• Title/Summary/Keyword: Bonding ability

Search Result 125, Processing Time 0.041 seconds

Hydrogen Bonding Analysis of Hydroxyl Groups in Glucose Aqueous Solutions by a Molecular Dynamics Simulation Study

  • Chen, Cong;Li, Wei Zhong;Song, Yong Chen;Weng, Lin Dong;Zhang, Ning
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.7
    • /
    • pp.2238-2246
    • /
    • 2012
  • Molecular dynamics simulations have been performed to investigate hydrogen bonding characteristics of hydroxyl groups in glucose aqueous solutions with different concentrations. The hydrogen bonding abilities and strength of different O and H atom types have been calculated and compared. The acceptor/donor efficiencies have been predicted and it has been found that: (1) O2-HO2 and O3-HO3 are more efficient intramolecular hydrogen bonding acceptors than donors; (2) O1-HO1, O4-HO4 and O6-HO6 are more efficient intramolecular hydrogen bonding donors than acceptors; (5) O1-HO1 and O6-HO6 are more efficient intermolecular hydrogen bonding acceptors than donors while hydroxyl groups O2-HO2 and O4-HO4 are more efficient intermolecular hydrogen bonding donors than acceptors. The hydrogen bonding abilities of hydroxyl groups revealed that: (1) the hydrogen bonding ability of OH2-$H_w$ is larger than that of hydroxyl groups in glucose; (2) among the hydroxyl groups in glucose, the hydrogen bonding ability of O6-HO6 is the largest and the hydrogen bonding ability of O4-HO4 is the smallest; (3) the intermolecular hydrogen bonding ability of O6-HO6 is the largest; (4) the order for intramolecular hydrogen bonding abilities (from large to small) is O2-HO2, O1-HO1, O3-HO3, O6-HO6 and O4-HO4.

A STUDY OF THE DURABILITY OF DENTINAL TUBULE SEALING EFFECTS OF DENTIN BONDING AGENTS (상아질 접착제의 상아세관 밀봉지속효과에 관한 연구)

  • Kim, Eui-Seong;Park, Dong-Soo
    • Restorative Dentistry and Endodontics
    • /
    • v.19 no.1
    • /
    • pp.180-193
    • /
    • 1994
  • The purpose of this study was to observe the sealing ability and durability of All-Bond 2, Gluma Bonding System, Scotch bond 2 and Superbond D-liner which are dentin bonding agents used as desensitizing agents. The durability of the sealing ability of the materials were compared after 0, 140, 420, 840 tooth brushing strokes. 120 extracted teeth were divided into 5 groups and the agents were applied to the exposed dentin. No agents was applied on group I, the control group. Each specimen went through thermocycling from $5^{\circ}$ to $55^{\circ}C$, 200 times. Each group was devide into 4 subgroups and artificial tooth brushing strokes were done for 0, 140, 420, 840 times. Finally the specimens were stored in 0.5 % methylene blue solution for 24 hours in a incubator set at $37^{\circ}C$. The tooth were sectioned perpendicular to the long axis and the dye penetration ratio to the pulp was measured. The following results were obtained. 1. All four dentin bonding agents initially showed excellent sealing ability. 2. All-bond 2, Gluma Bonding System and Superbond D-liner showed durability of dentinal tubule sealing effect after 840 strokes(6-week) artificial tooth brushing. 3. Scotchbond 2 showed a significant decrease in sealing ability after 420 strokes(3-week) artificial tooth brushing. (P<0.05).

  • PDF

THE EFFECT OF DENTIN BONDING AGENTS ON MARGINAL LEAKAGE FOLLOWING RESTORATION ON THE CERVICAL ABRASION (치경부 마모증 수복시 상아질 접착제가 변연누출에 미치는 영향)

  • Koo, Bon-Wook;Son, Ho-Hyun
    • Restorative Dentistry and Endodontics
    • /
    • v.12 no.2
    • /
    • pp.55-63
    • /
    • 1987
  • The purpose of this study is to evaluate the effect of dentin bonding agents on marginal leakage. V-shaped cavities were prepared on the faciocervical area of 140 extracted human teeth. In Groups of twenty cavities, they were restored as follow: Group 1 with enamel bonding resin and Silux, Group 2 Scotchbond and Silux, Group 3 enamel bonding resin and Heliomolar, Group 4 Dentin Adhesit and Heliomolar, Group 5 enamel bonding resin and Durafill, Group 6 Dentin Adhesive and Durafill, Group 7 Chembond. All specimens were thermocycled alternatively at $4^{\circ}C$ and $60^{\circ}C$ of 2% methylene blue dye solution, and sectioned faciolingually with diamond disk under water spray. The sectioned specimens observed with stereo microscope. Following results were obtained: 1. The groups filled with Scotchbond-Silux or Dentin Adhesit-Heliomolar had appeared lesser marginal leakage compared with the groups with enamel bonding resin-Silux or enamel bonding resin-Helimolar. 2. The group filled with Dentin Adhesive-Durafill did not show the reduction of the marginal leakage compared with the group with enamel bonding resin-Durafill. 3. There was significant difference among the four dentin bonding agents. Scotchbond showed the greatest marginal sealing ability, and Dentin Adhesit was the next. The marginal sealing ability of Dentin Adhesive was the worst.

  • PDF

TFT LCD Panel에서의 Bonding Tester를 통한 Sealant 접착력 특성 연구

  • Kim, Dae-Hui;Baek, Seong-Sik;Gang, Sin-U;Choe, Byeong-Deok;Jeong, Han-Uk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2009.11a
    • /
    • pp.198-198
    • /
    • 2009
  • The size of LCD Panel is gradually getting bigger. But the efficient uses of glass and the increasing output of narrow bezel type makes importantly the role of sealant which bonding two glasses. We devised a new tester with pre-inserted blade for interfacial fracture toughness measurement, and evaluated quantitatively bonding ability of sealant. The blade tester has been analyzed with two process parameter, moving speed and inserting depth of blade.

  • PDF

A Study on the Characteristics of Cast Bonding Aluminium Alloy and Fe-17wt%Cr Steel with Vacuum Die Casting (진공다이캐스트법에 의한 Al합금과 Fe-17wt%Cr 강의 주조접합 특성연구)

  • Kim, Yong-Hyun;Kim, Eok-Soo;Kim, Heung-Sik;Lee, Kwang-Hak
    • Journal of Korea Foundry Society
    • /
    • v.19 no.5
    • /
    • pp.410-418
    • /
    • 1999
  • To overcome the undesirable deformation, peeling off and geometrical restrictions which were mainly caused by differences in thermal expansion coefficients during the cladding of aluminum strip and stainless strip, new processing method based on vacuum die casting is designed and implemented in fabricating Fe-17wt%Cr steel (stainless steel). To increase cast-bonding ability, the surface of Fe-17wt%Cr steel is electrochemical etched to have optimum pit size (above 0.2 mm) and pit density (above 30%). The implementation of vacuum die casting by using surface treated stainless steel (Fe-17wt%Cr Steel) produces good trial products having acceptable cast-bonding ability. The enabling conditions for cast-bonding are pouring temperature $690^{\circ}C$, filling speed 30 m/sec and casting pressure $800\;kg/cm^2$. The microscopic observation of cast-bonded Al/Fe-17wt%Cr steel does not show any evidence of intermetallic compounds. The bonding strength of trial products is $150-400\;kg/cm^2$ and this is stronger than conventionally cladded metal having $30-70\;kg/cm^2$.

  • PDF

A Study on the Diffusion Bonding of Mg-Ni under Low Eutectic Temperature (최소 공정온도하에서 Mg-Ni의 열확산 접합에 관한 연구)

  • Jin, Yeung Jun
    • Journal of the Korean Society of Safety
    • /
    • v.32 no.1
    • /
    • pp.9-14
    • /
    • 2017
  • Diffusion bonding is a technique that has the ability to join materials with minimum change in joint micro-structure and deformation of the component. The quality of the joints produced was examined by metallurgical characterization and the joint micro-structure developed across the diffusion bonding was related to changes in mechanical properties as a function of the bonding time. An increase in bonding time also resulted in an increase in the micro-hardness of the joint interface from 55 VHN to 180 VHN, The increase in hardness was attributed to the formation of intermetallic compounds which increased in concentration as bonding time increased.

Dyeing of Thermal Bonded Polyester Fabric by using Low-melting-point Bicomponent Filament Yarn - Head tie - (저융점 복합사에 의해 열융착된 폴리에스테르 직물의 염색 - 헤드타이를 중심으로 -)

  • Ji, Myeong-Gyo;Lee, Shin-Hee
    • Fashion & Textile Research Journal
    • /
    • v.11 no.4
    • /
    • pp.661-666
    • /
    • 2009
  • The purpose of this study is to analyze the dyeability of polyester(PET) fabric by thermal bonding with low melting component of bicomponent fiber and to describe the change of physical properties of thermal bonded PET fabrics. The PET fabrics were prepared with regular PET fiber as warp and bicomponent fiber as weft. The bicomponent fiber of sheath-core type was composed with a regular PET core and low melting PET sheath. The thermal bonding of PET fabric was carried out in pin tenter($195^{\circ}C$) for 60 seconds. In this study, we investigated the dye ability and fastness of the dyed PET fabric. Dye ability of E-type dyestuff is higher than S-type dyestuff. In the case of E- type dyestuff, the saturated dyeing time was 10minutes at $130^{\circ}C$. The washing fastness and light fastness were excellent as 4-5grade.

The Temperature Dependence of the Diffusion Bonding Between Tungsten Carbides for Micro WC-PCD Tool Fabrication (초소형 초경 PCD Tool 제작을 위한 초경합금간 확산접합의 온도 의존성 연구)

  • Jeong, B.W.;Park, J.W.
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.22 no.5
    • /
    • pp.812-817
    • /
    • 2013
  • This study demonstrates the diffusion bonding process between a tungsten carbide shank (K30) and tungsten carbide (DX5) for micro WC-PCD tool fabrication. A type of nickel alloy was used as the filler met alto improve the bond ability between K30 and DX5. The bonding pressure, time, and surrounding conditions were kept constant. In particular, the normal pressure was controlled precisely under buckling analysis. Diffusion bonding was performed at various operation temperatures (1170-1770 K) by using a specially designed jig. The microstructure on the localized bonded surface was analyzed using scanning electron microscopy and optical microscopy. In the case of diffusion bonding of WCat 1370-1770K, the filler metal melted completely and diffused between the two base metals, and they were bonded more tightly on both sides than at temperatures below 1370 K. Our results demonstrated the importance of sensitive temperature dependence of diffusion bonding.

Campers' Place Bonding: a Case Study in Worak-san National Park

  • Shin, Won Sop;Kim, Bum Soo
    • Journal of Korean Society of Forest Science
    • /
    • v.94 no.2 s.159
    • /
    • pp.90-95
    • /
    • 2005
  • Place bonding, defined as the extent to which a person values or identifies with a particular environment, has focused as a research topic recently. This paper investigates the dimensions of place bonding for Worak-san National Park campers to enhance managers' ability to address deeper landscape meanings. Worak-san National Park campers (n=416) were surveyed during summer and fall of 2004 to collect the data. Confirmatory factor analysis of the data demonstrated that place bonding was composed of four dimensions such as place identity, familiarity, place dependence and place belongingness. The results of this study can provide valuation information for developing management actions to enhance park visitors' quality of recreational experiences.