Browse > Article
http://dx.doi.org/10.9719/EEG.2012.45.2.205

Chemical Properties of Mineral Surfaces and Metal Ion Sorption: A Review  

Yoon, Soh-Joung (Mineral Resources Research Department, Korea Institute of Geoscience and Mineral Resources)
Publication Information
Economic and Environmental Geology / v.45, no.2, 2012 , pp. 205-215 More about this Journal
Abstract
Metal ions, toxic or potentially toxic to biota and human beings, can be immobilized by sorption onto the mineral surfaces in soils and sediments. This article briefly explains theories regarding the chemical properties of mineral surfaces to sorb metal ions and processes of extended X-ray absorption fine structure (EXAFS) analysis for sorption study, and reviews atomic-scale findings on metal sorption on mineral surfaces. The theoretical understanding on the chemistry of mineral surfaces and metal sorption is fundamental to the proper analysis of the atomic-scale spectroscopy to determine the sorption phases. Atomic-scale findings on metal sorption phases discussed here include co-precipitation, ternary complexation, aging effects, and desorption possibilities, as well as outer-sphere complexation, inner-sphere complexation, and surface precipitation.
Keywords
metal ions; sorption; mineral surface; EXAFS;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Sparks, D.L. (2000) New frontiers in elucidating the kinetics and mechanisms of metal and oxyanion sorption at the soil mineral/water interface. Journal of Plant Nurition and Soil Science, v.163, p.563-570.   DOI
2 Zhang, Y., Dou, X.-M., Yang, M., He, H., Jing, C.-Y. and Wu, Z.-Y. (2010) Removal of arsenate from water by uing an Fe-Ce oxide adsorbent: Effects of cooexistent fluoride and phosphate. Journal of Hazardous Materials, v.179, p.208-214.   DOI
3 Strawn, D.G., Scheideger, A.M. and Sparks, D.L. (1998) Kinetics and mechanisms of Pb(II) sorption and desorption at the aluminum oxide-water interface. Environmental Science and Technology, v.32, p.2596-2601.   DOI
4 Swedlund, P.J., Webster, J.G. and Miskelly, G.M. (2009) Goethite adsorption of Cu(II), Pb(II), Cd(II), and Zn(II) in the presence of sulfate: Properties of the ternary complex. Geochimica et Cosmochimica Acta, v.73, p.1548-1562.   DOI
5 Teo, B.K. (1986) EXAFS: Principles and data analysis. Springer-Verlag, Berline, p.30.
6 Thompson, H.A., Parks, G.A. and Brown, Jr., G.E. (1999) Dynamic interactions of dissolution, surface adsorption, and precipitation in an aging cobalt(II)-clay-water system. Geochimica et Cosmochimica Acta, v.63, p.1767-1779.   DOI
7 Thompson, H.A., Parks, G.A. and Brown, Jr., G.E. (2000) Formation and release of cobalt(II) sorption and precipitation products in aging kaolinte-water slurries. Journal of Colloid and Interface Science, v.222, p.241-253.   DOI   ScienceOn
8 Towle, S.N., Bargar, J.R., Brown, Jr., G.E. and Parks, G.A. (1997) Surface precipitation of Co(II) (aq) on $Al_2O_3$. Journal of Colloid and Interface Science, v.187, p.62-82.   DOI
9 Trainor, P.T., Fitts, J.P., Templeton, A.S., Grolimund, D. and Brown, Jr., G.E. (2001) Grazing-incidence XAFS study of aqueous Zn(II) sorption on ${\alpha}-Al_2O_3$ single crystals. Journal of Colloid and Interface Science, v. 244, p. 239-244.   DOI
10 Wang, Y., Morin, G., Ona-Nguema, G., Juillot, F., Calas, G. and Brown, Jr., G.E. (2011) Distinctive arsenic(V) trapping modes by magnetite nanoparticles induced by different sorption processes. Environmental Science and Technology, v.45, p.7258-7266.   DOI   ScienceOn
11 Weesner, F.J. and Bleam, W.F. (1998) Binding characteristics of $Pb^{2+}$ on anion-modified and pristine hydrous oxide surfaces studied by electrophoretic mobility and X-ray absorption spectroscopy. Journal of Colloid and Interface Science, v.205, p.380-389.   DOI
12 Xu, Y., Boonfueng, T., Axe, L., Maeng, S. and Tyson, T. (2006) Surface complexation of Pb(II) on amorphous iron oxide and manganese oxide: Spectroscopic and time studies. Journal of Colloid and Interface Science, v.299, p.28-40.   DOI
13 Xu, Y. and Schwartz, F.W. (1994) Lead immobilization by hydroxyapatite in aqueous solutions. Journal of Contaminant Hydrology, v.15, p.187-206.   DOI   ScienceOn
14 Xu, Y., Schwartz, F.W. and Traina, S.J. (1994) Sorption of $Zn^{2+}$ and $Cd^{2+}$ on hydroxyapatite surfaces. Environmental Science and Technology, v.28, p.1472-1480.   DOI   ScienceOn
15 Yin, S. and Ellis, D.E. (2009) DFT studies of Cr(VI) complex adsorption on hydroxylated hematite (1102) surfaces. Surface Science, v.603, p.736-746.   DOI
16 Yoon, S., Helmke, P.A., Amonett, J.E. and Bleam, W.F. (2002) X-ray absorption and magnetic studies of trivalent lanthanide ions sorbed on pristine and phosphatemodified boehmite surfaces. Langmuir, v.18, p.10128-10136.   DOI   ScienceOn
17 Bardelli, F., Benvenuti, M., Costagliola, P., Benedetto, F.D., Lattanzi, P., Meneghini, C., Romanelli, M. and Valenzano, L. (2011) Arsenic uptake by natural calcite: An XAS study. Geochimica et Cosmochimica Acta, v.75, p.3011-3023.   DOI
18 Alexandros, V.G., Elzinga, E.J. and Reeder, R.J. (2007) Arsenate uptake by calcite: Macroscopic and spectroscopic characterization of adsorption and incorporation mechanisms. Geochimica et Cosmochimica Acta, v.71, p.4172-4187.   DOI   ScienceOn
19 Arai, Y., Elzinga, E.J. and Sparks, D.L. (2001) X-ray absorption spectroscopic investigation of arsenite and arsenate adsorption at the aluminum oxide-water interface. Journal of Colloid and Inerface Science, v.235, p.80-88.   DOI   ScienceOn
20 Bailey, E.H., Mosselmans, J.F.W. and Young, S.D. (2005) Time-dependent surface reactivity of Cd sorbed on calcite, hydroxylapatite and humic acid. Mineralogical Magazine, v.695, p.563-575.
21 Bargar, J.R., Brown, Jr., G.E. and Parks, G.A. (1998) Surface complexation of Pb(II) at oxide-water interfaces: III. XAFS determination fo Pb(II) and Pb(II)-chloro adsorption complexes on goethite and alumina. Geochimica et Cosmochimica Acta, v.62, p.193-207.   DOI
22 Bargar, J.R., Towle, S.N., Brown, Jr., G.E. and Parks, G.A. (1997a) Surface complexation of Pb(II) at oxide-water interfaces: I. XAFS and bond-valence determination of mononuclear and polynuclear Pb(II) sorption products on aluminum oxides. Geochimica et Cosmochimica Acta, v.61, p.2617-2637.   DOI
23 Chakraborty, S., Bardelli, F., Mullet, M., Greneche, J.-M., Varma, S., Ehrhardt, J.-J., Banerjee, D. and Charlet, L. (2011) Spectroscopic studies of arsenic retention onto biotite. Chemical Geology, v.281, p.83-92.   DOI
24 Zhang, Z. Fenter, P., Kelly, S.D., Catalano, J.G., Bandura, A.V., Kubicki, J.D., Sofo, J.O., Wesolowski, D.J., Machesky, M.L., Sturchio, N.C. and Bedzyk, M.J. (2006) Structure of hydrated $Zn^{2+}$ at the rutile TiO2 (110)-aqueous solution interface: Comparison of Xray standing wave, X-ray absorption spectroscopy, and density functional theory results. Geochimica et Cosmochimica Acta, v.70, p.4039-4056.   DOI
25 Zhang, G.Y. and Peak, D. (2007) Studies of Cd(II)-sulfate interactions at the goethite-water interface by ATRFTIR spectroscopy. Geochimica et Cosmochimica Acta, v.71, p.2158-2169.   DOI
26 Zhang, P. and Ryan, J.A. (1998) Formation of pyromorphite in anglesite-hydroxyapatite suspensions under varying pH conditions. Environmental Science and Technology, v.32, p.3318-3324.   DOI
27 Bargar, J.R., Towle, S.N., Brown, Jr., G.E. and Parks, G.A. (1997b) XAFS and bond-valence determination of the structures and compositions of surface functional groups and Pb(II) and Co(II) sorption products on single- crystal ${\alpha}-Al_2O_3$. Journal of Colloid and Interface Science, v.185, p.473-492.   DOI
28 Brown, Jr., G.E. and Parks, G.A. (2001) Sorption of trace elements on mineral surfaces: Modern perspectives from spectroscopic studies, and comments on sorption in the marine environment. International Geology Review, v.43, p.963-1073.   DOI
29 Charlet, L. and Manceau, A. (1992) X-ray absorption spectroscopic study of the sorption of Cr(III) at the oxide-water interface. II. Adsorption, coprecipitation, and surface precipitation on hydrous ferric oxide. Journal of Colloid and Interface Science, v.148, p.443-458.   DOI   ScienceOn
30 Chen, X., Wright, J.V., Conca, J.L. and Peurrung, L.M. (1997) Evaluation of heavy metal remediation using mineral apatite. Water, Air, and Soil Pollution, v.98, p.57-78.
31 Dahn, R., Scheidegger, A.M., Manceau, A., Schlegel, M.L., Baeyens, B., Bradbury, M.H. and Morales, M. (2002) Neoformation of Ni phyllosilicate upon Ni uptake on montmorillonite: A kinetics study by powder and polarized extended X-ray abrosption fine structure spectroscopy. Geochimica et Cosmochimica Acta, v.66, p.2335-2347.   DOI
32 Dou, X., Zhang, Y., Zhao, B., Wu, X., Wu, Z. and Yang, M. (2011) Arsenate adsorption on an Fe-Ce binetal oxide adsorbent: EXAFS study and surface complexation modeling. Colloids and Surfaces A: Physicochemical and Engineering Aspects, v. 379, p. 109-115.   DOI
33 Elzinga, E.J., Tand, Y., McDonald, J., DeSisto, S. and Reeder, R.J. (2009) Macroscopic and spectroscopic characterization of selenate, selenite, and chromate adsorption at the solid-water interface of ${\gamma}-Al_2O_3$. Journal of Colloid and Interface Science, v.340, p.153-159.   DOI
34 Elzinga, E.J., Peak, D. and Sparks, D.L. (2001) Spectroscopic studies of Pb(II)-sulfate interactions at the goethite-water interface. Geochimica et Cosmochimica Acta, v.65, p.2219-2230.   DOI
35 Elzinga, E.J., Rouff, A.A. and Reeder, R.J. (2006) The long-term fate of $Cu^{2+}Zn^{2+}$, and $Pb^{2+}$ adsorption complexes at the calcite surface: An X-ray absorption spectroscopy study. Geochimica et Cosmochimica Acta, v.70, p.2715-2725.   DOI
36 Elzinga, E.J. and Sparks, D.L. (2002) X-ray absorpion spectroscopy study of the effects of pH and ionic strength on Pb(II) sorption to amorphous silica. Environmental Science and Technology, v.36, p.4352-4357.   DOI
37 Farquhar, M.L., Vaughan, D.J., Hughes, C.R., Charnock, J.M. and England, K.E.R. (1997) Experimental studies of the interacion of aqueous metal cations with mineral substrates: Lead, cadmium, and copper with perthitic feldspar, muscovite, and biotite. Geochimica et Cosmochimica Acta, v.61, p.3051-3064.   DOI
38 Fendorf, S.E., Eick, M.J., Grossl, P. and Sparks, D.L. (1997) Arsenate and chromate retention mechanism on goethite. I. Surface structure. Environmental Science and Technology, v.31, p.315-320.   DOI   ScienceOn
39 Fendorf, S.E., Lamble, G.M., Stapleton, M.G., Kelley, M.J. and Sparks, D.L. (1994) Mechanisms of chromium( III) sorption on silica. 1. Cr(III) surface structure derived by extended x-ray absorption fine structure spectroscopy. Environmental Science and Technology, v.28, p.284-289.   DOI
40 Foster, A.L., Brown, Jr., G.E. and Parks, G.A. (2003) Xray absorption fine structure study of As(V) and Se(IV) sorption complexes on hydrous Mn oxide. Geochimica et Cosmochimica Acta, v.67, p.1937-1953.   DOI   ScienceOn
41 Goh, K.-H., Lim, T.-T., Banas, A. and Dong, Z. (2010) Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles. Jounal of Hazardous Materials, v.179, p.818-827.   DOI
42 Grafe, M., Nachtegaal, M. and sparks, D.L. (2004) Formation of metal-arsenate precipitates at the goethite-water interface. Environmental Science and Technology, v.38, p.6561-6570.   DOI
43 Grafe, M., Mustafa, G., Singh, B. and Kookana, R.S. (2008) Temperature and aging effects on the surface speciation of Cd(II) at the goethite-water interface. In Barnett, M.O. and Kent, D.B.(ed.) Developments in Earth and Environmental Sciences, v.7, Elsevier, p.187-204.
44 Grafe, M., Singh, B. and Balasubramanian, M. (2007) Surface speciation of Cd(II) and Pb(II) on kaolinite by XAFS spectroscopy. Journal of Colloid and Interface Science, v.315, p.21-32.   DOI
45 Guan, X.-H., Wnag, J. and Chusuei, C.C. (2008) Removal of arsenic from water using granular ferric hydroxide: Macroscopic and microscopic studies. Journal of Hazardous Materials, v.156, p.178-185.   DOI
46 Harrington, R., Hausner, D.B., Bhandari, N., Strongin, D.R., Chapman, K.W., Chupas, P.J. Middlemiss, D.S., Grey, C.P. and Parise, J.B. (2010) Investigation of surface structures by powder diffraction: A differential pair distribution function study on arsenate sorption of ferrihydrite. Inorganic Chemistry, v.49, p.325-330.   DOI
47 He, G., Pan, G. and Zhang, M. (2011) Studies on the reaction pathway of arsenate adsorption at water-$TiO_2$ interfaces using density functional theory. Journal Colloid and Interface Science, v.364, p.476-481.   DOI
48 Jia, Y., Xu, L., Wang, X. and Demopoulos, G.P. (2007) Infrared spectroscopic and X-ray diffraction characterization of the nature of adsorbed arsenate on ferrihydrite. Geochimica et Cosmochimica Acta, v.71, p.1643-1654.   DOI
49 He, G., Zhang, M. and Pan, G. (2009) Influence of pH on initial concentration effect of arsenate adsorption on $TiO_2$ surfaces: Thermodynamic, DFT, and EXAFS interpretations. Journal of Physical Chemistry, C, v.113, p.21679-21686.   DOI
50 Hingston, F.J., Posner, A.M. and Quirk, J.P. (1972) Anion adsorption by goethite and gibbsite. I. The role of the proton in determining adsorption envelopes. Journal of Soil Science, v.23, p.177-192.   DOI
51 Kim, C.S., Rytuba, J.J. and Brown, Jr., G.E. (2004) EXAFS study of mercury(II) sorption to Fe- and Al- (hydr)oxides. II. Effects of chloride and sulfate. Journal of Colloid and Interface Science, v.270, p.9-20.   DOI
52 Laperche, V., Traina, S.J., Gaddam, P. and Logan, T.J. (1996) Chemical and mineralogical characterizations of Pb in a contaminated soil: Reactions with synthetic apatite. Environmental Science and Technology, v.30, p.3321-3326.   DOI
53 Lee , S., Anderson, P.R., Bunker, G.B. and Karanfil, C. (2004) EXAFS study of Zn sorption mechanisms on montmorillonite. Environmental Science and Technology, v.38, p.5426-5432.   DOI
54 Lee, S., dyer, J.A., Sparks, D.L., Scrivner, N.C. and Ezinga, E.J. (2006) A multi-scale assessment of Pb(II) sorption on dolomite. Journal of Colloid and Interface Science, v.298, p.20-30.   DOI
55 Lee, Y.J., Elznga, E.J. and Reeder, R.J. (2005) Sorption mechanisms of zinc on hydroxyapatite: Systematic uptake studies and EXAFS spectroscopy analysis. Environmental Science and Technology, v.39, p.4042-4048.   DOI
56 Ma, Q.Y., Traina, S.J. and Logan, T.J. (1993) In situ lead immobilization by apatite. Environmental Science and Technology, v.27, p.1803-1810.   DOI   ScienceOn
57 Li, W. Harrington R., Tang, Y., Kubicki, J.D., Aryanpour, M., Reeder, R.J., Parise, J.B. and Phillips, B.L. (2011) Differential pair distribution function study of the structure of arsenate adsorbed on nanocrystalline ${\gamma}-Al_2O_3$. Environmental Science and Technology, v.45, p. 9687-9692.   DOI
58 Liu, Y.T., Chen, T.Y., Wang, M.K., Huang, PM., Chiang, P.N. and Lee, J.F. (2010) Mechanistic study of arsenate adsorption on lithium/aluminum layered double hydroxide. Applied Clay Science, v.48, p.485-491.   DOI
59 Lower, S.K., Maurice, P.A., Traina, S.J. and Carlson, E.H. (1998) Aqueous Pb sorption by hydroxylapatite: Application of atomic force microscopy to dissolution, nucleation, and growth studies. American Mineralogist, v.83, p.147-158.   DOI
60 Ma, Q.Y., Traina, S.J., Logan, T.J. and Ryan, J.A. (1994) Effects of aqueous Al, Cd, Cu, Fe(II), Ni, and Zn on Pb immobilization by hydroxyapatite. Environmental Science and Technology, v.28, p.1219-1228.   DOI
61 Ma, L.Q. and Rao, G.N. (1997) Effects of phosphate rock on sequential chemical extraction of lead in contaminated soils. Journal of Environal Quality, v.26, p.788-794.
62 Manning, B., Hunt, M.L., Amrhein, C. and Yarmoff, J.A. (2002) Arsenic(III) and arsenic(V) reactions with zerovalent iron corrosion products. Environmental Science and Technology, v.36, p.5455-5461.   DOI   ScienceOn
63 McKenzie, R.M. (1980) The adsorption of lead and other heavy metals on oxides of manganese and iron. Australian Journal of Soil Research, v.18, p.61-73.   DOI
64 O'Day, P.A., Brown, Jr., G.E. and Parks, G.A. (1994b) Xray absorpion spectroscopy of cobalt(II) multinuclear surface complexes and surface precipitates on kaolinite. Journal of Colloid and Interface Science, v.165, p.269-289.   DOI
65 Nguyen, Q.T. and Manning, B.A. (2003) Spectroscopic and modeling study of lead adsorption and precipitation reactions on a mineral soil. In Cai, Y. and Braids, O.C.(eds.) Biogeochemistry of Environmentally Important Trace Elements. ACS Symposium Series, v.835, ACS, p.388-403.
66 O'Day, P.A., Chisholm-Brause, C.J., Towle, S.N., Parks, G.A. and Brown, Jr., G.E. (1996) X-ray absorption spectroscopy of Co(II) sorption complexes on quartz ($a-SiO_2$) and rutile ($TiO_2$). Geochimica et Cosmochimica Acta, v.60, p.2515-2532.   DOI
67 O'Day, P.A., Parks, G.A. and Brown, Jr., G.E. (1994a) Molecular structure and binding sites of cobalt(II) surface complexes on kaolinite from x-ray absorption spectroscopy. Clays and Clay Minerals, v.42, p.337-355.   DOI
68 Ostergren, JD., Brown, Jr., G.E., Parks, G.A. and Persson, P. (2000a) Inorganic ligand effects on Pb(II) sorption to goethite(${\alpha}$-FeOOH). II. Sulfate. Journal of Colloid and Interface Science, v.225, p.483-493.   DOI
69 Ostergren, J.D., Trainor, T. P., Bargar, J.R., Brown, Jr., G.E. and Parks, G.A. (2000b) Inorganic ligand effects on Pb(II) sorption to goethite(${\alpha}$-FeOOH). I. Carbonate. Journal of Colloid and Interface Science, v.225, p.466-482.   DOI
70 Papelis, C. and Hayes, K.F. (1996) Distinguishing between interlayer and external sorption sites of clay minerals using x-ray absorption spectroscopy. Colloids and Surface. A., v.107, p.89-96.   DOI
71 Roe, A.L., Hayes, K.F., Chishom-Brause, C., Brown, Jr., G.E., Parks, G.A., Hodgson, K.O. and Leckie, J.O. (1991) In situ X-ray absorption study of lead ion surface complexes at the goethite-water interface. Langmuir, v.7, p.367-373.   DOI
72 Parks, G.A. (1967) Aqueous surface chemistry of oxides and complex oxide minerals - Isoelectric point and zero point of charge. In Stumm, W.(ed.) Equilibrium Concepts in Natural Water Systems, Adv. Chem. Ser. No. 67. Am.Chem. Soc., Washington, DC, p.121-160.
73 Pathak, P.N. and Coppin, G.R. (2007) Effect of complexing anions on europium sorption on suspended silica: A TRLFS study for ternary complex formation. Radiochimica Acta, v.95, p.267-273.   DOI
74 Roberts, D.R., Ford, R.B. and Sparks, D.L. (2003) Kinetics and mechanisms of Zn complexation on metal oxides using EXAFS spectroscopy. Journal of Colloid and Interface Science, v.263, p.364-376.   DOI
75 Rouff, A.A., Elzinga, E.J., Reeder, R.J. and Fisher, N.S. (2004) X-ray absorption spectroscopic evidence for the formation of Pb(II) inner-sphere adsorption complexes and precipitates at the calcite-water interface. Environmental Science and Technology, v.38, p.1700-1707.   DOI
76 Rouff, A.A., Elzinga, E.J., Reeder, R.J. and Fisher, N.S. (2006) The effect of aging and pH on Pb(II) sorption processes at the calcite-water interface. Environmental Science and Technology, v.40, p.1792-1798.   DOI
77 Sahai, N., Carroll, S.A., Roberts, S. and O'Day, P.A. (2000) X-ray absorption spectroscopy of strontium(II) coordination. Journal of Colloid and Interface Science, v.222, p.198-212.   DOI
78 Scheckel, K.G., Impellitteri, C.A. and Ryan, J.A. (2004) Lead sorption on ruthenium oxide: A macroscopic and spectroscopic study. Environmental Science and Technology, v.38, p.2836-2842.   DOI
79 Scheidegger, A.M., Lamble, G.M. and Sparks, D.L. (1996b) Investigation of Ni sorption on pyrophyllite: An XAFS study. Environmental Science and Technology, v.30, p.548-554.   DOI
80 Scheidegger, A.M., Fendorf, M. and Sparks, D.L. (1996a). Mechanisms of nickel sorption on pyrophyllite: Macroscopic and microscopic approaches. Soil Science Society of America Journal, v.60, p.1763-1772.   DOI
81 Scheidegger, A.M., Lamble, G.M. and Sparks, D.L. (1997) Spectroscopic evidence for the formation of mixed-cation hydroxide phases upon metal sorption on clays and aluminum oxides. Jounral of Colloid and Interface Science, v.186, p.118-128.   DOI
82 Scheidegger, A.M. and Sparks, D.L. (1996a) A critical assessment of sorption-desorption mechanisms at the soil mineral/water interface. Soil Science, v.161, p.813-831.   DOI
83 Scheidegger, A.M. and Sparks, D.L. (1996b) Kinetics of the formation and the dissolution of nickel surface precipitates on pyrophyllite. Chemical Geology, v.132, p.157-164.   DOI
84 Scheidegger, A.M., Strawn, D.G., Lamble, G.M. and Sparks, D.L. (1998) The kinetics of mixed Ni-Al hydroxide formation on clay and aluminum oxide minerals: A time-resolved XAFS study. Geochimica et Cosmochimica Acta, v.62., p.2233-2245.   DOI
85 Scheinost, A.C., Abend, S., Panday, K.I. and Sparks, D.L. (2001) Kinetic controls on Cu and Pb sorption by ferrihydrite. Environmental Science and Technology, v.35, p.1090-1096.   DOI
86 Schindler, P.W. (1991) A solution chemists view of surface chemistry. Pure and Applied Chemistry, v.63, p.1697-1704.   DOI