• Title/Summary/Keyword: Barrier layer

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Sputtering법으로 제조한 OLED용 Barrier Layer의 특성평가

  • Jeong, Eun-Uk;Kim, Hoe-Bong;Lee, Jong-U;Jo, Yeong-Rae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.163-163
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    • 2012
  • 차세대 모바일용 전자디스플레이로 각광받고 있는 FOLED (flexible organic light emitting display)의 연구에서 display의 신뢰성과 수명은 매우 중요한 연구 테마이다. OLED의 수명단축에 영향을 미치는 요소는 수분에 의한 열화가 가장 치명적이다. Barrier layer를 통한 수분의 주요 침투경로는 pin-hole과 void 등과 같은 defect에 의한 것으로 보인다. 수분의 침투 경로를 제어하는 OLED용 barrier layer의 요구조건은 WVTR (water vapor transmission rate)이 $10^{-6}g/m^2{\cdot}day$ 이하로 낮아야 한다. Barrier layer가 가져야 할 핵심적인 조건은 유연성을 가지면서 동시에 WVTR 값이 매우 낮아야 하는데, 아직까지 이를 만족하는 barrier layer의 개발은 아직 덜된 실정이다. 본 연구에서는 PET (polyethylene terephthalate) 기판에 sputtering법으로 barrier layer를 제조하였다. 증착에 이용한 타겟은 두가지 종류인 Al과 $Al_2O_3$를 사용하였으며, 다층박막으로 제조하였다. 제조된 barrier layer의 수분침투 특성은 WVTR의 측정으로, 유연성의 평가는 in-situ fatigue test를 수행하여 측정하였다. 종합적인 특성 평가를 위하여 SEM과 AFM (atomic force microscope) 관찰도 하였다.

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A study on ZrN layer as a diffusion barrier between Cu and Si (Cu와 Si 사이에서 확산방지막으로 사용하기 위한 ZrN 층의 연구)

  • 김창조;김좌연;윤의중;이재갑
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.21-24
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    • 1998
  • The properties of ZrN layer deposited by Sputtering system have been investigated in the application of diffusion barrier layer to copper. ZrN layer exhibited a excellent barrier property up to $700^{\circ}$ and higher resistivity. If an excess $O_2$is protected during the process of ZrN deposition, ZrN layer will be possible to use a diffusion barrier layer to copper.

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Effect of Metal Barrier Layer for Flexible Solar Cell Devices on Tainless Steel Substrates

  • Kim, Kyoung-Bo
    • Applied Science and Convergence Technology
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    • v.26 no.1
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    • pp.16-19
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    • 2017
  • A thin metal layer of molybdenum is placed between the conventional barrier layer and the stainless steel substrate for investigating the diffusion property of iron (Fe) atoms. In this study, the protection probability was confirmed by measuring the concentration of out-diffused Fe using a SIMS depth profile. The Fe concentration of chromium (Cr) barrier layer with 10 nm molybdenum (Mo) layer is 5 times lower than that of Cr barrier without the thin Mo layer. The insertion of a thin Mo metal layer between the barrier layer and the stainless steel substrate effectively protects the out-diffusion of Fe atoms.

Seepage-Advection-Dispersion Numerical Analysis of Barrier System of Offshore Rubble Mound Revetment Landfill Under Steady Flow (정상류 조건에서 경사식호안 해상폐기물매립장의 차수에 대한 침투이류 분산해석)

  • Hwang, Woong-Ki;Kim, Hyang-Eun;Kim, Tae-Hyung
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.4
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    • pp.97-106
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    • 2019
  • This study was conducted to propose a reasonable requirement regulation of barrier system of rubble mound revetment offshore landfill for preventing contaminant leakage. The barrier is composed with bottom layer and side barrier. The bottom layer was assumed as impermeable clay layer and side barrier was composed with HDPE sheet (primary element) and mid-protection layer (supplementary element). Seepage-advection-dispersion numerical analysis has been conducted using SEEP/W and CTRAN/W programs under steady flow. As the results, the minimum required barrier regulations for hydraulic conductivity and thickness of the bottom layer were suggested. For side barrier, the extended length of HDPE sheet and the hydraulic conductivity of mid-protection layer were also suggested.

Improving Gas Barrier Property of Polymer Based Nanocomposites Using Layer by Layer Deposition Method for Hydrogen Tank Liner

  • Lee, Suyeon;Han, Hye Seong;Seong, Dong Gi
    • Composites Research
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    • v.35 no.3
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    • pp.121-126
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    • 2022
  • Owing to advantages of polymeric materials for hydrogen tank liner like light-weight property and high specific strength, polymer based composites have gained much attention. Despite of many benefits, polymeric materials for fuel cell tank cause problems which is critical to applications as low gas barrier property, and poor processability when adding fillers. For these reasons, improving gas barrier property of polymer composites is required to study for expanding application fields. This work presents impermeable polymer nanocomposites by introducing thin barrier coating using layer by layer (LBL) deposition method. Also, bi-layered and quad-layered nanocomposites were fabricated and compared for identifying relationship between deposition step and gas barrier property. Reduction in gas permeability was observed without interrupting mechanical property and processability. It is discussed that proper coating conditions were suggested when different coating materials and deposition steps were applied. We investigated morphology, gas barrier property and mechanical properties of fabricated nanocomposites by FE-SEM, Oxygen permeation analyzer, UTM, respectively. In addition, we revealed the mechanism of barrier performance of LBL coating using materials which have high aspect ratio.

The Effect of Barrier Layer on Thin-film Silicon Solar Cell Using Graphite Substrates (탄소 기판을 이용한 박막 실리콘 태양전지의 배리어 층 효과)

  • Cho, Young Joon;Lee, Dong Won;Cho, Jun Sik;Chang, Hyo Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.505-509
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    • 2016
  • We have investigated the characteristics of amorphous silicon (a-Si) thin-film solar cell by inserting barrier layer. The conversion efficiency of a-Si thin-film solar cells on graphite substrate shows nearly zero because of the surface roughness of the graphite substrate. To enhance the performance of solar cells, the surface morphology of the back side were modified by changing the barrier layer on graphite. The surface roughness of graphite substrate with the barrier layer grown by plasma enhanced chemical vapor deposition (PECVD) reduced from ~2 um to ~75 nm. In this study, the combination of the barrier layer on graphite substrate is important to increase solar cell efficiency. We achieved ~ 7.8% cell efficiency for an a-Si thin-film solar cell on graphite substrate with SiNx/SiOx stack barrier layer.

Analysis of IGBT with Hole barrier layer and Diverter (Hole barrier layer 와 Diverter 구조의 IGBT에 관한 특성 분석)

  • Yu, Seung-Woo;Shin, Ho-Hyun;Kim, Yo-Hann;Sung, Man-Young
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1315-1316
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    • 2007
  • This is paper, a new structure to effectively improve the Vce(sat) voltage and latch-up current in NPT type IGBTs with hole barrier layer and diverter. The hole barrier layer acts as a barrier to prevent the holes from flowing into the p-layer and stores them in the n-layer. And the diverter significantly reduce hole current from flowing into the p-layer and improve latch up current. Analysis on the Breakdown voltage shows identical values compared to existing Conventional IGBT structures. This shows an improvement on Vce(sat) and Latct-up current without lowering other characteristics of the device. The electrical characteristics were studied by MEDICI simulation results.

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Barrier Layers and Pulsed Laser Annealing Effects on TFEL Device with Cu and Ag co-doped SrS blue Phosphor Layer

  • Nam, Tae-Sung;Liew, Shan-Chun;Koutsogeorgis, Demosthenes C;Cranton, Wayne M
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.910-913
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    • 2003
  • In order to enhance performance, stability, and brightness of inorganic blue-light emitting EL device, barrier layer structure and pulsed laser annealing(PLA) treatment were introduced. The barrier layer structure was utilized for improving brightness of the device and instead of thermal annealing, pulsed laser annealing process was used. From this study, optimum barrier layer thickness and number of pulsed laser irradiation are established.

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The Effect of Diffusion Barrier and thin Film Deposition Temperature on Change of Carbon Nanotubes Length (탄소나노튜브 길이 변화에 대한 확산방지층과 박막 증착 온도의 영향)

  • Hong, Soon-kyu;Lee, Hyung Woo
    • Journal of Powder Materials
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    • v.24 no.3
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    • pp.248-253
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    • 2017
  • In this study, we investigate the effect of the diffusion barrier and substrate temperature on the length of carbon nanotubes. For synthesizing vertically aligned carbon nanotubes, thermal chemical vapor deposition is used and a substrate with a catalytic layer and a buffer layer is prepared using an e-beam evaporator. The length of the carbon nanotubes synthesized on the catalytic layer/diffusion barrier on the silicon substrate is longer than that without a diffusion barrier because the diffusion barrier prevents generation of silicon carbide from the diffusion of carbon atoms into the silicon substrate. The deposition temperature of the catalyst and alumina are varied from room temperature to $150^{\circ}C$, $200^{\circ}C$, and $250^{\circ}C$. On increasing the substrate temperature on depositing the buffer layer on the silicon substrate, shorter carbon nanotubes are obtained owing to the increased bonding force between the buffer layer and silicon substrate. The reason why different lengths of carbon nanotubes are obtained is that the higher bonding force between the buffer layer and the substrate layer prevents uniformity of catalytic islands for synthesizing carbon nanotubes.

Study on the Water-Vapor Permeation through the Al Layer on Polymer Substrate (폴리머 기판에 형성한 알루미늄 보호막의 수분침투 특성 연구)

  • Choi, Young-Jun;Ha, Sang-Hoon;Park, Ki-Jung;Choe, Youngsun;Cho, Young-Rae
    • Korean Journal of Metals and Materials
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    • v.47 no.12
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    • pp.873-880
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    • 2009
  • Water-vapor permeation through metallic barriers deposited on polymer substrates has been an important technological issue because the performance of the barrier is critical to the reliability of flexible organic devices. For the development of long-lifetime flexible organic devices, two different sets of samples were designed and demonstrated from the viewpoint of the water-vapor transmission rate (WVTR). Aluminum (Al) and polyethylene terephthalate (PET) were chosen for the barrier layer and the polymer substrate, respectively. Two stacking structures, a single-layer (Al/PET) structure and a double-layer (Al/PET/Al) structure, were used for the WVTR measurement. For the single-layer structure, the WVTR decreases as the thickness of the barrier layer increases. Compared to the single-layer sample, the double-layer sample showed superior WVTR performance (by nearly three times) when the total thickness of the Al barrier was greater than 100 nm.