• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 2003년도 International Symposium on Clean Environment
• /
• pp.79-84
• /
• 2003

The main objective of this study was to investigate the chemical characteristics of post-harvest biomass burning aerosols from field burning of barley straw in late spring and rice straw in late fall in rural area in Korea. 12-hr integrated intensive sampling of $PM_{10}$ and $PM_{2.5}$ biomass burning aerosols had been conducted continuously at Gwangju, Korea 4-15 June 2001 and 8 October-14 November 2002. The fine and coarse particles of biomass burning aerosols were collected for mass, ionic, elemental, and carbonaceous species analysis. Average fine and coarse mass concentrations of biomass burning aerosols were measured to be 129.6, 24.2 ${{\mu}gm}^{-3}$ in June 2001 and 47.1, 33.2 ${{\mu}gm}^{-3}$ in October to November 2002, respectively. Exceptionally high level of $PM_{2.5}$ concentration up to 157.8 ${{\mu}gm}^{-3}$ well above 24-hour standard was observed during the biomass burning event days under stagnant atmosphere condition. During biomass burning periods dominant ionic species were $Cl^{-}$, ${NO_3}^{-}$, ${SO_4}^{2-}$, and ${NH_4}^{+}$ in fine and coarse mode. In the fine mode $Cl^{-}$ and ${KCl}^{+}$ were unusually rich due to the high content of the semiarid vegetation. High OC values and OC/EC ratios were also measured during the biomass burning periods. Increased amount of fine aerosols with high enrichment, which were originated from biomass burning of post-harvest agricultural waste, resulted in extremely severe particulate air pollution and visibility degradation in the region. Particulate matters from open field burning of agricultural wastes cause great adverse impact on local air quality and regional climate.

• Asian Journal of Atmospheric Environment
• /
• 제5권2호
• /
• pp.79-85
• /
• 2011

The purpose of this study is to evaluate the strength of the near-UV wavelength of 380 nm relative to visible and near-IR bands, and to find the suitable wavelength for detecting aerosols by using the Global Imager (GLI) sensor aboard the Advanced Earth Observing Satellite-II (ADEOS-II). Sensitivity analysis is performed for the retrieval of biomass burning aerosols by employing the radiative transfer model Rstar5b. It is determined that background surface reflectance in the blue band is similar to that in the near-UV band, and that wavelengths in the blue bands are more sensitive to the Aerosol Optical Thickness (AOT) than wavelengths in the near-UV band. The Total Ozone Mapping Spectrometer (TOMS) Aerosol Index (AI) is used in the indirect method used for aerosol retrieval, and the wavelength pair 380 nm and 460 nm is determined to be the most sensitive to the AOT. The results of this study suggest that wavelengths in the blue bands are suitable for detecting biomass burning aerosols over the Korean peninsula.

• Journal of Korean Society for Atmospheric Environment
• /
• 제24권E1호
• /
• pp.32-43
• /
• 2008

Source samples were collected to construct source profiles for 9 different source types, including soil, road dust, gasoline/diesel-powered vehicles, a municipal incinerator, industrial sources, agricultural/biomass burning, marine aerosol, and a coal-fired power plant. Seasonal profiles for 'Chinese aerosol', aerosols derived from the urban area of China, were reconstructed from seasonal $PM_{2.5}$ compositions reported in Beijing, China. Ambient $PM_{2.5}$ at a receptor site was also measured during each of the four seasons, from April 2001 to February 2002, in Seoul. The Chemical Mass Balance receptor model was applied to quantify source contributions during the study period using the estimated source profiles. Consequently, motor vehicle exhaust (33.0%), in particular 23.9% for diesel-powered vehicles, was the largest contributor affecting the $PM_{2.5}$ levels in Seoul, followed by agricultural/biomass burning (21.5%) and 'Chinese aerosol' (13.1%), indicating contributions from long-range transport. The largest contributors by season were: for spring, 'Chinese aerosol' (31.7%); for summer, motor vehicle exhaust (66.9%); and for fall and winter, agricultural/biomass burning (31.1% and 40.1%, respectively). These results show different seasonal patterns and sources affecting the $PM_{2.5}$ level in Seoul, than those previously reported for other cities in the world.

• 한국지리정보학회지
• /
• 제15권1호
• /
• pp.184-196
• /
• 2012

바이오매스 연소 활동은 인위적 또는 자연적인 원인에 의하여 발생하며 연소과정에서 다량의 대기오염물질을 배출한다. 이 과정에서 발생한 온실가스와 대기 에어러솔은 대기환경 저해와 기후변화의 원인으로 알려져 있으나 바이오매스 연소 활동에 대한 감시와 대기환경에 미치는 영향을 파악하기가 쉽지 않다. 본 연구는 동북아 지역의 바이오매스 연소 활동의 현황과 대기환경에 미치는 영향을 평가하고자, 지구관측 위성인 Terra/MODIS 관측 자료를 이용하였다. 바이오매스 연소의 발생 원인은 매우 다양하지만, 주 연료가 공급되는 토지피복과 계절별 변화에 의존하므로, 본 연구에서는 지역별 토지피복과의 관련성과 시간에 따른 현황과 변화 패턴을 분석하였다. 그 결과, 가장 넓은 영역을 차지하고 있는 녹지대 또는 상록수림 지역에서의 발생수가 많았으며, 경작지에도 많은 발생횟수를 나타내었다. 그리고 대기 오염물질 중 하나인 대기 에어러솔의 상대적인 양을 나타내는 에어러솔 광학두께자료와 연소 자료와 비교결과는 두 산출물간 뚜렷한 연중 변화와 관련성이 있는 것으로 나타났다. 즉, 바이오매스 연소 활동이 지역 대기환경에 미치는 영향을 증명하였으며, 중국대륙에서 발생빈도가 증가하고 있어 지역 대기환경 및 기후변화에 영향을 줄 것으로 예상된다.

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2006년도 춘계학술대회 논문집
• /
• pp.55-56
• /
• 2006

This thesis describes the use of measured aerosol size distributions and size-resolved hygroscopic growth to examine the physical and chemical properties of several particle classes. The primary objective of this work was to investigate the optical and cloud forming properties of a range of ambient aerosol types measured in a number of different locations. The tool used for most of these analyses is a differential mobility analyzer / tandem differential mobility analyzer (DMA / TDMA) system developed in our research group. To collect the data described in two of the chapters of this thesis, an aircraft-based version of the DMA / TDMA was deployed to Japan and California. The data described in two other chapters were conveniently collected during a period when the aerosol of interest came to us. The unique aspect of this analysis is the use of these data to isolate the size distributions of distinct aerosol types in order to quantify their optical and cloud forming properties. I used collected data during the Asian Aerosol Characterization Experiment (ACE-Asia) to examine the composition and homogeneity of a complex aerosol generated in the deserts and urban regions of China and other Asian countries. An aircraft-based tandem differential mobility analyzer was used for the first time during this campaign to examine the size-resolved hygroscopic properties of particles having diameters between 40 and 586 nm. Asian Dust Above Monterey (ADAM-2003) study was designed both to evaluate the degree to which models can predict the long-range transport of Asian dust, and to examine the physical and optical properties of that aged dust upon reaching the California coast. Aerosol size distributions and hygroscopic growth are measured in College Station, TX to investigate the cloud nucleating and optical properties of a biomass burning aerosol generated from fires on the Yucatan Peninsula. Measured aerosol size distributions and size-resolved hygroscopicity and volatility were used to infer critical supersaturation distributions of the distinct particle types that were observed during this period. The predicted CCN concentrations were used in a cloud model to determine the impact of the different aerosol types on the expected cloud droplet concentration. RH-dependent aerosol extinction coefficients are calculated at a wavelength of 550 nm.

• 한국대기환경학회지
• /
• 제31권1호
• /
• pp.28-40
• /
• 2015

To investigate the seasonal variations of carbonaceous aerosol in Daejeon, OC (organic carbon), EC (elemental carbon) and WSOC (water soluble organic carbon) in $PM_{2.5}$ samples collected from March 2012 to February 2013 were analyzed. $PM_{2.5}$ concentrations were estimated by the sum of organic matter ($1.6{\times}OC$), EC, water-soluble ions ($Na^+$, $NH_4{^{+}}$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, $SO_4{^{2-}}$, $NO_3{^{-}}$). The estimated $PM_{2.5}$ concentrations were relatively higher in winter ($29.50{\pm}12.04{\mu}g/m^3$) than those in summer ($13.72{\pm}6.92{\mu}g/m^3$). Carbonaceous aerosol ($1.6{\times}OC+EC$) was a significant portion (34~47%) of $PM_{2.5}$ in all season. The seasonally averaged OC and WSOC concentrations were relatively higher in winter ($6.57{\times}3.48{\mu}gC/m^3$ and $4.07{\pm}2.53{\mu}gC/m^3$ respectively), than those in summer ($3.07{\pm}0.8{\mu}gC/m^3$, $1.77{\pm}0.68{\mu}gC/m^3$, respectively). OC was correlated well with WSOC in all season, indicating that they have similar emission sources or formation processes. In summer, both OC and WSOC were weakly correlated with EC and also poorly correlated with a well-known biomass burning tracer, levoglucosan, while WSOC is highly correlated with SOC (secondary organic carbon) and $O_3$. The results suggest that carbonaceous aerosol in summer was highly influenced by secondary formation rather than primary emissions. In contrast, both OC and WSOC in winter were strongly correlated with EC and levoglucosan, indicating that carbonaceous aerosol in winter was closely related to primary source such as biomass burning. The contribution of biomass burning to $PM_{2.5}$ OC and EC, which was estimated using the levoglucosan to OC and EC ratios of potential biomass burning sources, was about $70{\pm}15%$ and $31{\pm}10%$, respectively, in winter. Results from this study clearly show that $PM_{2.5}$ OC has seasonally different chemical characteristics and origins.

• Asian Journal of Atmospheric Environment
• /
• 제7권2호
• /
• pp.95-104
• /
• 2013

The study of carbonaceous aerosols in the atmosphere is critical to understand the role of aerosols in human health and climate. Using standardized thermal optical transmittance methods, organic carbon (OC), elemental carbon (EC), and water soluble organic carbon (WSOC) were determined using a combustion sampling system for four types of agricultural crop residues (rice straw, red pepper stems, soybean stems, and green perilla stems) and eight types of forest trees (pine stems, pine needles, ginkgo stems, ginkgo leaves, maple stems, maple leaves, cherry stems, and cherry leaves). The aerosol particles between 0.056 and $5.6{\mu}m$ in size were analyzed using a Micro-Orifice Uniform Deposit Impactor (MOUDI). In the current study, the Carbonaceous Thermal Distribution (CTD) by carbon analyzer was discussed in order to understand the carbon fractions from the twelve types of biomass burning. Also, the concentration of OC, EC, WSOC, and water insoluble organic carbon (WIOC) detected in the emissions were described.

• 대한원격탐사학회지
• /
• 제21권4호
• /
• pp.273-285
• /
• 2005

본 연구에서는 GLI 센서의 자외선인 380nm, 가시광선 영 역의 400nm와 412nm, 가시광선의 푸른 파장영역인 460nm와 490nm, 근파장 적외선인 2100nm를 비교 분석하여 생체 소각 에어러솔 탐지에 효과적인 파장을 살펴보고자 하였다. 자외선 파장이 지표 반사도가 낮고 BRDF 효과도 작게 나타나므로 에어러솔 추정시 효과적이라고 알려져 있으나 412nm를 제외한 400nm, 460nm, 490nm에서 380nm와 비슷한 지표 반사도를 보였다. 지표 반사도 대비 방법을 2003년 5월에 적용해 에어러솔 반사도를 산출하였을때 460nm의 에어러솔 반사도가 380nm 보다 민감하게 나타났다. GLI의 두파장을 이용해 TOMS 에어러솔 지수를 산출하였을 때 생체 소각 에어러솔은 흡수성 에어러솔로 나타났으며 380nm와 460nm를 이용한 TOMS 에어러솔 지수가 AERONET의 에어러솔 광학 두께와 높은 상관관계를 보이며 에어러솔의 광학 두께에 민감하게 반응하고 있다. 그러므로 생체소각 에어러솔을 탐지할 때에는 가시광선의 푸른색 영역의 파장대가 효과적일 것으로 사료된다.

• 대한원격탐사학회지
• /
• 제30권4호
• /
• pp.417-430
• /
• 2014

본 연구는 현재 NASA에서 제공되는 operational OMI HCHO 관측 값에서 에러를 발견하여, 월평균 HCHO 자료의 시계열에 4 차 다항식을 피팅함으로써 구한 배경 모수화(parameterization)값을 이용하여 OMI HCHO 자료의 보정을 수행하였다. 보정후의 OMI HCHO는 동태평양과 서태평양 지역에서 -1.48%, 0.65%/year 경향성을 보였으며 이 수치는 GOME(-0.99%, 1.1%/year)과 SCAIMACHY(-0.92%, 0.03%/year)의 경향성과 유사한 결과이며 적절하게 비정상적인 배경 HCHO 농도의 증가가 제거되었음을 나타낸다. 이 자료의 검증과 분석은 EOF와 SVD 통계적 분석 방법을 사용하여 아프리카 지역에서 다양한 위성 관측 값과의 (HCHO, CO, $NO_2$ 그리고 firecount) 시공간 변동성의 일치성을 비교 분석함으로써 수행되었다. 아프리카에서 MOPITT CO, OMI $NO_2$, SCIAMAHCY 그리고 OMI HCHO의 EOF와 SVD 분석 결과는 생태계화재(biomass burning)의 시공간 변동성 분포와 매우 높은 일치성을 보여준다. 그러나 OMI HCHO 관측 값은 화재가 가장 강하게 발생하는 지역의 풍하측에서 최대 값이 보이며, 화재 발생이 가장 높은 1월에 다소 낮은 HCHO 값이 보이는 등 시공간적으로 생태계 화제 분포와 차이를 보인다. 이것의 원인으로 우리는 이 지역의 열대우림의 식물활동(biogenic activity)영향으로는 설명할 수 없고, biomass burning 에어로졸에 의한 잘못된 AMF 계산이 OMI HCHO 산출에 사용됨으로써 발생한 오차라는 것을 밝혔다. AMF와 관련된 오차가 적절하게 보정된다면, 아프리카 지역의 HCHO 시공간 변동성은 생태계 화제의 변동성을 따를 것이라 예상된다. 따라서 본 연구는 통계적 기법이 위성 자료를 평가하는데 매우 효율적인 방법임을 제안한다.

• 한국입자에어로졸학회지
• /
• 제10권1호
• /
• pp.9-17
• /
• 2014

Several studies have been carried out on the source contribution of the particulate Polycyclic Aromatic Hydrocarbons (PAHs) over Seoul by using the Chemical Mass Balance Model (CMB)(Lee and Kim, 2007; Kim et al., 2013). To confirm the validity of the modeling results, the modified model employing a photochemical loss rate along with varying residence times and the standard model that considers no loss were compared. It was found that by considering the photochemical loss rate, a better performance was obtained as compared to those obtained from the standard model in the CMB calculation. The modified model estimated higher contributions from coke oven, transportation, and biomass burning by 4 to 8%. However, the order of the relative importance of major sources was not changed, coke oven followed by transportation and biomass burning. Thus, it was concluded that the standard CMB model results are reliable for identifying the relative importance of major sources.