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http://dx.doi.org/10.5806/AST.2012.25.6.467

Simultaneous determination of ultra-trace phenols, polycyclic aromatic hydrocarbons and pesticides in surface water by gas chromatography-mass spectrometry  

Lee, Young Joon (Geum River Environment Research Center, National Institute of Environmental Research)
Lee, Jun Bae (Geum River Environment Research Center, National Institute of Environmental Research)
Hong, Seon Haw (Geum River Environment Research Center, National Institute of Environmental Research)
Oh, Jin-Aa (Department of Environmental Science, Kongju National University)
Shin, Ho-Sang (Department of Environmental Education, Kongju National University)
Publication Information
Analytical Science and Technology / v.25, no.6, 2012 , pp. 467-475 More about this Journal
Abstract
A gas chromatography-mass spectrometric (GC-MS) method was developed for determining 17 hazard compounds containing phenols, polycyclic aromatic hydrocarbons and pesticides in surface water. A 1.0 L surface water sample was placed in a separatory funnel and saturated with NaCl, and the solution was extracted with 40 mL of methylene chloride. Under the established condition, the lowest quantification limit was 1.0-10 ng/L and the relative standard deviations were less than 22%. The method was used to analyze 70 surface water samples collected from 35 regions in Gum-River. The samples revealed the compounds concentrations in the range of 1.1-26,604 ng/L. Maximum concentrations of compounds detected were not exceeded guidelines established in other countries. The developed method may be valuable for monitoring hazards in water.
Keywords
phenols; polycyclic aromatic hydrocarbons; pesticides; gas chromatography-mass spectrometry; surface water;
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