• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.210-218
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• 2019

Batch experiment studies were carried out on the adsorption of the major tar compound, 2-picoline, derived from the plant cell cultures of Taxus chinensis, using Sylopute while varying parameters such as initial 2-picoline concentration, contact time and adsorption temperature. The experimental data were fitted to the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. Comparison of results revealed that the Langmuir isotherm model could account for the adsorption isotherm data with the highest accuracy among the four isotherm models considered. From the analysis of adsorption isotherms, it was found that adsorption capacity decreased with increasing temperature and the adsorption of 2-picoline onto Sylopute was favorable. The kinetic data were well described by the pseudo-second-order kinetic model, while intraparticle diffusion and boundary layer diffusion did not play a dominated role in 2-picoline adsorption according to the intraparticle diffusion model. Thermodynamic parameters revealed the exothermic, irreversible and non-spontaneous nature of adsorption. The isosteric heat of adsorption decreased as surface loading ($q_e$) increased, indicating a heterogeneous surface.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.46 no.12
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• pp.986-993
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• 2018

Lateral thrust jet has better maneuverability performance than the control surface like the conventional fin for attitude control or orbital transition of guided weapons. However, in the supersonic region, a jet interaction flow occurs due to the lateral thrust jet during flight, and a complicated flow structure is exhibited by the interaction of the shock wave, boundary layer flow, and the vortex flow. Especially, hit-to-kill interceptors require precise control and maneuvering, so it is necessary to analyze the effect of jet interaction flow. Conventional jet interaction analyses were performed under low altitude conditions, but there are not many cases in the case of medium altitude condition, which has different flow characteristics. In this study, jet interaction flow analysis is performed on the lateral jet controlled interceptor operating at medium altitude. Based on the results, the structural characteristics of the flow field and the changes of aerodynamic coefficient are analyzed.

• Journal of Electrochemical Science and Technology
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• v.10 no.3
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• pp.335-343
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• 2019

In this study, $Sr_2Ni_{1.8}Mo_{0.2}O_{6-{\delta}}$ (SNM) with a double perovskite structure was investigated as an alternative anode for use in the $CH_4$ fuel in solid oxide fuel cells. SNM demonstrates a double perovskite phase over $600^{\circ}C$ and marginal crystallization at higher temperatures. The Ni nanoparticles were exsolved from the SNM anode during the fabrication process. As the SNM anode demonstrates poor electrochemical and electro-catalytic properties in the $H_2$ and $CH_4$ fuels, it was modified by applying a samarium-doped ceria (SDC) coating on its surface to improve the cell performance. As a result of this SDC modification, the cell performance improved from $39.4mW/cm^2$ to $117.7mW/cm^2$ in $H_2$ and from $15.9mW/cm^2$ to $66.6mW/cm^2$ in $CH_4$ at $850^{\circ}C$. The mixed ionic and electronic conductive property of the SDC provided electrochemical oxidation sites that are beyond the triple boundary phase sites in the SNM anode. In addition, the carbon deposition on the SDC thin layer was minimized due to the SDC's excellent oxygen ion conductivity.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.24 no.2
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• pp.249-265
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• 2019

A passive sampler is one of the promising methods to easily and more accurately predict the free dissolved and bioavailable concentration ($C_{free}$) in seawater or pore water in sediments. In Europe and the United States, the use of passive samplers has been highly encouraged for more accurate marine environmental risk assessment. However, long deployment time in the field causes problems such as biofouling of the samplers, so there are few studies using passive samplers in Korea. Therefore, we review the principle and basic characteristics of the passive sampler for persistent organic pollutants, and introduce various improvement cases for the field applications of the passive sampler.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.19 no.1
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• pp.247-252
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• 2019

The diffraction properties of optical signals by multi-layered periodic structures is formulated in two-dimensional space by using Fourier expansions associated with basic grating profile. The fields in each layer are then expressed in terms of characteristic modes, and the complete solution is found rigorously by using a modal transmission-line theory(MTLT) to address the pertinent boundary-value problems. Such an approach can treat periodic arbitrary gratings containing arbitrarily shaped dielectric components, which may generally have optical properties along directions that are parallel or perpendicular to the multi-layers. This paper illustrates the present approach by comparing our numerical results with data reported in the past for simple periodic circular 2D structures. In addition, this proposed theory can apply easily for more complex configurations, which include multiple periodic regions with several possible canonic shapes and high dielectric constants.

• International Journal of High-Rise Buildings
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• v.8 no.2
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• pp.107-116
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• 2019

The use of computational fluid dynamics (CFD) is becoming an increasingly popular means to model wind flows in and around buildings. The first published application of CFD to both indoor and outdoor building airflows was in the 1970's. Since then, CFD usage has expanded to include different aspects of building design. Wind tunnel testing (WTT) on buildings for wind loads goes back as far as 1908. Gustave Eiffel built a pair of wind tunnels in 1908 and 1912. Using these he published wind loads on an aircraft hangar in 1919 as cited in Hoerner (1965 - page 74). The second of these wind tunnels is still in use today for tests including building design ($Damljanovi{\acute{c}}$, 2012). The Empire State Building was tested in 1933 in smooth flow - see Baskaran (1993). The World Trade Center Twin Towers in New York City were wind tunnel tested in the mid-sixties for both wind loads, at Colorado State University (CSU) and the [US] National Physical Laboratory (NPL), as well as pedestrian level winds (PLW) at the University of Western Ontario (UWO) - Baskaran (1993). Since then, the understanding of the planetary boundary layer, recognition of the structures of turbulent wakes, instrumentation, methodologies and analysis have been continuously refined. There is a drive to replace WTT with computational methods, with the rationale that CFD is quicker, less expensive and gives more information and control to the architects. However, there is little information available to building owners and architects on the limitations of CFD for flows around buildings and communities. Hence building owners, developers, engineers and architects are not aware of the risks they incur by using CFD for different studies, traditionally conducted using wind tunnels. This paper will explain what needs to happen for CFD to replace wind tunnels. Ultimately, we anticipate the reader will come to the same conclusion that we have drawn: both WTT and CFD will continue to play important roles in building and infrastructure design. The most pressing challenge for the design and engineering community is to understand the strengths and limitations of each tool so that they can leverage and exploit the benefits that each offers while adhering to our moral and professional obligation to hold paramount the safety, health, and welfare of the public.

• Korean Journal of Environmental Agriculture
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• v.39 no.4
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• pp.289-296
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• 2020

BACKGROUND: There is a need for a revolutionary method to overcome the problem of biochar, which has relatively low adsorption capacity for existing anion pollutants, along with collectively recycling fallen leaves, a kind of forest by-product. Therefore, the objective of this study was to prepare iron-decorated biochar derived from fallen leaves (Fe-FLB), and to evaluate their adsorption properties to Congo red (CR) as anionic dye. METHODS AND RESULTS: The adsorption properties of CR by fallen leaves biochar (FLB) and Fe-FLB were performed under various conditions such as initial CR concentration, reaction time, pH and dosage with isotherm and kinetic models. In this study, Fe-FLB prepared through iron impregnation and pyrolysis of fallen leaves contained 56.9% carbon and 6.3% iron. Congo red adsorption by FLB and Fe-FLB was well described by Langmuir model and pseudo second order model and the maximum adsorption capacities of FLB and Fe-FLB were 1.1 mg/g and 25.6 mg/g, respectively. In particular, it was found that the adsorption of CR was occurred by chemical adsorption process by the outer boundary layer of Fe-FLB. CONCLUSION: Overall, the production of Fe-FLB using fallen leaves and using it as an anion adsorbent is considered to be a way to overcome the problem of biochar with relatively low anion adsorption in addition to the reduction effect of waste.

• Atmosphere
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• v.32 no.4
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• pp.277-295
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• 2022

The global weather prediction model, Korean Integrated Model (KIM), has been in operation since April 2020 by the Korea Meteorological Administration. This study assessed the performance of heat waves (HWs) in Korea in 2020. Case experiments during 2018-2020 were conducted to support the reliability of assessment, and the factors which affect predictability of the HWs were analyzed. Simulated expansion and retreat of the Tibetan High and North Pacific High during the 2020 HW had a good agreement with the analysis. However, the model showed significant cold biases in the maximum surface temperature. It was found that the temperature bias was highly related to underestimation of downward shortwave radiation at surface, which was linked to cloudiness. KIM tended to overestimate nighttime clouds that delayed the dissipation of cloud in the morning, which affected the shortage of downward solar radiation. The vertical profiles of temperature and moisture showed that cold bias and trapped moisture in the lower atmosphere produce favorable conditions for cloud formation over the Yellow Sea, which affected overestimation of cloud in downwind land. Sensitivity test was performed to reduce model bias, which was done by modulating moisture mixing parameter in the boundary layer scheme. Results indicated that the daytime temperature errors were reduced by increase in surface solar irradiance with enhanced cloud dissipation. This study suggested that not only the synoptic features but also the accuracy of low-level temperature and moisture condition played an important role in predicting the maximum temperature during the HWs in medium-range forecasts.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.49 no.2
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• pp.139-146
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• 2021

In hybrid rocket combustion, the oxidizer swirl injection is frequently used to stabilize the combustion as the rotational velocity component affects the boundary layer flow. However, as the swirl strength increases, a problem arises where the combustion performance changes too much. Thus, this study attempts to control the low frequency instability while minimizing the change in combustion performance by adapting attenuated swirl injection with fuel insert used in reference [7]. To this end, a series of experimental tests were performed by varying swirl intensity and the location of the fuel insert. In the tests, the occurrence of combustion instability and combustion performance were closely monitored. The results confirmed that combustion instability was successfully suppressed at the condition of the swirl angle 6 degree and the location of fuel insert 310 mm. And, the changes in combustion pressure, O/F ratio, and fuel regression rate were found as minimal compared to the baseline case. Also the results reconfirmed that the formation of positive coupling between two high frequency oscillations in 500 Hz band, combustion pressure(p') and heat release oscillation(q'), is the necessary and sufficient condition of the occurrence of low frequency instability.

• Journal of the wind engineering institute of Korea
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• v.22 no.4
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• pp.163-169
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• 2018

In this study, wind loads exerted on the offshore wind turbine rotor in parked condition were predicted with variations of wind speeds, yaw angles, azimuth angle, pitch angles, and power of the atmospheric boundary layer profile. The calculated wind loads using blade element theorem were compared with those of estimated aerodynamic loads for the simplified blade shape. Wind loads for an NREL's 5 MW scaled offshore wind turbine rotor were also compared with those of NREL's FAST results for more verification. All of the 6-component wind loads including forces and moments along the three axis were represented on a non-rotating coordinate system fixed at the apex of rotor hub. The calculated wind loads are applicable for the dynamic analysis of the wind turbine system, or obtaining the over-turning moment at the foundation of support structure for wind turbine system.