-n junction diodes fabricated on the poly 3C-SiC/Si(p-type) were obtained like characteristics of single 3C-SiC p-n junction diodes. Therefore, poly 3C-SiC thin film diodes will be suitable microsensors in conjunction with Si fabrication technology.

  • PDF

A CHARACTERIZATION OF Ck×(C*) FROM THE VIEWPOINT OF BIHOLOMORPHIC AUTOMORPHISM GROUPS

  • Kodama, Akio;Shimizu, Satoru
    • Journal of the Korean Mathematical Society
    • /
    • v.40 no.3
    • /
    • pp.563-575
    • /
    • 2003
  • We show that if a connected Stein manifold M of dimension n has the holomorphic automorphism group Aut(M) isomorphic to $Aut(C^k {\times}(C^*)^{n - k})$ as topological groups, then M itself is biholomorphically equivalent to C^k{\times}(C^*)^{n - k}$. Besides, a new approach to the study of U(n)-actions on complex manifolds of dimension n is given.

WEAKLY LAGRANGIAN EMBEDDING AND PRODUCT MANIFOLDS

  • Byun, Yang-Hyun;Yi, Seung-Hun
    • Bulletin of the Korean Mathematical Society
    • /
    • v.35 no.4
    • /
    • pp.809-817
    • /
    • 1998
  • We investigate when the product of two smooth manifolds admits a weakly Lagrangian embedding. Prove that, if $M^m$ and $N^n$ are smooth manifolds such that M admits a weakly Lagrangian embedding into ${\mathbb}C^m$ whose normal bundle has a nowhere vanishing section and N admits a weakly Lagrangian immersion into ${\mathbb}C^n$, then $M \times N$ admits a weakly Lagrangian embedding into ${\mathbb}C^{m+n}$. As a corollary, we obtain that $S^m {\times} S^n$ admits a weakly Lagrangian embedding into ${\mathbb}C^{m+n}$ if n=1,3. We investigate the problem of whether $S^m{\times}S^n$ in general admits a weakly Lagrangian embedding into ${\mathbb} C^{m+n}$.

  • PDF

Effect of Different Dietary n-6 to n-3 Fatty Acid Ratios on the Performance and Fatty Acid Composition in Muscles of Broiler Chickens

  • Mandal, G.P.;Ghosh, T.K.;Patra, A.K.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.27 no.11
    • /
    • pp.1608-1614
    • /
    • 2014
  • The objective of this study was to investigate the different dietary ratios of n-6 to n-3 (n-6/n-3) fatty acid (FA) on performance and n-6/n-3 FA in muscles of broiler chickens. A total of 300 one-day-old Cobb chicks were randomly assigned to 3 treatments of 10 replicates in each (10 birds/replicate). Birds were fed on a corn-soybean meal-based diet containing 1% oil during starter (day 1 to 21) and 2% oil during finisher (day 22 to 39) phases, respectively. Treatments of high, medium and low dietary n-6/n-3 FA were formulated by replacing rice bran oil with linseed oil to achieve n-6/n-3 FA close to >20:1, 10:1 and 5:1, respectively. Average daily gain, average daily feed intake, and feed conversion ratio were similar (p>0.05) among the treatments. Serum glucose, cholesterol and triglycerides concentrations were not affected (p>0.05) by dietary treatments. In breast, concentration of C18:3n-3 was significantly greater (p = 0.001) for medium and low vs high n-6/n-3 FA, while concentrations of C20:5n-3, C22:6n-3, total n-3 FA, and n-6/n-3 FA were significantly higher for low vs medium, and medium vs high dietary n-6/n-3 FA. In contrast, concentrations of C18:2 and mono-unsaturated FA (MUFA) were lower for low vs high dietary n-6/n-3 FA. In thigh muscles, concentrations of C20:5n-3 were higher (p<0.05) for medium and low vs high dietary n-6/n-3 FA, and concentrations of C18:3n-3, C22:6, and n-3 FA were greater (p<0.05) for medium vs high, low vs medium dietary n-6/n-3 FA. However, concentrations of C18:1, MUFA, n-6/n-3 were lower (p<0.05) for low and medium vs high dietary n-6/n-3 FA. In conclusion, lowering the dietary n-6/n-3 FA did not affect the performance of chickens, but enhanced beneficial long-chain n-3 FA and decreased n-6/n-3 FA in chicken breast and thigh, which could be advantageous for obtaining healthy chicken products.

Copolymerization of Ethylene and Cycloolefin with Metallocene Catalyst: I. Effect of Catalyst (메탈로센 촉매를 애용한 에틸렌과 시클로올레핀의 공중합 : I. 촉매의 영향)

  • 이동호;정희경;김우식;민경은;박이순
    • Polymer(Korea)
    • /
    • v.24 no.4
    • /
    • pp.445-452
    • /
    • 2000
  • The copolymerization of ethylene (E) and norbornene (N) was examined by using various metallocene catalysts and modified-MAO(MMAO) cocatalyst. For $C_2$-symmetry catalysts such as rac-Et(Ind)$_2$ZrC $l_2$, M $e_2$Si(Ind)$_2$ZrC $l_2$, M $e_2$Si(Cp)$_2$ZrC $l_2$ and Cs-symmetrical iPr(FluCp)ZrC $l_2$ as well as CGC and di-bridged zirconocene, the effects of catalyst structure and [N]/[E] feed ratio on catalyst activity, thermal property and [N] content of copolymer (COC) was investigated. For rac-Et(Ind)$_2$ZrC $l_2$ catalyst of a constant [N]/[E] feed ratio, the appropriate conditions of [Al]/[Zr] mole ratio, polymerization temperature and cocatalyst structure were found to be 3000, 4$0^{\circ}C$, MMAO cocatalyst, respectively. As [N]/[E] feed ratio increased, the incorporation of norbornene to copolymer increased while, the activity of catalyst decreased except for iPr(FluCp)ZrC $l_2$ With consideration of catalyst activity as well as N content, it was found that rac-Et(Ind)$_2$ZrC $l_2$/MMAO system exhibited relatively high activity and controllable $T_{g}$. Monomer reactivity ratio was determined by Kelen-Tudos method..

  • PDF

STRONG CONVERGENCE OF COMPOSITE ITERATIVE METHODS FOR NONEXPANSIVE MAPPINGS

  • Jung, Jong-Soo
    • Journal of the Korean Mathematical Society
    • /
    • v.46 no.6
    • /
    • pp.1151-1164
    • /
    • 2009
  • Let E be a reflexive Banach space with a weakly sequentially continuous duality mapping, C be a nonempty closed convex subset of E, f : C $\rightarrow$C a contractive mapping (or a weakly contractive mapping), and T : C $\rightarrow$ C a nonexpansive mapping with the fixed point set F(T) ${\neq}{\emptyset}$. Let {$x_n$} be generated by a new composite iterative scheme: $y_n={\lambda}_nf(x_n)+(1-{\lambda}_n)Tx_n$, $x_{n+1}=(1-{\beta}_n)y_n+{\beta}_nTy_n$, ($n{\geq}0$). It is proved that {$x_n$} converges strongly to a point in F(T), which is a solution of certain variational inequality provided the sequence {$\lambda_n$} $\subset$ (0, 1) satisfies $lim_{n{\rightarrow}{\infty}}{\lambda}_n$ = 0 and $\sum_{n=0}^{\infty}{\lambda}_n={\infty}$, {$\beta_n$} $\subset$ [0, a) for some 0 < a < 1 and the sequence {$x_n$} is asymptotically regular.