• Title/Summary/Keyword: Atomic Absorption Spectroscopy

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Analysis of Acetone Absorption Spectra Using Off-axis Integrated Cavity Output Spectroscopy for a Real-time Breath Test

  • Lim Lee;Yonghee Kim;Byung Jae Chun;Taek-Soo Kim;Seung-Kyu Park;Kwang-Hoon Ko;Ki-Hee Song;Hyunmin Park
    • Current Optics and Photonics
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    • v.7 no.6
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    • pp.761-765
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    • 2023
  • We analyzed the absorption spectra of acetone in the 3.37 ㎛ mid-infrared range using the off-axis integrated cavity output spectroscopy technique to develop a real-time, in-line breath analysis device. The linear relationship between acetone concentration and absorption increase was confirmed as 0.32%/ppm, indicating that the developed device allows for a quantitative analysis of acetone concentration in exhaled breath. To further confirm the feasibility of using our device for breath analysis, we measured the acetone concentration of human breath samples at the sub-ppm level.

Semiconductor laser-based absorption spectroscopy for monitoring physical vapor deposition process (증기증착 공정 감시를 위한 반도체 레이저 흡수 분광학)

  • 정의창;송규석;차형기
    • Journal of the Korean Vacuum Society
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    • v.13 no.2
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    • pp.59-64
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    • 2004
  • A study on the semiconductor laser-based atomic absorption spectroscopy was performed for monitoring physical vapor deposition process. Gadolinium metal was vaporized with a high evaporation rate by electron beam heating. Real-time atomic absorption spectra were measured by using tunable semiconductor laser beam at 770-794 nm (center wavelength of 780 nm) and its second harmonic at 388-396 nm. Atomic densities of metal vapor can be calculated from the absorption spectra measured. We plot the atomic densities as a function of the electron beam power and compare with the evaporation rates measured by quartz crystal monitor. We demonstrate that the semiconductor laser-based spectroscopic system developed in this study can be applied to monitor the physical vapor deposition process for other metals such as titanium.

Quantum Interference Effects on Optical Amplification and the Index of Refraction in a Four-Level System

  • Zhang, Hui-Fang;Wu, Jin-Hui;Gao, Jin--Yue
    • Journal of the Optical Society of Korea
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    • v.7 no.3
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    • pp.174-179
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    • 2003
  • We construct a four-level system where a metastable state is included in an $Er^{3+}$ Doped Yttrium aluminum garnet (YAG) crystal. Because of the action of the coherent field, the traditional light amplification with inversion can be exhibited with remarkable variation. As a result, we propose a method to achieve the gain equalization by atomic coherence. At the same time, we find that the high index of refraction accompanied by vanishing absorption can also be reached in this model. We also find that a higher index of refraction with zero absorption can be easily obtained when the coherent field is off resonance.

Direct Determination of Serum Zinc by Atomic Absorption Spectroscopy (원자흡광분광분석법에 의한 혈청 Zn의 측정)

  • Tchai, Bum-Suk;Suk, Young-Gunn;Park, Tong-Soo
    • Journal of Nutrition and Health
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    • v.4 no.3
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    • pp.1-4
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    • 1971
  • Zinc is an essential trace element. Previos methods for the determination of zinc in serum have been difficult and reported findings must be treated with caution. The normal range of zinc in serum varies significantly according to different methods and author. The scope of this work was to establish the normal range of zinc in serum values in healthy Korean persons. Methods are described for the determination of zinc in serum diluted ten-fold with deionised water using Hitachi Model 207, atomic absorption spectrophotometer. The values of zinc in serum of 23 healthy Korean persons by atomic absorption spectroscopy ranged from 87.6 to $131.2\;{\mu}g/100\;ml$ with the mean value $109.1\;{\mu}g/100\;ml$ and standard deviation 10.86. In this method, satifactory result was obtained with regard to the coefficient variation and recoveries of added zinc in the measurenents.

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Measurement of excited species in discharges using Laser Absorption spectroscopy

  • Sakai, Yosuke
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.5-8
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    • 2000
  • The population density of excited species in dc, rf and laser ablation plume plasmas has been measured using laser absorption spectroscopy. It was shown that, when the plasma was modulated by on and off with, the sensitivity and signal to noise (S/N) ratio became high. For example, the atomic O(3$^{5}$ S$^{o}$ $_2$) Population density, No* in $O_2$/He mixtures was obtained by the highest S/N ratio at a frequency of 2.7kHz. In a 20Torr room air, the lowest No* level to be detectable was shown to be an order of 10$^{7}$ cm$^{-3}$ . The population densities of resonance Ar(1S$_2$) and Xe(1S$_4$) levels were also measured in barrier discharges and laser ablation plasmas.

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Characterization of uranium species in molten salt : An application of synchrotron-based XAFS spectroscopy

  • Cho, Young-Hwan;Choi, In-Kyu;Kim, Won-Ho
    • Proceedings of the Korean Nuclear Society Conference
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    • 2002.10a
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    • pp.319.2-319
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    • 2002
  • Synchrotron-based X-ray absorption spectroscopy has been applied to determine the changes in bulk oxidation state of uranium oxides in molten salt. From an analysis of XANES data, one can determine the cahnges in bulk oxidation-state of U compounds in salts(LiCl/KCl). XAFS spectroscpy is a powerful tool for probing the changes in valence state and structure of uranium compounds in colten salt as well as in noncrystalline form and doped in other matrices.

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Measurement of oxygen isotope ratio using tunable diode laser absorption spectroscopy (다이오드 레이저 흡수분광법을 이용한 산소 동위원소의 성분비 측정)

  • Park, Sang-Eon;Jung, Do-Young;Kim, Jae-Woo;Ko, Kwang-Hoon;Im, Kwon;Jung, Eui-Chang;Kim, Chul-Joong
    • Korean Journal of Optics and Photonics
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    • v.15 no.1
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    • pp.1-5
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    • 2004
  • Tunable diode laser absorption spectroscopy was performed for analysis of the H$_2$$^{18}$ O/H$_2$$^{16}$ O isotope ratio of a water sample which was enriched by the membrane distillation method. In order to improve the signal-to-noise ratio, the wavelength modulation spectroscopic method was used with a lock-in amplifier. The fringe noise could be suppressed by using the FFT (Fast Fourier Transform) lowpass filter and the optimization of the modulation depth of the laser frequency. The maximum deviation of $\delta$-value was measured to be$\pm$4$\textperthousand$.

Trace elements analysis in some medicinal plants using graphite furnace-atomic absorption spectroscopy

  • Anal, Jasha Momo H.;Chase, Petevino
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.247-255
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    • 2016
  • Ten trace elements (Mg, Ca, V, Cr, Mn, Fe, Cu, Zn, Mo, and Cd) were determined in seven traditionally used wild medicinal plants of the Nagas in the North-East India viz Cynoglossum furcatum Wallich, Elsholtzia blanda Bentham, Lycopodium cernuum Linnaeus, Potentilla fulgens Wallich ex Hooker, Swertia macrosperma C.B. Clarke, Thalictrum foliolosum DC and Valeriana jatamansi Jones. Plant samples were dried, weighed, digested and analyzed for their mineral distribution level ranging from trace to major elements by graphite furnace-atomic absorption spectroscopy. All the medicinal herbs studied were found to contain the ten elements analyzed. The elemental concentration is given in mg/kg. Mg and Ca are present in high concentrations in both the roots and leaves of the plant samples. Among trace transition metals Fe had the highest concentration, followed by Mn, Cr, Cu, V, Zn, and Mo. Analysis showed that the toxic Cd element was at a lower concentration and is within the permissible limit of FAO/WHO, California standards and United States Pharmacopeia Limit for Nutritional Supplements.

Determination of Lead in Different Samples by Atomic Absorption Spectrometry after Preconcentration with Dithizone Immobilized on Surfactant-Coated Alumina

  • Dadfarnia, S.;Haji Shabani, A.M.;Dehgan Shirie, H.
    • Bulletin of the Korean Chemical Society
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    • v.23 no.4
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    • pp.545-549
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    • 2002
  • A simple and rapid technique for the separation and preconcentration of lead in water and biological samples has been devised. Preconcentrationis based on the depositionof analyte onto a column packed with dithizone immobilized on sodium dodecyl sulfate coated alumina at pH $\geq$ 3. The trapped lead is eluted with 5 mL of 4 M nitric acid and determined by flame atomic absorption spectroscopy. A sample of 1 L, results in a preconcentration factor of 200 and the precision at 20${\mu}g$ $L^{-1}$ is 1.3%(n=8). The procedure is applied to tap water, well water, river water, vegetable extract and milk samples, and accuracy is assessed through recovery experiments and by independent analysis by furnace atomic absorption.