• Title/Summary/Keyword: Aromatic pesticides

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Effect of Adsorption on the Removal of Aromatic Pesticides by Hollow Fiber NF Membrane (중공사 나노여과막에 의한 방향족 농약의 제거에서 흡착의 영향)

  • Jung, Yong-Jun
    • Journal of Environmental Science International
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    • v.25 no.3
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    • pp.395-403
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    • 2016
  • This study examined the adsorption effect of aromatic pesticides by hollow fiber NF membrane on rejection and removal properties. Batch type adsorption test and hollow fiber NF membrane filtration were conducted with 5 different kinds of aromatic pesticides. 3 to 15 days were required to reach the equilibrium concentration and $0.3181{\sim}0.8094{\mu}g/cm^2$ were adsorbed to hollow fiber NF membrane. Since 5 hours of separation test were too short to keep steady state for permeate due to the repetition of sorption and desorption, longer times were required to evaluate the rejection performance of NF membrane. Sorption and desorption were confirmed by the separation test equipped with membrane and without membrane. Adsorption contribution of aromatic pesticides to hollow fiber membranes were shown to be ranged from 16.1% to 36.3% and indicated the difference considering sorption effect.

Rejection Properties of Aromatic Pesticides by a Hollow Fiber NF Membrane (중공사 나노여과막을 이용한 방향족 농약의 배제 특성)

  • Jung, Yong-Jun;Kiso, Yoshiaki;Park, Soon-Gil;Kim, Jong-Yong;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.296-300
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    • 2004
  • The rejection properties of 6 aromatic pesticides were evaluated by a continuous flow system equipped with a hollow fiber NF membrane. Different from the separation experiment of batch cell, the rejection and the removal could be calculated exactly because the concentration of feed, permeate and retentate was separately obtained. The lowest and the highest rejection were found in carbaryl(54.8%) and methoxychlor(99.2%), respectively, and the removals were always shown higher than rejections. This may be caused by some reasons such as the solute adsorption on the membrane, the variation of feed concentration. Although molecular weight, molecular width regarded as solute characteristics and log P(n-octanol/water partition coefficient) as hydrophobicity could be applied to explain the rejection property, these factors should be considered together for better analysis. According to the higher relationship between log B(solute permeability) and molecular weight, it was revealed that the solute separation with this membrane was influenced more by molecular weight.

Simultaneous determination of ultra-trace phenols, polycyclic aromatic hydrocarbons and pesticides in surface water by gas chromatography-mass spectrometry (지표수에서 GC-MS에 의한 극미량 페놀류, 다환방향족탄화수소류와 농약류의 동시 분석법)

  • Lee, Young Joon;Lee, Jun Bae;Hong, Seon Haw;Oh, Jin-Aa;Shin, Ho-Sang
    • Analytical Science and Technology
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    • v.25 no.6
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    • pp.467-475
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    • 2012
  • A gas chromatography-mass spectrometric (GC-MS) method was developed for determining 17 hazard compounds containing phenols, polycyclic aromatic hydrocarbons and pesticides in surface water. A 1.0 L surface water sample was placed in a separatory funnel and saturated with NaCl, and the solution was extracted with 40 mL of methylene chloride. Under the established condition, the lowest quantification limit was 1.0-10 ng/L and the relative standard deviations were less than 22%. The method was used to analyze 70 surface water samples collected from 35 regions in Gum-River. The samples revealed the compounds concentrations in the range of 1.1-26,604 ng/L. Maximum concentrations of compounds detected were not exceeded guidelines established in other countries. The developed method may be valuable for monitoring hazards in water.

A Study on Distribution Property of Micropollutants in Gwang-Yang Bay Sediment (광양만 저질에서의 미량오염물질 분포특성에 관한 연구)

  • Han Sang-Kuk;Park Ji-Young
    • Journal of Environmental Science International
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    • v.15 no.7
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    • pp.643-651
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    • 2006
  • This study investigated the distributive property of micropollutants in sediment around Gwang-yang bay using simultaneous analytical method of 310 chemicals. In the results, the major micropollutants detected were CH type chemicals such as aliphatic, polycyclic compounds, benzenes, and CHN(O) type chemicals aromatic amines, and pesticides. Insecticides of pesticide type were frequently detected at all sampling site. The total concentration of micropollutants were higher in summer than in winter and measured within the range of $ND{\sim}36.50{\mu}g/L$. Also, because of effect of seomjin river, GY6 of all sampling site detected by the highest concentration, GY10 and 11 located in Gwang-yang outside bay were not detected the micropollutants. From the result of this study, we should estimated that the industrial complex located in Gwang-yang inside bay and an inflow of fresh water through the Seomjin river are major pollution sources of Gwang-yang bay.

A Study on Distribution Property of Organic Pollutants in Southwest Coastal Waters (서남해 연안해역의 유기오염물질 분포특성에 관한 연구)

  • Han Sang-Kuk;Park Ji-Young;Lee Moon-Hee
    • Journal of Environmental Science International
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    • v.14 no.6
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    • pp.597-603
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    • 2005
  • In this study, we try to determine the distributive property in southwest coastal waters, such as K wang-yang bay, Ka-mak bay, Yeo-ja bay, Wan-do, Hea-nam, Young-gwang, and Mok-po, using simultaneous analytical method of 310 chemicals. The results were detected tens of the organic pollutants in sampling sites, and the major chemicals detected were CH type chemicals such as aliphatic, polycyclic compounds and were CHN(O) type chemicals such as aromatic amines, nitro compounds, In particular, pesticides were mainly detected in summer, phenols and phthalate esters were not seasonal effect. Also, a number of aromatic chemicals were detected in Kwang-yang bay, From the results of this study, we confirmed that it is mainly contaminated in summer and the pesticide chemicals are the major pollutants in southwest coastal waters.

Harmful Environmental Factors Leading to Attention-Deficit Hyperactivity Disorder (아동기 주의력결핍 과잉행동장애의 유해환경인자)

  • Kwon, Ho Jang;Ha, Mina;Kim, Bung Nyun;Lim, Myung Ho
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.27 no.4
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    • pp.267-277
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    • 2016
  • Attention-deficit hyperactivity disorder (ADHD) is a common, childhood-onset, neuropsychiatric disorder with an estimated prevalence of 2-7.6% in Korean children. Although the etiology of ADHD is not well understood, evidence from genetic factor and environmental factor studies suggests that ADHD results from a gene environmental interaction. In the current study, we reviewed the evidence for and clinical implications of the hypothetical roles of organophosphate pesticides, organochlorine pesticides, polychlorinated biphenyls, phthalate, bisphenol, polyfluoroalkyl chemicals, polycyclic aromatic hydrocarbons, mercury, lead, arsenic, cadmium, manganese, tobacco, alcohol as harmful risk factors in the development of ADHD.

Quantitative Assessment of Micropollutants in the Southern Coastal Waters of Korea (남해 연안 해역에 있어서 미량유기오염물질의 정량적 평가)

  • Han, Sang-Kuk;Park, Ji-Young;Lee, Jong-Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.4
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    • pp.213-219
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    • 2005
  • In this study, we try to Quantitatively assess the micropollutants in Gwangyang bay, Gamag bay and Yeoa bay, using simultaneous analytical method fir 310 chemicals. In the results, several dozen organic pollutants were detected in sampling sites, and the major chemicals detected were CH type chemicals, such as aliphatic and polycyclic compounds, and CHN(O) type chemicals, such as aromatic ammines and nitro compounds. The concentration of organic pollutants was higher in summer than in winter. However, there was no association of species of organic pollutants with season. The total concentration of pesticides at each sampling site was measured within the range of $ND{\sim}9.11{\mu}g/L$. Insecticides and fungicides of pesticide type were detected in Gwangyang bay and Gamag bay, while six kinds of endocrine disrupter were detected in southern coastal waters. From the results of this study, we should estimated that the insecticides, the fungicides, and a few of the endocrine disrupters are major pollutant factors in southern coastal waters.

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Concentration Variations of Persistent Organic Pollutants in Gosan, Jeju during the Polluted Period in November 2001 and the Yellow Sand Period in Spring 2002 (2001년 11월 오염시기와 2002년 봄 황사시기 제주도 고산에서의 잔류성 유기오염물질 농도 변화)

  • 김영성;김진영;김연제;문길주;문광주;한진석;김상우;윤순창;권성안
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.469-490
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    • 2003
  • Atmospheric concentrations of persistent organic pollutants (POPs) were measured at Gosan, Jeju in November 2001 and spring 2002, each time for two weeks. Primary target pollutants were organochlorine pesticides, coplanar polychlorinated biphenyls (co- PCBs), and dioxin/furans listed in the Stockholm Convention adopted in May 2001. Polycyclic aromatic hydrocarbons (PAHs) were also measured in order to understand the overall characteristics of the POPs distribution as well as PM$_{2.5}$, a potent carrier of POPs. In the latter part of the measurement period of November 2001, almost every pollutant of combustion origin including dioxin/furans went high probably due to influence of emissions in the nearby area. The characteristics of atmospheric environment at Gosan in this period were rather close to urban areas far from those of a background area. A severe dust storm swept for three days at the end of the measurement period of spring 2002. However, changes in pollutant concentrations were relatively small except PM$_{10}$. Nevertheless, increases in particulate PAHs and OCDD (octachlorinated dibenzo-p-dioxins), mostly present in fine particles, were observed. Trends in organochlorine pesticide variations were mixed although possible volatilization of DDT residues from soil was inferred from the measurements of spring 2002.2.2.

전남지역 하${\cdot}$폐수처리장 방류수중의 유기오염물질 분포특성과 그들의 독성 평가

  • Lee, Mun-Hui;Han, Sang-Guk
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2007.05a
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    • pp.518-521
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    • 2007
  • 생활하수처리장과 농공단지폐수처리장 방류수의 화학분석과 in vitro bio-assay를 통한 세포독성의 결과를 통해 다음과 같은 결론을 얻었다. 1) 다성분 동시분석법을 통해 다양한 성상을 가진 9곳의 방류수에서는 phenol, aliphatic compounds, polycyclic compounds, phthalate, pesticides, aromatic amines, benzens, nitro compounds이 주오염물질로 검출이 되었다. 2) 세포독성을 나타내는 TU값이 생활하수에서는 화학분석에 결과 다종고농도의 유기오염물질이 검출된 A지점과 농공폐수의 F지점에서 높게 나타났다. 즉, 화학분석결과와 in vitro bio-assay에 의한 상관관계를 유추해 볼 수 있다. 3) S9 mixture에 따른 대사활성으로 난분해성, 소수성 유기오염물질에 대한 세포독성에 악영향을 미침을 알 수 있다.

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Biodecolorization and Biodegradation of Dye by Fungi: A Review (곰팡이를 이용한 염료의 탈색 및 생분해)

  • Cho, Kyung-Suk;Ryu, Hee Wook
    • KSBB Journal
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    • v.30 no.5
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    • pp.203-222
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    • 2015
  • In recent years, there has been an intensive research on the application of degradative activities of fungi for treatment of various non-degradable materials such as petroleum hydrocarbons, polychlorinated biphenyls, pesticides, polycyclic aromatic hydrocarbons, dyes and so on. Chief of all, the fungal treatment technology is received the spotlight as one of the most promising alternatives to replace present methods for the treatment of dye wastewater. The present paper reviews the recent trend in research on the decolorization and biodegradation of dyes by various fungi, and improvements in bioreactors and bioprocesses involved the fungal treatment of dye wastewater. It also discusses alternatives and perspectives for the innovation of mycoremediation to treat dye wastewaters.