• 제목/요약/키워드: Amorphous matrix

검색결과 230건 처리시간 0.027초

스트레처블 배선용 저저항 알루미늄-몰리브데늄 합금에 대한 연구 (A study on the Low Resistance Aluminum-Molybdenum Alloy for stretchable metallization)

  • 이민준;배진원;박수연;최재익;김건호;서종현
    • 한국표면공학회지
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    • 제56권2호
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    • pp.160-168
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    • 2023
  • Recently, investigation on metallization is a key for a stretchable display. Amorphous metal such as Ni and Zr based amorphous metal compounds are introduced for a suitable material with superelastic property under certain stress condition. However, Ni and Zr based amorphous metals have too high resistivity for a display device's interconnectors. In addition, these metals are not suitable for display process chemicals. Therefore, we choose an aluminum based amprhous metal Al-Mo as a interconnector of stretchable display. In this paper, Amorphous Forming Composition Range (AFCR) for Al-Mo alloys are calculated by Midema's model, which is between 0.1 and 0.25 molybdenum, as confirmed by X-ray diffraction (XRD). The elongation tests revealed that amorphous Al-20Mo alloy thin films exhibit superior stretchability compared to pure Al thin films, with significantly less increase in resistivity at a 10% strain. This excellent resistance to hillock formation in the Al20Mo alloy is attributed to the recessed diffusion of aluminum atoms in the amorphous phase, rather than in the crystalline phase, as well as stress distribution and relaxation in the aluminum alloy. Furthermore, according to the AES depth profile analysis, the amorphous Al-Mo alloys are completely compatible with existing etching processes. The alloys exhibit fast etch rates, with a reasonable oxide layer thickness of 10 nm, and there is no diffusion of oxides in the matrix. This compatibility with existing etching processes is an important advantage for the industrial production of stretchable displays.

Microstructure and Magnetic Characteristics of Mn-doped Finemet Nanocomposites

  • Le, Anh-Tuan;Kim, Chong-Oh;Chau Nguyen;Tho Nguyen Duc;Hoa Nguyen Quang;Lee, Hee-Bok
    • Journal of Magnetics
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    • 제11권1호
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    • pp.30-35
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    • 2006
  • A thorough study about the influences of Mn substitution for Fe on the microstructure and magnetic characteristics of $Fe_{73.5-x}Mn-{x}Si_{13.5}B_{9}Nb_{3}Cu_1$ (x = 1, 3, 5) alloys prepared by the melt-spinning technique has been performed. Nanocomposites composed of nanoscale $(Fe,Mn)_{3}Si$ magnetic phase embedded in an amorphous matrix were obtained by annealing their amorphous alloys at $535^{\circ}C$ for 1 hour. The addition of Mn causes a slight increase in the mean grain size. The Curie temperatures of the initial amorphous phase and of the nanocrystals phase decreased, while the Curie temperature of the remaining amorphous phase remained nearly constant with increasing Mn content. Soft magnetic properties of the crystallized samples have been significantly improved by a proper thermal treatment. Accordingly, the giant magnetoimpedance effect is observed and ascribed to the increase of the magnetic permeability, and the decrease of the coercivity of the samples. The increased magnetic permeability is resulted from a decrease in the magnetocrystalline anisotropy and saturation magnetostriction.

고체분산체를 이용한 약물의 생체이용율 향상을 위한 전략 (Solid Dispersion as a Strategy to Improve Drug Bioavailability)

  • 박준형;전명관;조훈;최후균
    • KSBB Journal
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    • 제26권4호
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    • pp.283-292
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    • 2011
  • Solid dispersion is one of well-established pharmaceutical techniques to improve the dissolution and consequent bioavailability of poorly water soluble drugs. It is defined as a dispersion of drug in an inert carrier matrix. Solid dispersions can be classified into three generations according to the carrier used in the system. First and second generations consist of crystalline and amorphous substances, respectively. Third generation carriers are surfactant, mixture of polymer and surfactants, and mixture of polymers. Solid dispersions can be generallyprepared by melting method and solvent method. While melting method requires high temperature to melt carrier and dissolve drug, solvent method utilizes solvent to dissolve the components. The improvement in dissolution through solid dispersions is attributed to reduction in drug particle size, improvement in wettability, and/or formation of amorphous state. The primary characteristics of solid dispersions, the presenceof drug in amorphous state, could be determined by differential scanning calorimetry (DSC), powder X-ray diffraction (PXRD), and fourier-transformed infrared spectroscopy (FTIR). In spite of the significant improvement in dissolution by solid dispersion technique, some drawbacks have limited the commercial application of solid dispersions. Thus, further studies should be conducted in a direction to improve the congeniality to commercialization.

액체급랭응고법으로 제조된 리튬 이차전지 음극활물질용 Si50Al30Fe20 비정질 합금의 결정화 거동 및 전기화학적 특성 (Crystallization Behavior and Electrochemical Properties of Si50Al30Fe20 Amorphous Alloys as Anode for Lithium Secondary Batteries Prepared by Rapidly Solidification Process)

  • 서덕호;김향연;김성수
    • 한국전기전자재료학회논문지
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    • 제32권4호
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    • pp.341-348
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    • 2019
  • This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as $Fe_2Al_3Si_3$, $FeSi_2$, and $Fe_{0.42}Si_{2.67}$, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately $700mAh^{g-1}$, and exhibited a high Coulombic efficiency of 99.0~99.6% from the $2^{nd}$ to $70^{th}$ cycles.

Active-Matrix Field Emission Display with Amorphous Silicon Thin-Film Transistors and Mo-Tip Field Emitter Arrays

  • Song, Yoon-Ho;Hwang, Chi-Sun;Cho, Young-Rae;Kim, Bong-Chul;Ahn, Seong-Deok;Chung, Choong-Heui;Kim, Do-Hyung;Uhm, Hyun-Seok;Lee, Jin-Ho;Cho, Kyoung-Ik
    • ETRI Journal
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    • 제24권4호
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    • pp.290-298
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    • 2002
  • We present, for the first time, a prototype active-matrix field emission display (AMFED) in which an amorphous silicon thin-film transistor (a-Si TFT) and a molybdenum-tip field emitter array (Mo-tip FEA) were monolithically integrated on a glass substrate for a novel active-matrix cathode (AMC) plate. The fabricated AMFED showed good display images with a low-voltage scan and data signals irrespective of a high voltage for field emissions. We introduced a light shield layer of metal into our AMC to reduce the photo leakage and back channel currents of the a-Si TFT. We designed the light shield to act as a focusing grid to focus emitted electron beams from the AMC onto the corresponding anode pixel. The thin film depositions in the a-Si TFTs were performed at a high temperature of above 360°C to guarantee the vacuum packaging of the AMC and anode plates. We also developed a novel wet etching process for $n^+-doped$ a-Si etching with high etch selectivity to intrinsic a-Si and used it in the fabrication of an inverted stagger TFT with a very thin active layer. The developed a-Si TFTs performed well enough to be used as control devices for AMCs. The gate bias of the a-Si TFTs well controlled the field emission currents of the AMC plates. The AMFED with these AMC plates showed low-voltage matrix addressing, good stability and reliability of field emission, and good light emissions from the anode plate with phosphors.

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비정질강섬유 보강콘크리트 작업성 및 섬유 분산성 비교분석 (Comparison Analysis of Fiber Distribution and Workability for Amorphous Steel Fiber Reinforced Concrete)

  • 김병일;이세현
    • 자원리싸이클링
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    • 제23권4호
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    • pp.47-57
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    • 2014
  • 본 논문에서는 비정질 강섬유의 길이 및 혼입률 변화에 의한 섬유보강콘크리트의 작업성과 섬유분산성에 대한 기초연구를 수행하였다. 일반적인 슬럼프시험 외에 역슬럼프 및 베베시험을 이용하여 일반 강섬유와는 외관 및 형상이 다른 비정질 감섬유의 유동성을 평가하였다. 실험결과, 얇은 판상형의 비정질강섬유의 작업성 평가를 위해서는 일반적인 슬럼프시험보다는 진동 하에서 수행된 역슬럼프 및 베베시험을 통한 유동성 평가가 바람직한 것으로 나타났다. 결론적으로 섬유의 혼입률 및 길이 증가는 콘크리트의 유동성을 현저히 감소시켰으며, 시멘트 메트릭스내에서 섬유간 간격 또한 감소시키는 결과를 보여주었다.

초고속화염용사법으로 제조된 Ni-Cr-W-Mo-B 합금 코팅의 미세조직과 특성에 미치는 열처리 효과 (Effect of Heat Treatment on the Microstructures and Properties of HVOF Sprayed Ni-Cr-W-Mo-B Alloy Coatings)

  • 민경오;이창희
    • Journal of Welding and Joining
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    • 제18권6호
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    • pp.48-54
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    • 2000
  • The corrosion properties of Ni-Cr-W-Mo-B alloy sprayed by the high velocity oxy-fuel spraying (HVOF) was studied as a function of heat treatment by using both potentiodynamic polarization and immersion tests in the H₂SO₄ solution. The mechanical property was also evaluated by a microhardness tester. Microstructural characteristics of te as-sprayed and annealed coatings at 550, 750 and 950℃ have been analyzed by means of OM, XRD, SEM and TEM. The results showed that the corrosion resistance was improved by increasing the annealing temperature. As-sprayed coating had metastable and heterogeneous phases such as amorphous, nanocrystalline and very refined grain and precipitates, which induced a localized corrosion. The localized corrosion occurred preferentially at the unmelted particles which were composed of Ni matrix and Cr, W and Mo riched phase segregated in the boundaries. As annealing temperature was increased, the microstructure had shown some changes - reduction of porosity and s[plat boundary decomposition and crystallization of amorphous/nanocrystalline phases, grain coarsening,, formation and growth of precipitates such as {TEX}$M_{23}C_{6}${/TEX} and {TEX}$M_{7}C_{3}${/TEX}. In addition, the compositional difference between matrix and boundary phases gradually disappeared, which changed the corrosion type from localized corrosion to general corrosion and thus enhanced corrosion resistance.

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용탕단조한 $Al/Al_2O_3$ 복합재료에서의 예비성형체 변형 및 섬유열처리 영향 (Preform Deformation and Fiber Heat-Treatment Effect in Squeeze Cast $Al/Al_2O_3$ Metal Matrix Composites)

  • 지동철;정성실;조경목;박익민;김진
    • 한국주조공학회지
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    • 제13권1호
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    • pp.62-70
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    • 1993
  • This study presents the effect of applied pressure on the preform deformation during squeeze casting of $Al_2O_3$ short fiber reinforced aluminum alloy (AC8A) metal matrix composites. A preliminary model based on the general beam theory is suggested for the prediction of the preform deformation. Two different commercially available $Al_2O_3$ short fiber (Saffil, Kaowool) were used to study the influence of the fibers on the microstructure and mechanical properties of the squeeze cast $Al/Al_2O_3$ composites. The composites were fabricated with the applied pressure of 75 MPa which was found to be the optimum condition for the squeeze casting of the composites in this study. For the amorphous Kaowool fiber, hard crystalline Mullite phase was formed with heat treatment. Both of amorphous and the crystallized Kaowool fibers were used to fabricate $Al/Al_2O_3$ composites. Microhardness of crystallized Kaowool fiber revealed higher than that of the amorphous Kaowool fiber in the squeeze cast composites. It was also found that the wear resistance of Kaowool fiber reinforced composites increased with the amount of Mullite.

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한국인 태아 조기질의 미세구조에 관한 연구 (The Fine Structure of Human Fetal Nail Matrix)

  • 손형선;최재권;정윤영;배춘상
    • Applied Microscopy
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    • 제26권1호
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    • pp.79-93
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    • 1996
  • The differentiation of nail matrix and fine structure of matrix cells were studied with light and electron microscope using specimens from nails of thumb finger in Korean fetuses 14 to 24 weeks old. Fetal nail matrix consisted of two horizontal layers, thicker ventral and thinner dorsal matrices, originating from invagination of epidermis in proximal nail field. Matrix being generally thicker in its distal region than the apex became gradually thickened with increase of the fetal age. Each matrix consisted of single layer of basal cells and multiple layers of squamous cells which are arranged close to and parallel to the central axis of the nail mairix. The process of keratinization of fetal nail matrix was noted to be occured concurrently in the ventral and dorsal matrices along the central axis of matrix toward distal and dorsal direction. Squamous cells became matured with accumulation of tonofilaments, increase of keratohyalin granules, discharge of membrane coating granules, and narrowing of intercellular spaces, thickening of plasma membrane and finally being transformed into horny cells of nail plate. Horny cells of nail plate filled with fibrous elements in the electron dense amorphous substance. These findings of keratinization process of fetal nail matrix appeared to be similar to those of keratinization in epidermis and inner root sheath of the hair. In the nail matrix, however, corresponding region to the keratogenous zone of growing hair follicle was not observed. Vacuolated squamous cells of nail matrix seen on light microscopy was considered to be artefactual product, but squamous cells with condensed small nuclei rarely found adjacent nail plate was considered to be one of the squamous cells with unknown function. Proximal end of nail plate was observed on dorsal surface of nail field distal to the proximal nail fold at 14 and 16 weeks old human embryos. Proximal prolongation of the proximal end of nail plate was occured with advancing fetal age and afterward 21 weeks nail plate invaded into nail matrix. Melanin granule containing cells and Merkel cells were present only on the basal layer of dorsal nail matirx.

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Fabrication of Charge-pump Active-matrix OLED Display Panel with 64 ${\times}$ 64 Pixels

  • Na, Se-Hwan;Shim, Jae-Hoon;Kwak, Mi-Young;Seo, Jong-Wook
    • Journal of Information Display
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    • 제7권1호
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    • pp.35-40
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    • 2006
  • Organic light-emitting diode (OLED) display panel using the charge-pump (CP) pixel addressing scheme was fabricated, and the results show that it is applicable for information display. A CP-OLED panel with 64 ${\times}$ 64 pixels consisting of thin-film capacitors and amorphous silicon Schottky diodes was fabricated using conventional thin-film processes. The pixel drive circuit passes electrical current into the OLED cell during most of the frame period as in the thin-film transistor (TFT)-based active-matrix (AM) OLED displays. In this study, the panel was operated at a voltage level of below 4 V, and this operation voltage can be reduced by eliminating the overlap capacitance between the column bus line and the common electrode.