DOI QR코드

DOI QR Code

Measurement of oxygen isotope ratio using tunable diode laser absorption spectroscopy

다이오드 레이저 흡수분광법을 이용한 산소 동위원소의 성분비 측정

  • Park, Sang-Eon (Time and Frequency Lab., Korea Research Institute of Standards and Science) ;
  • Jung, Do-Young (Lab. of Quantum Optics, Korea Atomic Energy Research Institute) ;
  • Kim, Jae-Woo (Lab. of Quantum Optics, Korea Atomic Energy Research Institute) ;
  • Ko, Kwang-Hoon (Lab. of Quantum Optics, Korea Atomic Energy Research Institute) ;
  • Im, Kwon (Lab. of Quantum Optics, Korea Atomic Energy Research Institute) ;
  • Jung, Eui-Chang (Lab. of Quantum Optics, Korea Atomic Energy Research Institute) ;
  • Kim, Chul-Joong (Lab. of Quantum Optics, Korea Atomic Energy Research Institute)
  • 박상언 (한국표준과학연구원 시간주파수 연구실) ;
  • 정도영 (한국원자력연구소 양자광학기술개발부) ;
  • 김재우 (한국원자력연구소 양자광학기술개발부) ;
  • 고광훈 (한국원자력연구소 양자광학기술개발부) ;
  • 임권 (한국원자력연구소 양자광학기술개발부) ;
  • 정의창 (한국원자력연구소 양자광학기술개발부) ;
  • 김철중 (한국원자력연구소 양자광학기술개발부)
  • Published : 2004.02.01

Abstract

Tunable diode laser absorption spectroscopy was performed for analysis of the H$_2$$^{18}$ O/H$_2$$^{16}$ O isotope ratio of a water sample which was enriched by the membrane distillation method. In order to improve the signal-to-noise ratio, the wavelength modulation spectroscopic method was used with a lock-in amplifier. The fringe noise could be suppressed by using the FFT (Fast Fourier Transform) lowpass filter and the optimization of the modulation depth of the laser frequency. The maximum deviation of $\delta$-value was measured to be$\pm$4$\textperthousand$.

분리막을 이용한 산소-18 분리실험에서 분리된 시료의 동위원소 성분비 분석을 위해 다이오드 레이저 흡수분광장치를 구성하였다. 흡수신호의 신호 대 잡음비를 높이기 위해 lock-in증폭기를 사용한 파장변조 분광법을 채택하였다. 레이저의 주파수 변조폭 최적화와 FFT 저역통과 필터링을 통해 다중반사흡수셀에서 발생하는 간섭무늬 잡음을 줄였다. 산소-18에 대한 흡수분광장치의 최대편차는 $\pm$4$\textperthousand$로 측정되었다.

Keywords

References

  1. Appl. Opt. v.32 no.33 Measurement of $^{12}CO_2:^{13}CO_2$ ratios for medical diagnostics with 1.6-μm distributed-feedback semiconductor diode lasers D.E.Cooper;R.U.Martinelli;C.B.Carlisle;H.Riris;D.B.Bour;R.J.Menna https://doi.org/10.1364/AO.32.006727
  2. Anal. Chem. v.52 no.3 Oxygen-18 and deuterium determination on a single water sample of a few milligrams N.Kishima;H.Sakal https://doi.org/10.1021/ac50052a038
  3. Spectrochim. Acta A. v.58 no.11 Determination of the ²H/¹H, $^{17}O/^{16}O$, and $^{18}O/^{16}O$ isotope ratios in water by means of tunable diode laser spectroscopy at 1.39 μm E.R.Th.Kerstel;G.Galiardi;L.Gianfrani;H.A.J.Meijer;R. van Trigt;R.Ramaker https://doi.org/10.1016/S1386-1425(02)00053-7
  4. Phys. Rev. B. v.59 no.18 Oxygen isotope effects on the critical and Curie temperatures and Raman modes in the ferromagnetic superconductor RuSr₂GdCu₂$O_8$ D.J.Pringle,J.L.Tallon;B.G.Walker;H.J.Trodahl https://doi.org/10.1103/PhysRevB.59.R11679
  5. Phys. Rev. Lett. v.86 no.9 Boron Isotope Effect in Superconducting MgB₂ S.L.Bud'Ko;G.Lapertot;C.Petrovic;C.E.Cunningham;N.Anderson;P.C.Canfield https://doi.org/10.1103/PhysRevLett.86.1877
  6. Phys. Rev. Lett v.89 no.1 All-Silicon Quantum Computer T.D.Ladd;J.R.Goldman;F.Yamaguchi;Y.Yamamoto;E.Abe;K.M.Itoh https://doi.org/10.1103/PhysRevLett.89.017901
  7. Sep. Sci. Technol. v.32 Multistage process of deuterium and heavy oxygen enrichment by membrane distillation A.G.Chmielewski;G.Zakrzewska-Trznadel;N.R.Miljevi;W. A. Van Hook https://doi.org/10.1080/01496399708003213
  8. Appl. Opt. v.19 no.19 Sensitivity limits of a tunable diode laser spectrometer with application to the detection of NO₂ at the 100-ppt level J.Reid;M.El-Sherbiny;B.K.Garside;E.A.Ballik https://doi.org/10.1364/AO.19.003349
  9. J. Opt. Soc. Am. B v.2 no.9 Brewster-plate spoiler: a novel method for reducing the amplitude of interference fringes that limit tunable-laser absorption sensitivities C.R.Webster https://doi.org/10.1364/JOSAB.2.001464
  10. Appl. Opt. v.27 no.10 Optical interference fringe reduction in laser absorption experiments J.A.Silver;A.C.Stanton https://doi.org/10.1364/AO.27.001914
  11. Appl. Opt. v.31 no.24 Novel etalon fringe rejection technique for laser absorption spectroscopy H.C.Sun;E.A.Whittacker https://doi.org/10.1364/AO.31.004998
  12. H. C. Sun and E. A. Whittacker, 'Novel etalon fringe rejection technique for laser absorption spectroscopy,' Appl. Opt. vol 31, no. 24, pp. 4998-5002 (1992). https://doi.org/10.1364/AO.31.004998