• Title/Summary/Keyword: Atomic structure

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INVESTIGATION ON THE CORROSION BEHAVIOR OF HAHA-4 CLADDING BY OXIDE CHARACTERIZATION

  • Park, Jeong-Yong;Choi, Byung-Kwon;Jeong, Yong-Hwan
    • Nuclear Engineering and Technology
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    • v.41 no.2
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    • pp.149-154
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    • 2009
  • The microstructure, the corrosion behavior and the oxide properties were examined for Zr-1.5Nb-0.4Sn-0.2Fe-0.1Cr (HANA-4) alloys which were subjected to two different final annealing temperatures: $470^{\circ}C$ and $570^{\circ}C$. HANA-4 was shown to have $\ss$-enriched phase with a bcc crystal structure and Zr(Nb,Fe,Cr)$_2$ with a hcp crystal structure with $\ss$-enriched phase being more frequently observed compared with Zr(Nb,Fe,Cr)$_2$. The corrosion rate of HANA-4 was increased with an increase of the final annealing temperature in the PWR-simulating loop, $360^{\circ}C$ pure water and $400^{\circ}C$ steam conditions, which was correlated well with a reduction in the size of the columnar grains in the oxide/metal interface region. The oxide growth rate of HANA-4 was considerably affected by the alloy microstructure determined by the final annealing temperature.

Microstructure Evolution of 15Cr ODS Steel by a Simple Torsion Test (단순 전단변형에 의한 15Cr 산화물 분산강화 강의 미세조직 변화)

  • Jin, Hyun Ju;Kang, Suk Hoon;Kim, Tae Kyu
    • Journal of Powder Materials
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    • v.21 no.4
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    • pp.271-276
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    • 2014
  • 15Cr-1Mo base oxide dispersion strengthened (ODS) steel which is considered to be as a promising candidate for high- temperature components in nuclear fusion and fission systems because of its excellent high temperature strength, corrosion and radiation resistance was fabricated by using mechanical alloying, hot isostatic pressing and hot rolling. Torsion tests were performed at room temperature, leading to two different shear strain routes in the forward and reverse directions. In this study, microstructure evolution of the ODS steel during simple shearing was investigated. Fine grained microstructure and a cell structure of dislocation with low angle boundaries were characterized with shear strain in the shear deformed region by electron backscattered diffraction (EBSD). Grain refinement with shear strain resulted in an increase in hardness. After the forward-reverse torsion, the hardness value was measured to be higher than that of the forward torsion only with an identical shear strain amount, suggesting that new dislocation cell structures inside the grain were generated, thus resulting in a larger strengthening of the steel.

A Study on the Electrical Properties of $Ta_2O_{5}$ Thin Films by Atomic Layer Deposition Method in MOS Structure (MOS구조에서의 원자층 증착 방법에 의한 $Ta_2O_{5}$ 박막의 전기적 특성에 관한 연구)

  • 이형석;장진민;임장권;하만효;김양수;송정면;문병무
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.4
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    • pp.159-163
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    • 2003
  • ln this work, we studied electrical characteristics and leakage current mechanism of $Ta_2O_{5}$ MOS(Metal-Oxide-Semiconductor) devices. $Ta_2O_{5}$ thin film (63 nm) was deposited by ALD(Atomic Layer Deposition) method at temperature of 235 $^{\circ}C$. The structures of the $Ta_2O_{5}$ thin films were examined by XRD(X-Ray Diffraction). From XRD, it is found that the structure of $Ta_2O_{5}$ is single phase and orthorhombic. From capacitance-voltage (C-V) anaysis, the dielectric constant was 19.4. The temperature dependence of current density-electric field (J-E) characteristics of $Ta_2O_{5}$ thin film was studied at temperature range of 300 - 423 K. In ohmic region (<0.5 MV/cm), the resistivity was 2.456${\times}10^{14}$ ($\omega{\cdot}cm$ at 348 K. The Schottky emission is dominant at lower temperature range from 300 to 323 K and Poole-Frenkel emission is dominant at higher temperature range from 348 to 423 K.

International Comparison of Contents about Particle Concept in National Science Curricula (국가 수준 과학과 교육과정의 입자 관련 내용 국제 비교)

  • Kim, Dong-Hyun;Kim, Hyo-Nam
    • Journal of Korean Elementary Science Education
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    • v.31 no.2
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    • pp.164-176
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    • 2012
  • The purpose of this study was to find some suggestions for reorganization of contents about particle concept of matter in Korean science curriculum. For the purpose of this study, authors analyzed features of Korean science curriculum and compared science curricula of Korea, USA, UK, Japan and Finland. From the result of this study, authors find some features and important suggestions about reorganization of contents about particle in science curriculum. First, the sequence of contents about particle concepts in 2009 Revised National Curriculum was similar to that in the 6th National Science Curriculum. And the feature of 2009 Revised National Curriculum showed the articulation of contents about particle concept. If contents about particle concept is increased in elementary science curriculum, the total articulation would be increased. Second, the presenting sequence of atomic structure-first and laws about atom-later should be changed to laws about atomic-first and atomic structure-later. This presenting sequence is grounded by science curricula of other countries, history of science and developmental psychology. And science curriculum of Korea was required specific extended concept statement like science curricula of USA or UK. Also, Korean science curriculum could benchmark Finnish science curriculum if we want to develop some integrated learning activities such as those in STS or STEAM program.

Chemical Properties of Mineral Surfaces and Metal Ion Sorption: A Review (광물표면의 화학적 특성과 금속이온 수착의 고찰: A Review)

  • Yoon, Soh-Joung
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.205-215
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    • 2012
  • Metal ions, toxic or potentially toxic to biota and human beings, can be immobilized by sorption onto the mineral surfaces in soils and sediments. This article briefly explains theories regarding the chemical properties of mineral surfaces to sorb metal ions and processes of extended X-ray absorption fine structure (EXAFS) analysis for sorption study, and reviews atomic-scale findings on metal sorption on mineral surfaces. The theoretical understanding on the chemistry of mineral surfaces and metal sorption is fundamental to the proper analysis of the atomic-scale spectroscopy to determine the sorption phases. Atomic-scale findings on metal sorption phases discussed here include co-precipitation, ternary complexation, aging effects, and desorption possibilities, as well as outer-sphere complexation, inner-sphere complexation, and surface precipitation.

Seismic qualification using the updated finite element model of structures

  • Sinha, Jyoti K.;Rao, A. Rama;Sinha, R.K.
    • Structural Engineering and Mechanics
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    • v.19 no.1
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    • pp.97-106
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    • 2005
  • The standard practice is to seismically qualify the safety related equipment and structural components used in the nuclear power plants. Among several qualification approaches the qualification by the analysis using finite element (FE) method is the most common approach used in practice. However the predictions by the FE model for a structure is known to show significant deviations from the dynamic behaviour of 'as installed' structure in many cases. Considering such limitation, few researchers have advocated re-qualification of such structures after installation at site to enhance the confidence in qualification vis-$\grave{a}$-vis plant safety. For such an exercise the validation of FE model with experimental modal data is important. A validated FE model can be obtained by the Model Updating methods in conjugation with the in-situ experimental modal data. Such a model can then be used for qualification. Seismic analysis using the updated FE model and its advantage has been presented through an example of an in-core component - a perforated horizontal tube of a nuclear reactor.

Study of a Betavoltaic Battery Using Electroplated Nickel-63 on Nickel Foil as a Power Source

  • Uhm, Young Rang;Choi, Byoung Gun;Kim, Jong Bum;Jeong, Dong-Hyuk;Son, Kwang Jae
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.773-777
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    • 2016
  • A betavoltaic battery was prepared using radioactive $^{63}Ni$ attached to a three-dimensional single trenched P-N absorber. The optimum thickness of a $^{63}Ni$ layer was determined to be approximately $2{\mu}m$, considering the minimum self-shielding effect of beta particles. Electroplating of radioactive $^{63}Ni$ on a nickel (Ni) foil was carried out at a current density of $20mA/cm^2$. The difference of the short-circuit currents ($I_{sc}$) between the pre- and post-deposition of $^{63}Ni$ (16.65 MBq) on the P-N junction was 5.03 nA, as obtained from the I-V characteristics. An improved design with a sandwich structure was provided for enhancing performance.

Synthesis of Core/shell Structured Ag/C Nano Particles and Properties on Annealing Conditions (전기선폭발법을 이용한 core/shell 구조 Ag/C 나노 입자의 제조 및 열처리조건에 따른 특성)

  • Jun, S.H.;Uhm, Y.R.;Rhee, C.K.
    • Journal of Powder Materials
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    • v.17 no.4
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    • pp.295-301
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    • 2010
  • Multi shell graphite coated Ag nano particles with core/shell structure were successfully synthesized by pulsed wire evaporation (PWE) method. Ar and $CH_4$ (10 vol.%) gases were mixed in chamber, which played a role of carrier gas and reaction gas, respectively. Graphite layers on the surface of silver nano particles were coated indiscretely. However, the graphite layers are detached, when the particles are heated up to $250^{\circ}C$ in the air atmosphere. In contrast, the graphite coated layer was stable under Ar and $N_2$ atmosphere, though the core/shell structured particles were heated up to $800^{\circ}C$. The presence of graphite coated layer prevent agglomeration of nanoparticles during heat treatment. The dispersion stability of the carbon coated Ag nanoparticles was higher than those of pure Ag nanoparticles.

Study of Mechanically Alloyed Nano Cu-Fe Particles With a Hetero-Structure (헤테로 구조 Cu-Fe 나노분말의 제조 연구)

  • Uhm, Y.R.;Lee, H.M.;Rhee, C.K.
    • Journal of Powder Materials
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    • v.14 no.2 s.61
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    • pp.97-100
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    • 2007
  • The magnetic alloys of Cu-Fe ($Cu_{50}Fe_{50},\;Cu_{80}Fe_{20}\;and\;Cu_{90}Fe_{10}$) were prepared by a mechanical alloying method and their structural and magnetic behaviors were examined by X-ray diffraction and Mossbauer spectra. The magnetization curves did not distinctly show the saturation at 70 kOe for the concentrated alloys of $Cu_{80}Fe_{20}\;and\;Cu_{90}Fe_{10}$. The Mossbauer spectrum of $Cu_{80}Fe_{20}$ at room temperature shows one Lorentzian line of the paramagnetic phase, whereas the Mossbauer spectrum of $Cu_{90}Fe_{10}$ consists of sextet Lorentzian line at room temperature and a centered doublet line. The Mossbauer spectra of $Cu_{90}Fe_{10}$ measured in the temperature ranges from 13 to 295 K, implies that $Cu_{90}Fe_{10}$ to consists of two magnetic phases. One superimposed sextet corresponds to the ferromagnetic iron in Cu and the other one indicates the superparamagnetic iron rich phase.

3D Shape Descriptor with Interatomic Distance for Screening the Molecular Database (분자 데이터베이스 스크리닝을 위한 원자간 거리 기반의 3차원 형상 기술자)

  • Lee, Jae-Ho;Park, Joon-Young
    • Korean Journal of Computational Design and Engineering
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    • v.14 no.6
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    • pp.404-414
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    • 2009
  • In the computational molecular analysis, 3D structural comparison for protein searching plays a very important role. As protein databases have been grown rapidly in size, exhaustive search methods cannot provide satisfactory performance. Because exhaustive search methods try to handle the structure of protein by using sphere set which is converted from atoms set, the similarity calculation about two sphere sets is very expensive. Instead, the filter-and-refine paradigm offers an efficient alternative to database search without compromising the accuracy of the answers. In recent, a very fast algorithm based on the inter-atomic distance has been suggested by Ballester and Richard. Since they adopted the moments of distribution with inter-atomic distance between atoms which are rotational invariant, they can eliminate the structure alignment and orientation fix process and perform the searching faster than previous methods. In this paper, we propose a new 3D shape descriptor. It has properties of the general shape distribution and useful property in screening the molecular database. We show some experimental results for the validity of our method.