• 한국식품저장유통학회지
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• 제4권3호
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• pp.343-349
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• 1997

The rheological Voperties of biopolymers produced by Bacilli sp. K-1 and its mutant strains(KM-21, KM-83) were studied at the temperature ranges with 20∼80$^{\circ}C$, at the concenration of 2∼6%, at the pH ranges from 3.0 to 9.0 and at the shear rate of 9.3-930sec-1 The apparent viscosity of biopolymers was decreased with increasing shear rate, and thereby biopolymers showed pseudoplastic characteristics. It was found that the apparent viscosity models respected 19 temperature, concentration and both temperature and concentration were expressed by Arrhenius Model, Exponential Model and combined of the above two Models. Therefore, the apparent viscosity could be predictable by Arrhenius and Exponential Models with high R2.

• 한국정밀공학회지
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• 제23권12호
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• pp.16-20
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• 2006

• Geomechanics and Engineering
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• 제12권5호
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• pp.815-830
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• 2017

Due to numerous environmental concerns in recent years, the search for and the development of sustainable technologies have been pursued. In particular, environmentally friendly methods of soil improvement, such as the potential use of biopolymers, have been researched. Previous studies on the use of biopolymers in soil improvement have shown that they can provide substantial strengthening efficiencies. However, in order to fully understand the applicability of biopolymer treated soils, various properties of these soils such as their dynamic properties must be considered. In this study, the dynamic properties of gel-type biopolymer treated soils were observed through the use of resonant column tests. Gellan gum and Xanthan gums were the target gel-type biopolymers used in this study, and the target soil for this study was jumunjin sand, the standard sand of Korea. Through this study it was demonstrated that biopolymers can be used to enhance the dynamic properties of the soil, and that they offer possibilities of reuse to reduce earthquake related soil failures.

• Geomechanics and Engineering
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• 제25권1호
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• pp.49-58
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• 2021

The resistance of soil to the tractive force of flowing water is one of the essential parameters for the stability of the soil when directly exposed to the movement of water such as in rivers and ocean beds. Biopolymers, which are new to sustainable geotechnical engineering practices, are known to enhance the mechanical properties of soil. This study addresses the surface erosion resistance of river-sand treated with several biopolymers that originated from micro-organisms, plants, and dairy products. We used a state-of-the-art erosion function apparatus with P-wave reflection monitoring. Experimental results have shown that biopolymers significantly improve the erosion resistance of soil surfaces. Specifically, the critical shear stress (i.e., the minimum shear stress needed to detach individual soil grains) of biopolymer-treated soils increased by 2 to 500 times. The erodibility coefficient (i.e., the rate of increase in erodibility as the shear stress increases) decreased following biopolymer treatment from 1 × 10-2 to 1 × 10-6 times compared to that of untreated river-sands. The scour prediction calculated using the SRICOS-EFA program has shown that a height of 14 m of an untreated surface is eroded during the ten years flow of the Nakdong River, while biopolymer treatment reduced this height to less than 2.5 m. The result of this study has demonstrated the possibility of cross-linked biopolymers for river-bed stabilization agents.

• Geomechanics and Engineering
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• 제12권5호
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• pp.849-862
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• 2017

With growing interests in using bacterial biopolymers in geotechnical practices, identifying mechanical properties of soft gel-like biopolymers is important in predicting their efficacy in soil modification and treatment. As one of the promising candidates, dextran was found to be produced by Leuconostoc mesenteroides. The model bacteria utilize sucrose as working material and synthesize both soluble and insoluble dextran which forms a complex and inhomogeneous polymer network. However, the traditional rheometer has a limitation to capture in situ properties of inherently porous and inhomogeneous biopolymers. Therefore, we used the particle tracking microrheology to characterize the material properties of the dextran polymer. TEM images revealed a range of pore size mostly less than $20{\mu}m$, showing large pores > $2{\mu}m$ and small pores within the solid matrix whose sizes are less than $1{\mu}m$. Microrheology data showed two distinct regimes in the bacterial dextran, purely viscous pore region of soluble dextran and viscoelastic region of the solid part of insoluble dextran matrix. Diffusive beads represented the soluble dextran dissolved in an aqueous phase, of which viscosity was three times higher than the growth medium viscosity. The local properties of the insoluble dextran were extracted from the results of the minimally moving beads embedded in the dextran matrix or trapped in small pores. At high frequency (${\omega}>0.2Hz$), the insoluble dextran showed the elastic behavior with the storage modulus of ~0.1 Pa. As frequency decreased, the insoluble dextran matrix exhibited the viscoelastic behavior with the decreasing storage modulus in the range of ${\sim}0.1-10^{-3}Pa$ and the increasing loss modulus in the range of ${\sim}10^{-4}-1\;Pa$. The obtained results provide a compilation of frequency-dependent rheological or viscoelastic properties of soft gel-like porous biopolymers at the particular conditions where soil bacteria produce bacterial biopolymers in subsurface.

• Geomechanics and Engineering
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• 제17권5호
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• pp.453-464
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• 2019

Soft marine soil has high fine-grained soil content and in-situ water content. Thus, it has low shear strength and bearing capacity and is susceptible to a large settlement, which leads to difficulties with coastal infrastructure construction. Therefore, strength improvement and settlement control are essential considerations for construction on soft marine soil deposits. Biopolymers show their potential for improving soil stability, which can reduce the environmental drawbacks of conventional soil treatment. This study used two biopolymers, an anionic xanthan gum biopolymer and a cationic ${\varepsilon}-polylysine$ biopolymer, as representatives to enhance the geotechnical engineering properties of soft marine soil. Effects of the biopolymers on marine soil were analyzed through a series of experiments considering the Atterberg limits, shear strength at a constant water content, compressive strength in a dry condition, laboratory consolidation, and sedimentation. Xanthan gum treatment affects the Atterberg limits, shear strength, and compressive strength by interparticle bonding and the formation of a viscous hydrogel. However, xanthan gum delays the consolidation procedure and increases the compressibility of soils. While ${\varepsilon}-polylysine$ treatment does not affect compressive strength, it shows potential for coagulating soil particles in a suspension state. ${\varepsilon}-Polylysine$ forms bridges between soil particles, showing an increase in settling velocity and final sediment density. The results of this study show various potential applications of biopolymers. Xanthan gum biopolymer was identified as a soil strengthening material, while ${\varepsilon}-polylysine$ biopolymer can be applied as a soil-coagulating material.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.243.1-243.1
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• 2010

Devices based on nanomaterials platforms are emerging as a powerful tool for ultrasensitive sensors for the direct detection of biological and chemical species. In this talk, we will report the preparation and the full characterization of electrochemical polymerization of biopolymers platforms and nano-structure formation for electrochemical detection of enzymatic activity and toxic compound in electrolyte for biosensor applications. Formation of an electroactive polymer film of two different compounds has been quantified by observing new redox peak at higher potentials in cyclic voltammogram measurements. RCT value of at various biopolymer concentration based hybrid films has been obtained from electrochemical impedance spectroscopy analysis and possible mechanism for formation of complexes during electrochemical polymerization on conducting substrates has been investigated. Biosensors developed based on these hybrid biopolymers have very high sensitivity.

• KSBB Journal
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• 제25권5호
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• pp.409-420
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• 2010

Biopolymer-based materials recently have garnered considerable interest as they can decrease dependency on fossil fuel. Biopolymers are naturally obtainable macromolecules including polysaccharides, polyphenols, polyesters, polyamides, and proteins, that play an important role in biomedical applications such as tissue engineering, regenerative medicine, drug-delivery systems, and biosensors, because of their inherent biocompatibility and biodegradability. However, the insolubility of unmodified biopolymers in most organic solvents has limited the applications of biopolymer-based materials and composites. Ionic liquids (ILs) are good solvents for polar organic, nonpolar organic, inorganic and polymeric compounds. Biopolymers such as cellulose, chitin/chitiosan, silk, and DNA can be fabricated from ILs into films, membranes, fibers, spheres, and molded shapes. Various biopolymer/biopolymer and biopolymer/synthetic polymer composites also can be prepared by co-dissolution of polymers into IL mixtures. Heparin/biopolymer composites are especially of interest in preparing materials with enhanced blood compatibility.

• Journal of Dairy Science and Biotechnology
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• 제36권4호
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• pp.187-195
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• 2018

Nano-delivery systems, such as nanoparticles, nanoemulsions, and nanoliposomes, are carriers that have been used to enhance the chemical as well as physical stability and bioavailability of bioactive compound. Food-grade nano-delivery system can be produced with edible biopolymers including proteins and carbohydrates. In addition to the low-toxicity, biocompatibility, and biodegradability of these biopolymers, their functional characteristics, such as their ability to bind hydrophobic bioactive compounds and form a gel, make them potential and ideal candidates for the fortification of bioactive compounds in functional dairy foods. This review focuses on different types of nano-delivery systems and edible biopolymers as delivery materials. In addition, the applications of food-grade nano-delivery systems to dairy foods are also described.

• 생명과학회지
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• 제29권3호
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• pp.382-393
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• 2019

상처 치료는 전세계 인류에 영향을 미치는 보건 산업계의 관심사다. 당뇨병과 같은 대사증후군 유병률 증가로 상처에 의한 합병증의 위험이 높아지고 상처치유의 복잡함 때문에 상처의 치료와 관리가 어렵다. 전통적 상처 드레싱은 제한된 보호기능을 제공하며, 상처 드레싱의 치료 능력을 향상시키기 위해 생체고분자 기반의 드레싱들이 개발되고있다. 생체고분자는 생분해성이 뛰어나고 생체적합성이 좋으며 효과적인 상처 관리에 중요한 항균, 항염증, 지혈, 세포증식, 혈관성 활동 등 다양한 효과가 있다. 키토산, 셀룰로오스, 콜라겐, 히알루론산, 알긴산 등의 여러 생체고분자가 이미 상처치유제로 활용되고 있으며 생체고분자를 다른 고분자, 생체활성 분자 및 약물과 결합하여 생리학적 문제 없이 흉터를 최소화하는 새로운 상처 드레싱이 개발되고 있다. 본 논문에서는, 향후의 연구와 활용을 위한 현재의 생체고분자의 상처처리에 대해 알아보았다.