• Journal of the Korean Society of Safety
• /
• v.17 no.2
• /
• pp.39-44
• /
• 2002

This study was investigated the thermal decomposition characteristics of azo type sponge blowing agent azodicarbonamide(ADCA) using differential scanning calorimeter(DSC). The experimental results showed that the exothermic onset $temperatures(T_{o})$ for ADCA were about $201{\sim}206^{\circ}C$ and evolution heats(Q) were about $144{\sim}150cal/g$. The exothermic onset $temperatures(T_{o})$, exothermic maximum $temperature(T_{m})$ and exothermic final $temperature(T_{f})$ were decreased by decreasing particle size of ADCA and evolution heats(Q) were increased with it. $T_{o}$ and Q for $6.1{\sim}7.2{\mu}m$ ADCA were increased by increasing heating rate at constant sample weight and activation energy was about 37.29kcal/mol. A positive gas pressure was employed in the elucidation of the decomposition behavior of ADCA because it sublimes during linear heating at atmospheric pressure. $T_{o}$ and Q of ADCA tended to increase with a pressure in air or nitrogen. In the case of azo dye, experimental results showed that $T_{o}$ were about $280{\sim}420^{\circ}C$ and Q were about $2{\sim}30cal/g$.

• Polymer(Korea)
• /
• v.29 no.6
• /
• pp.557-564
• /
• 2005

Thermoplastic starch (TPS) was manufactured and blended with poly(butylene adipate-co-succinate) (PBAS), which is one of the most popular biodegradable aliphatic polyesters. The effects of the TPS contents on the mechanical properties, thermal characteristics, and biodegradability of PBAS/TPS blends were investigated. The foaming characteristics of those were also studied. With small amount of TPS, mechanical properties of the blends were largely deteriorated and the variations of them decreased with more addition of TPS. In addition, TPS decreased crystallinity and thermal decomposition temperature of PBAS. The PBAS/TPS foam having maximum blowing ratio was obtained with 20 Phr of TPS, and their blowing ratio decreased with the further increase of TPS.

• Journal of Korean Society for Atmospheric Environment
• /
• v.16 no.3
• /
• pp.225-236
• /
• 2000

Diurnal variations of wind field and pollutant dispersion over the Yosu area under the insolation conditions of summer and winter were investigated by using the Regional Atmospheric Modeling System (RAMS). Initially, horizontally homogeneous wind field were assumed on the basis of sounding data at the Kwangju upper-air station for days whose morning wind speeds were below 2m/s. In these days, the sea breeze prevailed in summer while the land breeze lasted for a few hours in the morning; the effect of synoptic winds was strong in winter with some inclusion of wind variations owing to the interaction between sea and land. The predicted wind direction at the location of the Yosu weather station captured an important change of the sea-land breeze of the observed one. The predicted wind speed and the air temperature agreed with observed ones in a reasonable range. In the morning, both in summer and winter, winds around the source location were diverged and became weak between the mountainous area to the southeast and the Kwangyang Bay to the north. Winds, however, accelerated while blowing to the east and south and blowing on the mountainous area. Complicated wind fields resulted in high pollutant concentrations at almost all receptors considered. These high concentrations in the morning were even comparable to the ISCST3 calculations with the worst-case and typical meteorological conditions designated by USEPA(1996). On the other hand, in the afternoon, the wind field was rather uniform even in the mountainous area with development of mixing layer and the concentration distributions being close to the Gaussian distributions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.8 no.3
• /
• pp.437-450
• /
• 1996

A set of stability equations is formulated for natural convection flows adjacent to a vertical isothermal surface melting in cold pure water. It takes account of the nonparallelism of the base flows. The melting rate is regarded as a blowing velocity at the ice surface. The numerical solutions of the linear stability equations which constitute a two-point boundary value problem are accurately obtained for various values of the density extremum parameter $R=(T_m-T_{\infty})/(T_0-T_{\infty})$ in the range $0.3{\leq}R{\leq}0.6$, by using a computer code COLNEW. The blowing effects on the base flow becomes more significant as ambient temperature ($T_{\infty}$) increases to $T_{\infty}=10^{\circ}C$. The maximum decrease of heat transfer rate is about 6.4 percent. The stability results show that the melting at surface causes the critical Grashof number $G^*$ and the maximum frequency of disturbances to decrease. In comparision with the results for the conventional parallel flow model, the nonparallel flow model has a higher critical Grashof number but has lower amplification rates of disturbances than does the parallel flow model. The spatial amplification contours exhibit that the selective frequency $B_0$ of the nonparallel flow model is higher than that of the parallel flow model and that the effects of melting are rather small. The present study also indicates that the selective frequency $B_0$ can be easily predicted by the value of the frequency parameter $B^*$ at $G^*$, which comes from the neutral stability results of the nonparallel flow model.

• Journal of the Korean Chemical Society
• /
• v.21 no.1
• /
• pp.53-59
• /
• 1977

A method of synthesizing $NaAlCO_3(OH)_2$ (Dawsonite) and $KAlCO_3(OH)_2$, was investigated by blowing $CO_2$ gas into sodium and potassium aluminate solutions. The reactions were accomplished at a temperature of 80 to $90^{\circ}C$, while $CO_2$ gas was blowing into the solutions which the molar ratios of $Na_2O/Al_2O_3,\;and\;K_2O/Al_2O_3$ were 6 to 8 and 8 to 10, respectively. It was observed that highly purified Dawsonite and $KAlCO_3(OH)_2$ are produced when Alumina is present in Boehmite at an equilibrium solid phase with a large amount of $HCO_3^-$ in the solutions. The rational formulas of Dawsonite and $KAlCO_3(OH)_2$synthesized under the conditions should be expressed as $NaAlO(OH)HCO_3\;and\;KAlO(OH)HCO_3$, respectively, by IR analysis. In addition, electron microscopic observation also indicated that Dawsonite in a fibrous crystal and $KAlCO_3(OH)_2$ in a needleshaped crystal.

• Journal of the Korean Society for Precision Engineering
• /
• v.33 no.5
• /
• pp.333-339
• /
• 2016

In this paper, a fundamental experiment regarding the formation of porous 3D structures for personal safety products using 3D PPP (Porous Polymer Printing) was introduced for the first time. The filament was manufactured by mixing PP (Polypropylene) and CBA (Chemical Blowing Agent) with polymer extruder, and the diameter of the filament was approximately 1.75mm. The proposed 3D PPP method, combined with the conventional FDM (Fused Deposition Modeling) procedure, was influenced by process parameters, such as the nozzle temperature, printing speed and CBA density. In order to verify the best processing conditions, the depositing parameters were experimentally investigated for the porous polymer structure. These results provide parameters under which to form a multiple of 3D porous polymer structures, as well as various other 3D structures, and help to improve the mechanical shock absorption for personal safety products.

• Applied Chemistry for Engineering
• /
• v.31 no.6
• /
• pp.630-634
• /
• 2020

We developed a processing recipe to synthesize flexible polyurethane foam with a pore size of 335 ± 107 ㎛. The gelling reaction time was varied from 0 to 30 minutes and the physical properties of the foam were evaluated. The gelling reaction where the polypropylene glycol and tolylene 2,4-diisocyanate (TDI) were reacted to form urethane prepolymer, proceeded until a chemical blowing agent, deionized water, was introduced. Fourier transform infrared (FT-IR) spectra showed that the composition of the foam did not change but the foam height reached a peak value when the gelling reaction time was 10 minutes. We found that increasing the gelling time lessened the coalescence and helped the formation of cells. Lastly, the repeatability of polyurethane foam was confirmed by one-way analysis of variance (ANOVA) by synthesizing ten identical polyurethane foams under the same experimental conditions, including the gelling reaction time. Overall, the new time parameter in-between the gelling and blowing reactions will give extra stability in manufacturing identical polyurethane foams and can be applied to various polyurethane foam processes.

• Korean Journal of Materials Research
• /
• v.21 no.1
• /
• pp.39-45
• /
• 2011

In this study, the heat flow of the plant scale aluminum extrusion process was investigated to establish optimum continuous heat treatment conditions. During the extrusion of 6061 aluminum alloy, processing parameters such as the extrusion pressure, speed and temperature histories of billets were logged as a function of time. The surface temperature of the billets increased at constant ram speed, while it decreased with decreases of the ram speed. In order to maintain the billet temperature within a solutionizing temperature range prior to the succeeding water quenching step, the ram speed or the temperature of the blower should be controlled. The temperature histories of the billets during the extrusion and hot air blowing processes were successfully simulated by using the velocity boundary model in ANSYS CFX. The methodology to design an optimum process by using a commercial simulation program is described in this study on the basis of the metallurgical validation results of the microstructural observation of the extrudates. The developed model allowed the advantages of taking into account the motion of the extrudate coupled with the temperature change based on empirical data. Calculations were made for the extrudate passing through the isothermal chamber maintained at appropriate temperature. It was confirmed that the continuous heat treatment system is beneficial to the productivity enhancement of the commercial aluminum extrusion industry.

• Polymer(Korea)
• /
• v.38 no.4
• /
• pp.441-448
• /
• 2014

Polyurethane/melamine phosphate composite foam (MP-PUF) was prepared from poly(adipate)diol/melamine phosphate composite (f=2), polyether-polyol (f=4.6), and PMDI (f=2.5). The thermal properties of MP-PUF such as morphology, closed-cell content, thermal conductivity, and thermal stabilities were characterized. Water was used as a blowing agent, and the composition of melamine phosphate (MP) was maintained at $1.43{\pm}0.3wt%$ of MP-PUF. As the content of water increased, the thermal conductivity of pure polyurethane foam (PUF) decreased, whereas the thermal conductivity of MP-PUF increased. The thermal stabilities of the PUF and the MP-PUF were maximized at 5 php $H_2O$, and then decreased at the higher $H_2O$ contents. The thermal stabilities of MP-PUF were greatly enhanced due to the synergetic effect of MP and urea, which was generated during the blowing process. The temperature of 50% residual mass of MP-PUF increased to $370{\sim}450^{\circ}C$ and the temperature of 30% residual mass exceeded over $700^{\circ}C$. Compared to the PUF, the temperature of 50% residual mass and 30% residual mass were higher than 25 and $70^{\circ}C$, respectively.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2004.10a
• /
• pp.143-146
• /
• 2004

Pultrusion process of phenolic foam composite is investigated. Phenolic foam composites provide heat and flame resistance with less weight. When made into foam, a variety of properties can be obtained with different bubble size and number density. In this study, effect of process variables on the foaming characteristics of phenolic resin composites during pultrusion process has been studied experimentally. The process variables considered are the heating temperature and the pulling speed as well as the mass fraction of blowing agent. Experiments were performed using a laboratory scale pultrusion apparatus. Optimal process condition was found by observing the micro-morphology.