• Title/Summary/Keyword: Bulk samples

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Structural and Magnetic Properties of LaFeO3-BaTiO3 Solid Solutions

  • Ramana, E.Venkata;Kwon, O-Ung;Kim, Jin-I;Jung, C.U.
    • Journal of Magnetics
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    • v.14 no.3
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    • pp.117-119
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    • 2009
  • Polycrystalline samples of LaFe$O_3$-BaTi$O_3$ were synthesized to examine the structural and magnetic behavior. X-ray diffraction confirmed that the ceramics had tetragonal symmetry with less tetragonal strain (c/a) than BaTi$O_3$. The magnetic hysteresis measured at room temperature suggested that the magnetic nature deviates from that of the parent LaFe$O_3$, which has antiferromagentic with a G-type spin structure. Improved magnetic behavior of the solid solution compound might be due to the increase in the canting angle of the spin. The presence of oxygen vacancies and fluctuating Fe valence, arising from the substitution of $Ba^{2+}$ and $Ti^{4+}$ at the A- and B-sites of the lattice, might contribute to bulk magnetization. The temperature dependent magnetization indicated that magnetization was higher at low temperatures and showed a decreasing trend with increasing temperature to room temperature. The magnetic transition temperature of these samples was 665 K and 743 K for the mixed system and LaFe$O_3$, respectively.

Evaluation of the radiopacity of restorative materials with different structures and thicknesses using a digital radiography system

  • Yaylaci, Ayla;Karaarslan, Emine Sirin;Hatırli, Huseyin
    • Imaging Science in Dentistry
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    • v.51 no.3
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    • pp.261-269
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    • 2021
  • Purpose: The aim of this study was to evaluate the radiopacities of various types of restorative materials with different thicknesses compared with enamel, dentin, and aluminum. Materials and Methods: Four bulk-fill resins, 2 hybrid ceramics, 2 micro-hybrid resin composites, 6 glass ionomer-based materials, 2 zinc phosphate cements, and an amalgam were used in the study. Twelve disk-shaped specimens were prepared from each of 17 restorative materials with thicknesses of 1 mm, 2 mm, and 4 mm (n=4). All the restorative material specimens with the same thickness, an aluminum (Al) step wedge, and enamel and dentin specimens were positioned on a phosphor storage plate and exposed using a dental X-ray unit. The mean gray values were measured on digital images and converted to equivalent Al thicknesses. Statistical analyses were performed using 2-way analysis of variance and the Bonferroni post hoc test(P<0.05). Results: Radiopacity was significantly affected by both the thickness and the material type (P<0.05). GCP Glass Fill had the lowest radiopacity value for samples of 1 mm thickness, while Vita Enamic had the lowest radiopacity value for 2-mm-thick and 4-mm-thick samples. The materials with the highest radiopacity values after the amalgam were zinc phosphate cements. Conclusion: Significant differences were observed in the radiopacities of restorative materials with different thicknesses. Radiopacity was affected by both the material type and thickness.

Tritium radioactivity estimation in cement mortar by heat-extraction and liquid scintillation counting

  • Kang, Ki Joon;Bae, Jun Woo;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3798-3807
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    • 2021
  • Tritium extraction from radioactively contaminated cement mortar samples was performed using heating and liquid scintillation counting methods. Tritiated water molecules (HTO) can be present in contaminated water along with water molecules (H2O). Water is one of the primary constituents of cement mortar dough. Therefore, if tritium is present in cement mortar, the buildings and structures using this cement mortar would be contaminated by tritium. The radioactivity level of the materials in the environment exposed to tritium contamination should be determined for their disposal in accordance with the criteria of low-level radioactive waste disposal facility. For our experiments, the cement mortar samples were heated at different temperature conditions using a high-temperature combustion furnace, and the extracted tritium was collected into a 0.1 M nitric acid solution, which was then mixed with a liquid scintillator to be analyzed in a liquid scintillation counter (LSC). The tritium extraction rate from the cement mortar sample was calculated to be 90.91% and 98.54% corresponding to 9 h of heating at temperatures of 200 ℃ and 400 ℃, respectively. The tritium extraction rate was close to 100% at 400 ℃, although the bulk of cement mortar sample was contaminated by tritium.

SWIR-LWIR Photoluminescence from Sb-based Epilayers Grown on GaAs Substrates by using MBE

  • Hussain, Laiq;Pettersson, Hakan;Wang, Qin;Karim, Amir;Anderson, Jan;Jafari, Mehrdad;Song, Jindong;Choi, Won Jun;Han, Il Ki;Lim, Ju Young
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1604-1611
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    • 2018
  • Utilizing Sb-based bulk epilayers on large-scale low-cost substrates such as GaAs for fabricating infrared (IR) photodetectors is presently attracting significant attention worldwide. For this study, three sample series of $GaAs_xSb_{1-x}$, $In_{1-x}Ga_xSb$, and $InAs_xSb_{1-x}$ with different compositions were grown on semi-insulating GaAs substrates by using molecular beam epitaxy (MBE) and appropriate InAs quantum dots (QDs) as a defect-reduction buffer layer. Photoluminescence (PL) signals from these samples were observed over a wide IR wavelength range from $2{\mu}m$ to $12{\mu}m$ in agreement with the expected bandgap, including bowing effects. In particular, interband PL signals from $InAs_xSb_{1-x}$ and $In_{1-x}Ga_xSb$ samples even at room temperature show promising potential for IR photodetector applications.

Influence of multiple holes on the magnetic properties of YBCO superconductor

  • Oh, W.S.;Oh, S.K.;Jang, G.E.;Kim, C.J.;Han, Y.H.;Jung, S.Y.;Sung, T.H.
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.2
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    • pp.15-19
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    • 2009
  • Bulk $YBa_2Cu_3O_{7-{\delta}}$ (YBCO) superconductor was manufactured with the top-seeded melt grown method. The 9, 16, and 25 holes, as small as 0.7mm in diameter, parallel to the c-axis were mechanically drilled. Magnetic flux mapping and levitation force were measured and compared to estimate the influence of multiple holes on the magnetic properties of YBCO superconductor at 77K. According to the measurements, the maximum magnetic flux density obtained from the plain sample was 2.48kG, while the maximum magnetic flux density of the sample with 25 holes was low as around 2.29kG. The levitation force measured on the sample with 9 holes increased from 91N to 105N. The levitation force measured on the samples with 9 holes is relatively higher than the plain sample without any holes. In this case, increase of the levitation force in the perforated samples could be explained by enhancement of the cooling efficiency more effectively. We investigated that the magnetic properties of YBCO superconductor were strongly influenced by the artificial holes.

Comparison of Methods for Detection of Escherichia coli O157:H7 in Ground Beef and Radish Sprouts

  • Lee, Jae-Hoon;Hyeon, Ji-Yeon;Heo, Seok;Hwang, In-Gyun;Kwak, Hyo-Sun;Choi, In-Soo;Park, Chan-Kyu;Seo, Kun-Ho
    • Food Science of Animal Resources
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    • v.30 no.2
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    • pp.179-184
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    • 2010
  • Escherichia coli O157:H7 is a food-borne pathogen that causes bloody diarrhea, hemorrhagic colitis, and hemolytic uremic syndrome (HUS). We compared three selective media and evaluated the performance of immunomagnetic separation (IMS) for the detection of low levels of E. coli O157:H7 in ground beef and radish sprouts with different levels of background flora. Bulk food samples (500 g for each trial) were artificially inoculated with nalidixic acid-resistant E. coli O157:H7 at the lowest dose that would generate 20 partial-positive samples of 25 g each. All samples were homogenized in mTSB (225 mL) and incubated overnight at $37^{\circ}C$. IMS was performed using the enriched mTSB samples (1 mL) along with conventional spreads plated onto three different selective media: Sorbitol MacConkey agar (SMAC), Sorbitol MacConkey agar with cefixime and tellulite (CT-SMAC), and Sorbitol MacConkey agar with nalidixic acid (NAL-SMAC) as the gold standard. Two suspicious colonies from each medium were selected and confirmed usinga serological test after transfer to tryptic soy broth with yeast extract (TSAYE). CT-SMAC was better than SMAC for detecting E. coli O157:H7 in all food types. Although there was no statistical difference in the number of positive samples when using IMS vs. non-IMS techniques, more positive samples were detected when IMS was used in both ground beef and radish sprouts. It appears that the improvement was more significant in radish sprouts, which had a higher level of background flora than ground beef. The results also suggest that the combination of CT-SMAC and IMS is sufficient to recover low levels of E. coli O157:H7 in high background flora food samples.

A Study on the Thermal, Electrical Characteristics of Ge-Se-Te Chalcogenide Material for Use in Phase Change Memory

  • Nam, Ki-Hyun;Chung, Hong-Bay
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.6
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    • pp.223-226
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    • 2008
  • $Ge_1Se_1Te_2$ chalcogenide amorphous materials was prepared by the conventional melt-quenching method. Samples were processed bye-beam evaporator systems and RF-sputtering systems. Phase change characteristics were analyzed by measuring glassification temperature, crystallization temperature and density of bulk material. The thermal characteristics were measured at the temperature between 300 K and 700 K, and the electrical characteristics were studied within the range from 0 V to 3 V. The obtained results agree with the electrothermal model for Phase-Change Random Access Memory.

Dielectric properties of PZT thin films by 2 step sputtering (2단계 스퍼터링에 의한 PZT 박막의 유전특성)

  • Park Sam-Gyu;Mah Jae-Pyung
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.363-366
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    • 2004
  • PZT thin films were formed by rf-magnetron sputtering on $Pt/Ti/SiO_2/Si$ substrate. Bulk PZT target containing $5\%$ excess PbO was used. They were formed with in-situ process at $650^{\circ}C$ as total thickness of 175 and 250 nm after the depositing of thin PZT films at room temperature, i. e. 2-step Sputtering. It was found that the ferroelectric perovskite phase is formed at $650^{\circ}C$ by XRD and the interface between room temp.-layer and $650^{\circ}C$ -layer is not existent. In the samples undergoing 2-step sputtering the dielectric constant was 600 or more and the leakage current density was $2{\times}10^{-7}A/cm^2$. So, we found that the room temp.-layer on the bottom electrode stabilize the underlaid layers.

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The Effect of Microstructure on the Ionic Conductivity in the $Bi_2O_3-CaO$ System ($Bi_2O_3-CaO$계에서의 미세구조가 이온 전도도에 미치는 영향)

  • 백현덕
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.359-365
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    • 1995
  • The grain boundary effect on the ionic conductivity was investigated using a.c. admittance analysis in (Bi2O3)0.715(CaO)0.285 oxygen-ion conducting solid electrolyte. As a separated arc representing grain boundary polarization was not observed in the admittance plane, bulk conductivity was measrued for samples with various grain sizes in the temperature range from 48$0^{\circ}C$ to 72$0^{\circ}C$ and the conductivity distribution between grain interior and grain boundary was determined by the reported analytical methods. In the above temperature range, grain boundary worked as a high conductive path instead of blocking layer and ionic conduction through grain boundary was significant. The activation energy for conduction through grain and grain boundary was 78 and 106 kJ/mol, respectively.

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Herd Reproductive Performance Related to Urea Nitrogen Concentration in Bulk Milk (우유내 요소태 질소 농도와 관련된 우군의 번식성)

  • 박수봉;김현섭;이명식;박진기;장원경;이정규
    • Korean Journal of Animal Reproduction
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    • v.21 no.2
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    • pp.191-195
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    • 1997
  • The objective of this study were to compare two methods of analysis of milk urea nitrogen (MUN) and to relate conentration of MUN to pregnancy rate in dairy cows. The Azotest and Sigma method for MUN analysis were compared. The Azotest consistently underestimated the Sigma values for same samples, except for those in rank 3. The CV for the Azotest, within each rank, were less than 15%, demonstrating acceptable repeatability of the Azotest within a rank. Concentrations of MUN higher or lower than MUN in rank 3 and 4 were associated with decreased pregnancy rate. Mun concentrations in rank 5 and 6 were associated with a, pp.oximately a 16 percentage point decrease in pregnancy rate. Mun concentrations in rank 5 and 6 were associated with a, pp.oximately a 16 percentage point decrease in pregnancy rate after AI in dairy cow. This results suggest that Azotest may be benificial to dairy producers to monitor urea nitrogen concentration in their herd in efforts to maintain or improve reproductive efficiency.

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