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Organic Solvent Exposure of Thinner-Using Occupation and Its Treatment by Means of $TiO_2$ Photocatalyst (신너사용 작업장의 유기용제 노출 및 $TiO_2$ 광촉매를 이용한 BTX처리에 관한 연구)

  • 양원호;김현용;손부순;박종안
    • Journal of environmental and Sanitary engineering
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    • v.17 no.2
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    • pp.26-33
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    • 2002
  • Ultimate objective of industrial hygiene is the prevention of health impairment that may result from exposure to chemicals at workplace. Workers in solvent thinner-using occupation environment may be highly exposed to VOCs (volatile organic compounds) because solvent thinner has been used extensively such as painting, spraying, degreasing, coating and so on in Korea. The purpose of this study was to recognize, evaluate, and propose the control methods of VOCs from solvent thinner-using workplace. Five target volatile organic compounds (benzene, toluene, ethylbenzene, o-xylene, and m-xylene) were monitored in H company of Shiwa Industrial Complex and analyzed in perosnal, occupational indoor and outdoor during working hours simultaneously. Engineering control such as local ventilation should be made in considering the long-term exposure, though measured VOCs concentration did not exceed the workplace exposure standards. In addition, air cleaning device should be installed in local ventilation because Shiwa Industrial Complex has had the serious ambient air pollution. Currently, environmental purification using $TiO_2$ photocatalyst have attracted a great deal of attention with increasing number of recent environmental problems. In this study, $TiO_2$ sol coated on the ceramic bead was prepared by sol-gel method and the photodegradation of target compounds was investigated in gas phase by the exposure to UV-A lamp(365nm) in a batch system.

The Study of formation of LiCoO$_2$thin film electrode by RF-MSP (RF-MSP에 의한 LiCoO$_2$박막전극의 형성에 관한 연구)

  • 김상필;이우근;김익수;하홍주;박정후;조정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.167-170
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    • 1995
  • LiCoO$_2$is a electrode material of Li ion Cell which is expected as the cell with a very high electric charge density. The recent study is mainly to focused on a high power secondary cell. If very thin Li ion Cell can be made in the scale of IC substrate it can be a electric souse in IC chip , micro machine or very thin electrical display etc. LiCoO$_2$thin film can be made by CVD, Laser ablation, E-Beam, ton Beam process, sputtering etc. But to make the material with a high quality for a cell is difficult as the electrode in cell have the fitable ratio in components and a lattice structure of bulk etc. In this study, LiCoO$_2$is made by R.F magnetron sputtering with the variance of substrate temperature and oxygen partial pressure etc. In the substrate temperature of 600$^{\circ}C$ and the oxygen rate of 10%, we can acquire the good thin film LiCoO$_2$compared wish a bulk material.

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Defect Chemistry of the Mixed Conducting Cage Compound Ca12Al14O33

  • Janek, J.;Lee, D.K.
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.99-105
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    • 2010
  • The electrical transport properties of mayenite ($Ca_{12}Al_{14}O_{33}$ or $12CaO{\cdot}7Al_2O_3$; mostly abbreviated as $C_{12}A_7$) can be controlled in a wide range by varying the oxygen deficiency: At high temperatures mayenite becomes either an oxygen solid electrolyte, a mixed ionic/electronic conductor or an inorganic electride with metal-like properties upon chemical reduction (removing oxygen). The underlying defect chemistry can be understood on the basis of a relatively simple model-despite the complex cage structure: A point defect model based on the assumption that the framework $[Ca_{12}Al_{14}O_{32}]^{2+}$ acts as a pseudo-donor describes well the high temperature transport properties. It accounts for the observed conductivity plateau at higher oxygen activities and also describes the experimentally observed oxygen activity dependence of the electronic conductivity with -1/4 slope at temperatures between 800 and $1000^{\circ}C$. Doping effects in mayenite are still not well explored, and we review briefly the existing data on doping by different elements. Hydration of mayenite plays a crucial role, as Mayenite is hygroscopic, which may be a major obstacle for technical applications.

Implant supported over denture with O-ring abutment (O-ring abutment를 이용한 Implant over denture의 제작)

  • Lee, Sung-Uck;Lee, Jung-Hwan;Park, Hyo-Ryun
    • Journal of Technologic Dentistry
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    • v.26 no.1
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    • pp.209-216
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    • 2004
  • The purpose of this study is to introduce how to make implant supported over denture with Oring. Many kinds of attachments have used to dental restorations. The application of attachment has widely increased implant fixed prosthesis and implant supported over denture. In order that implant supported over denture have properly retention, generally used O-ring, magnetic, bar attachment. O-ring give us an advantage that is required more minimum vertical dimension than bar-type and easily replace with new part. When we make these prosthesis using O-ring, Bar, Ball attachment, we should following procedures. Strong occlusion force leads to fracture of over denture because part of functional mechanism as implant abutment or attachment is spaced. Clips are regularly activated. O-ring and springs are changed every year. The pattern of resorption should be carefully monitored and compensated for by relining procedures. If the over denture appears to rest on the bar or the ball attachments, relining should be performed and clips/caps should be changed.

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Charge-Directed Peptide Backbone Dissociations of o-TEMPO-Bz-C(O)-Peptides

  • Jeon, Aeran;Lee, Ji Hye;Kwon, Hyuk Su;Park, Hyung Soon;Moon, Bong Jin;Oh, Han Bin
    • Mass Spectrometry Letters
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    • v.4 no.4
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    • pp.71-74
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    • 2013
  • In the present study, we report that the charge-directed (assisted) peptide dissociation products, such as b- and y-type peptide backbone fragments, were the major products in MS/MS and $MS^3$ applications of some o-TEMPO-Bz-C(O)-peptide ions, while radical-driven dissociation products, such as a/x and c/z-type fragments, were previously shown to be the major products in the free radical initiated peptide sequencing mass spectrometry (FRIPS MS). Those o-TEMPO-Bz-C(O)-peptides share a common feature in their sequences, that is, the peptides do not include an arginine residue that has the highest proton affinity among free amino acids. The appearance of b- and y-type fragments as major products in FRIPS MS can be understood in terms of the so-called "mobile-proton model". When the proton is highly mobilized by the absence of arginine, the chare-directed peptide dissociation pathways appear to be more competitive than the radical-driven dissociation pathways, in our FRIPS experiments.

Numerical Analyses of O-Cell Load Test on Pile (양방향말뚝재하시험의 수치해석)

  • Joo, Yong-Sun;Kim, Nak-Kyoung;Kim, Woong-Jin;Park, Jong-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.748-753
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    • 2008
  • Bi-directional load test is one of O-cell tests. The O-cell test is a system which may be used for performing static load tests on cast in situ reinforced concrete bored piles. The technique was devised and developed by Osterberg of Northwestern University(USA) and has been in use around the world. The principle of the method is that an O-cell is installed in a cast in situ bored pile base. Once the pile concrete reaches its design strength the cell is connected to an hydraulic pump and pressured. Pressurisation causes the cell to expand, developing an upward force on the section of pile above the cell loads, pile movements and strains within the pile then enable the capacity of the pile and its load settlement curves to be ascertained. Bi-directional load tests using O-cell are now becoming common practice around the world, particularly where the loads to be applied are high or where it is not convenient to perform top-down loading tests. In the study, calculate ultimate capacity of bi-directional load test using FEM and beam on elasto-plastic foundation theory.

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Design Procedure for System in Package (SIP) Business

  • Kwon, Heung-Kyu
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.09a
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    • pp.109-119
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    • 2003
  • o In order to start SIP Project .Marketing (& ASIC team) should present biz planning, schedule, device/SIP specs., in SIP TFT prior to request SIP development for package development project. .In order to prevent (PCB) revision, test, burn-in, & quality strategy should be fixed by SIP TFT (PE/Test, QA) prior to request for PKG development. .Target product price/cost, package/ test cost should be delivered and reviewed. o Minimum Information for PCB Design, Package Size, and Cost .(Required) package form factor: size, height, type (BGA, QFP), Pin count/pitch .(Estimated) each die size including scribe lane .(Estimated) pad inform. : count, pitch, configuration(in-line/staggered), (open) size .(Estimated) each device (I/O & Core) power (especially for DRAM embedded SIP) .SIP Block diagram, and net-list using excel sheet format o Why is the initial evaluation important\ulcorner .The higher logic power resulted in spec. over of DRAM Tjmax. This caused business drop longrightarrow Thermal simulation of some SIP product is essential in the beginning stage of SIP business planning (or design) stage. (i.e., DRAM embedded SIP) .When SIP is developed using discrete packages, the I/O driver Capa. of each device may be so high for SIP. Since I/O driver capa. was optimized to discrete package and set board environment, this resulted in severe noise problem in SIP. longrightarrow In this case, the electrical performance of product (including PKG) should have been considered (simulated) in the beginning stage of business planning (or design).

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Annealing Effect on $SnO_2$ Thin Films Properties ($SnO_2$ 박막 특성에 미치는 annealing 효과)

  • Park, Kyung-Hee;Seo, Yong-Jin;Lee, Woo-Sun;Park, Jin-Seong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.99-102
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    • 2003
  • Tin dioxide thin films were deposited at $375^{\circ}C$ on alumina substrate by metal-organic chemical vapor deposition process to find the relationship between physicochemical properties and the annealing treatments. The small grains with heat treatments grew to the bunch of grains and then showed the hillocks on the film surface. The thickness decreased with annealing treatment. The measured binding energy (BE) and branching ratio of the Sn 3d spin-orbital doublet were typical of oxidized states of Sn and the BE of the O1s core level of about 530~530.65eV also confirmed the presence of O-Sn bonds. The BE of oxygen and tin with annealing treatment shifted to higher position. O/Sn atomic ratios of films deposited at $375^{\circ}C$ for 2min and 4min were 1.99 and 2.01, respectively. The value of the atomic ratio O/Sn of films deposited at $375^{\circ}C$ for 2min changed from 1.99 to 2.45 with annealing treatment. Gas sensitivity depended on annealing temperature, the sensitivity increased with increasing annealing temperature.

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A Study on the Mechanism of Solved Phosphate and $Ca^{2+}$ ion in Wastewater (廢水에서 용존隣(P)과 $Ca^{2+}$이온의 反應機構에 대한 점토)

  • 이순기;강현찬
    • Resources Recycling
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    • v.10 no.4
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    • pp.24-33
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    • 2001
  • For making a high degree of efficiency, this study attempts to gather each arisen-sludge from experiments and examine into its characteristics, in order to compare the biological reason of removing phosphorus with sintered body using calcite and the artificial reason of removing with a chemical reagent. First, it can be seen that sludge, which is identified CaCO$_3$, of 0.1∼0.2$\mu$m is regularly formed when using sintered body, calcite. And it is one of the results of the chemical methods in order to remove phosphorus that can be seen that sludges of 100∼50 $\mu$m are formed and that the forms of Ca$_2$P$_2$O$\_$7/, Ca$_3$(PO$_4$)$_2$$.$nH$_2$O, $\beta$-Ca$_2$P$_2$O$\_$7/ are shown when using a reagent, CaO dissolved water. The other of the results of the chemical methods can be seen that a lumpof sludge is formed when using wastewater and a reagent Ca$^2$$\^$+/ are used, and that the lump consists of Ca$_3$(PO$_4$)$_2$$.$nH$_2$O와 Ca$_2$H$_2$P$_4$O$\_$14/.

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Adsorption kinetics and isotherms of phosphate and its removal from wastewater using mesoporous titanium oxide

  • Lee, Kwanyong;Jutidamrongphan, Warangkana;Lee, Seokwon;Park, Ki Young
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.161-169
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    • 2017
  • The adsorption of phosphate onto mesoporous $TiO_2$ was investigated in order to reduce phosphorus concentrations in wastewater and provide a potential mode of phosphorus recovery. Three equilibrium isotherms were used to optimize and properly describe phosphate adsorption ($R^2$>0.95). The maximum capacity of phosphate on the adsorbent was found to be 50.4 mg/g, which indicated that mesoporous $TiO_2$ could be an alternative to mesoporous $ZrO_2$ as an adsorbent. A pseudo-second order model was appropriately fitted with experimental data ($R^2$>0.93). Furthermore, the suitable pH for phosphate removal by $TiO_2$ was observed to be in the range of pH 3-7 in accordance with ion dissociation. In contrast, increasing the pH to produce more basic conditions noticeably disturbed the adsorption process. Moreover, the kinetics of the conducted temperature study revealed that phosphate adsorption onto the $TiO_2$ adsorbent is an exothermic process that could have spontaneously occurred and resulted in a higher randomness of the system. In this study, the maximum adsorption using real wastewater was observed at $30^{\circ}C$.