• The Journal of the Convergence on Culture Technology
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• v.8 no.2
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• pp.349-354
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• 2022

This research was conducted in order to improve the hydrolysis resistance and mechanical properties of a resin compound and biodegradable mulching film, produced through the use of PBAT(Poly Butylene Adipate-co-Terephthalate) and PLA(Poly Lactic Acid). Various ratios of chain extenders and mechanical properties according to the annealing temperature conditions were investigated. The annealing process showed that compound resin can improve the crystallization capacity. In addition, incorporation of the chain extender was shown to improve and increase the tensile strength and hydrolysis resistance of the film. In the case of 0.6phr chain extender, the tensile strength was 383.0Kgf/cm², which was improved by 155% compared to the control films. When the blow up ratio(BUR) was 2.5, the optimal tensile strength of the film increased greatly, expanding up to 379.0/195.2kgf/cm² in the both machine direction (MD) and transverse direction (TD).

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.27 no.3
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• pp.169-174
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• 2021

Today, plastic waste has become a critical social issue due to the increasing of plastic consumption. Korean annual per capita plastic consumption was 132 kg, the most plastic consuming country in the world. Internationally, Carbon Neutral Agreement is underway due to global warming, consumers' interest and needs for biomass-based plastics has also been increased. In this study, film was produced by adding composite use additives to the biomass-based plastics according to concentration, and the resulting changes in discharge volume, melt index, and tensile strength were investigated. Melt index (MI) was significantly higher in PLA and PBAT than in petroleum-based resin LLDPE and LDPE. Also, among the same resin or in the same treatment group, MI has been increased when the heating temperature is increased. The discharge volume and gravity of the BDP-2 to which 4% compatibilizer was added were found to be higher among all treatments, while the tensile strength of MD and TD was also higher. BDP-2 was suitable to the film producing methods for biodegradable film production.

• Clean Technology
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• v.8 no.4
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• pp.223-228
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• 2002

The biodegradable Properties of various polyester resins with different chemical structures have been studied by applying the controlled compost test and soil burial test. Celluose was taken as a fully biodegradable reference resin while PVC and PE were empolyed as non-biodegradable reference chains or ester group were rather easily degraded by hydrolase, meanwhile copolymer type polyesters which contain aromatic rings showed relatively low biodegradability. According to the results from controlled compost test, cellulose(the positive reference) showed 70.6% degradation after 45 days, whereas synthetic poly(butylene adipate-co-succinate), poly(butylene succinate), poly(butylene adipate-co-succinate-co-terephthalate) showed 44.0%, 32.0% and 23.4% degradation respectively. In this regard, it was concluded that biodegradable properties of polymers are largely dependant on the chemical structures constituting the polymers.

• Carbon letters
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• v.22
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• pp.36-41
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• 2017

Biodegradable epoxy (B-epoxy) was prepared from diglycidyl ether of bisphenol A and epoxidized linseed oil. The mechanical properties of B-epoxy composites reinforced with multi-walled carbon nanotubes (MWCNTs/B-epoxy) were examined by employing dynamic mechanical analysis, critical stress intensity factor ($K_{IC}$) tests, and impact strength tests. The electromagnetic interference shielding effectiveness (EMI-SE) of the composites was evaluated using reflection and absorption methods. Mechanical properties of MWCNTs/B-epoxy were enhanced with an increase in the MWCNT content, whereas they deteriorated when the MWCNT content was >5 parts per hundred resin (phr). This can likely be attributed to the entanglement of MWCNTs with each other in the B-epoxy due to the presence of an excess amount of MWCNTs. The highest EMI-SE obtained was ~16 dB for the MWCNTs/B-epoxy composites with a MWCNT content of 13 phr at 1.4 GHz. The composites (13 phr) exhibited the minimum EMI-SE (90%) when used as shielding materials at 1.4 GHz. The EMI-SE of the MWCNTs/B-epoxy also increased with an increase in the MWCNT content, which is a key factor affecting the EMI-SE.

• Polymer(Korea)
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• v.35 no.6
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• pp.580-585
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• 2011

This article aims to enhance the biodegradability and environment-friendliness of petroleum based biodegradable poly(butylene adipate-co-succinate-co-terephthalate)(PBAST) by blending chemically modified thermoplastic starch(CMPS). CMPS is a kind of bio-based biodegradable resin which is manufactured by reacting starch with maleic anhydride(MA) in the presence of a plasticizer and a free radical initiator. The characteristic properties of PBAST/CMPS blends were investigated by observing their morphology, thermal, mechanical properties, and biodegradability. The good interfacial adhesion between the phases examined by SEM revealed that PBAST/CMPS blends were compatible blends. The tensile strength and elongation decreased with increasing CMPS content, while modulus increased. The biodegradability of the blends was much higher than that of pristine PBAST and increased with increasing CMPS contents.

• Fibers and Polymers
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• v.6 no.4
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• pp.289-296
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• 2005

Biodegradable nanocomposites were prepared by mixing a polymer resin and layered silicates by the melt intercalation method. Internal structure of the nanocomposite was characterized by using the small angle X-ray scattering (SAXS) and transmission electron microscope (TEM). Nanocomposites having exfoliated and intercalated structures were obtained by employing two different organically modified nanoclays. Rheological properties in shear and extensional flows and biodegradability of nanocomposites were measured. In shear flow, shear thinning behavior and increased storage modulus were observed as the clay loading increased. In extensional flow, strain hardening behavior was observed in well dispersed system. Nanocomposites with the exfoliated structure had better biodegradability than nanocomposites with the intercalated structure or pure polymer.

• Journal of the Korean Applied Science and Technology
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• v.34 no.3
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• pp.643-649
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• 2017

Biodegradable enzymes such as lipase and proteinase can hydrolyze not only fatty acid esters and triglycerides, but also aliphatic polyesters. We measured the biodegradability that biodegradable enzymes have an important role in the degradation of natural aliphatic poly material such as PLA, corn starch, and polyethylene glycol in the natural environment. However, we investigated on the biodegradability of PLA, PLA and Polyethylene acrylate blended, and PLAcoPolyethylene polymerized with PLA graft copolymer Polyethylene glycol acrylate. When prepared biodegradable polymers. the Mechanical properties of them were measured on Biodegradability, thermal properties, real time in-situ electrical monitoring of polymers resin. Therefore BOD and biodegradation of PLAcoPolyethylene was graft copolymerized with PLA and polyethylene acrylate were measured at a lower rate than the other samples.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.27 no.3
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• pp.159-167
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• 2021

The need for biodegradable plastic continues to increase, improvement of physical properties is necessary for actual use in the market. In this study, composite film was produced by adding peroxide additives to bioplastic according to concentration to investigate changes in the melt index, elongation, morphology, and TGA of the composite film. The addition of peroxide compatibilizer showed superior elongation of film and TGA compared to those of control. The added amount of compatibilizer affected the extrusion process, and it was revealed that adding an appropriate amount of peroxidizer is important. Analysis of the composite film's morphology revealed a heterogeneous dispersion sequence due to different rates of crystallization depending on the resin, and surface physical properties were best in the group added with 4% peroxide. The results above showed that the test group added with 4% peroxide compatibilizer was superior in the production of composite biodegradable film.

• The Journal of the Convergence on Culture Technology
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• v.8 no.5
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• pp.553-559
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• 2022

The film mulching technology is useful for controlling soil temperature and moisture by covering the soil surface, and for suppressing weeds. In this study, in order to improve the hydrolysis resistance and mechanical properties of the biodegradable mulching film, PBAT(Poly butylene adipate-co-terephthalate) and PLA(Poly lactic acid) were modified using a twin-screw extruder and then the physical and biodegradable properties of the film were investigated. After landfill the mulching film in soil, the weight reduction of the film was confirmed by period, and plant growth was observed after mulching in the dry paddy field for rice farming. Mulching films with improved hydrolysis resistance showed excellent crop growth properties, and biodegradable mulching films can offer potential as a new alternative for environmentally friendly, efficient and sustainable agricultural practices.

• YAKHAK HOEJI
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• v.31 no.3
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• pp.182-188
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• 1987

Simple coacervation of bovine serum albumin was studied to prepare biodegradable microacapsule. Albumin microcapsules were prepared by using acrylonitrilestyrene polymer (M-80) resin beads and sulfamethoxydiazine as the core materials. The albumin to beads ratio was found to be 1:2.3 and the albumin to sulfamethoxydiazine ratio to be 1:2.9. The 50% release times (T$_{50%}$) of sulfamethoxydiazine and microencapsulated sulfamethoxydiazine were 6 min. and 73 min., respectively. The surface appearance of the microcapsule collected after release experiment was not different from those of the original microcapsule. In addition to slowing release of drug the microencapsulation process masked characteristic bitter taste of sulfamethoxydiazine.