• Title/Summary/Keyword: Alternative Phosphorus

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Paddy Rice Culture Experiment Using Treated Sewage Effluent From Constructed Wetland (인공습지 오수처리수를 이용한 벼재배 실험)

  • 윤춘경;함종화;우선호;김민희
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.2
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    • pp.94-104
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    • 2001
  • A pilot study was performed at the experimental field of Konkuk University in Seoul, to examine the feasibility of the constructed wetland system for sewage and the effect of treated sewage irrigation on the paddy rice culture and its soil characteristics. The constructed wetland performed well, in that effluent concentrations of pollutants were significantly lower than concentrations of the influent. Median removal efficiencies of BOD$_{5}$ was about 78% and slightly lower during winter. Removal efficiencies form TN and TP were approximately 48 and 21%, respectively, and relatively less effective than that of BOD$_{5}$. Irrigation of treated sewage to paddy rice culture did not affect adversely in both growth and yield of rice. Instead, plots of treated sewage irrigation showed up to 50% more yield in average than the control plot. It implies that treated sewage irrigation might be beneficial to rice culture rather than detrimental as long as it is treated adequately and used properly. Soil was sampled and analyzed before transplanting and after harvesting. pH was slightly increased due to irrigation water, but it may not be concerned as long as the treated sewage is within the normal range. EC was increased in first year but decreased in second year, therefore salts accumulation in the soil could be less concerned. OM and CES was slightly increased, which might be beneficial on growing plants. TN did not show apparent pattern. Available phosphorus was decreased after rice culture, but the quantity of phosphorus(TP-available phosphorus) was rather increased which implies that excessive phosphorus supply may result in phosphorus accumulation in the soil. Overall, the constructed wetland was thought to be an effective sewage treatment alternative, and treated sewage could be reused as a supplemental source of irrigation water for paddy rice culture without causing adverse effect as long as it is treated adequately and used properly. For full-scale application, further investigation should be followed on environmental risk assessment, tolerable water quality, and fraction of supplemental irrigation.ion.

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Effect of Phosphorus Removal by Oyster Shell on Longevity of Constructed Wetlands (굴패각에 의한 인 처리가 인공습지의 수명에 미치는 영향)

  • Kim, Seong-Heon;Kim, Hong-Chul;Park, Jong-Hwan;Ryu, Seong-Ki;Kang, Se-Won;Cho, Ju-Sik;Seo, Dong-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.37 no.1
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    • pp.66-72
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    • 2018
  • BACKGROUND: Constructed wetlands are low-cost alternatives for treating domestics sewage. However, previous study has reported that the removal of phosphorus in constructed wetlands was limited. Therefore, a new alternative was needed to extend the life of the constructed wetlands. The purpose of this study was to evaluate the effect of total phosphorus removal by oyster shell on longevity of constructed wetlands for treating domestic sewage. METHODS AND RESULTS: The changes of total phosphorus concentration and treatment efficiency in two constructed wetlands (CWs) classified as system A (coarse sand 100%) and system B (coarse sand 90%+oyster shell 10%) were investigated for 6 years. The actual saturation time of total phosphorus in the systems A and B was estimated to be longer than that of theoretical saturation by adsorption isotherm experiment. In particular, the saturation pattern of phosphorus in system A was maintained at a certain concentration level in the initial stage of operation, and finally saturation was reached as the saturation gradually progressed from the breaking point. In system B, the saturation period of phosphorus was prolonged as compared with system A due to the addition of oyster shells. CONCLUSION: Our results suggest that the longevity of the constructed wetlands can be extended due to the phosphorus saturation by adding the oyster shells to the coarse sands in constructed wetlands.

Cultivation of Spirulina platensis Using Pig Wastewater in a Semi-Continuous Process

  • Chaiklahan, Ratana;Chirasuwan, Nattayaporn;Siangdung, Wipawan;Paithoonrangsarid, Kalyanee;Bunnag, Boosya
    • Journal of Microbiology and Biotechnology
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    • v.20 no.3
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    • pp.609-614
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    • 2010
  • The effluent from anaerobic digestion contains organic nitrogen and phosphorus, which are both required for growth of Spirulina platensis. Effluent (20%) from the upflow anaerobic sludge blanket (UASB) from a pig farm, supplemented with 4.5 g/l sodium bicarbonate ($NaHCO_3$) and 0.2 g/l urea fertilizer (46:0:0, N:P:K), was found to be not only a suitable medium for the growth of Spirulina platensis but also a low-cost alternative. Cost calculation showed that this medium is 4.4 times cheaper than modifized Zarrouk's medium. The average productivities of a semi-continuous culture grown under outdoor conditions in a 6-1 scale and a 100-1 pilot scale were 19.9 $g/m^2/d$ and 12 $g/m^2/d$, respectively. In addition, the biomass of organisms grown in UASB effluent contained approximately 57.9% protein, 1.12% $\gamma$-linolenic acid, and 19.5% phycocyanin. The average rates of bicarbonate, total nitrogen, and phosphorus removal were 380 mg/l/d, 34 mg/l/d, and 4 mg/l/d, respectively.

Optimization of TiCl4 Concentration and Initial pH for Phosphorus Removal in Synthetic Wastewater (합성폐수 내 인을 제거하기 위한 TiCl4 농도 및 초기 pH 최적조건 도출)

  • Shin, So-Yeun;Kim, Jong-Ho;Ahn, Johng-Hwa
    • Journal of Korean Society on Water Environment
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    • v.31 no.6
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    • pp.619-624
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    • 2015
  • This study experimentally determined the effect of titanium tetrachloride (TiCl4) concentration ([TiCl4]) (0.25-0.55 mM) and initial pH (3-11) on phosphorus (P) removal in synthetic wastewater (2 mg P/L). The P removal efficiency increased when [TiCl4] increased. The P removal efficiency showed a parabolic trend with an inflection point at pH 7. At the molar ratio of TiCl4 and P>6.2, the P removal efficiency was over 90% and the residual P concentration was less than 0.2 mg/L. Within the design boundaries, the complete P removal could be achieved at 7.0≤initial pH≤8.5 and 0.43≤[TiCl4]≤0.55 mM. The final pH was over 5.8 at initial pH≥7.7 and [TiCl4]≥0.35 mM. The results showed that TiCl4 was effective in P removal in water so that it could be an alternative chemical for P removal.

Dephosphorylation of Phytate from Rice Bran and Soybean Meal Using Phytases from Aspergillus sp. 5990

  • Kim Jong Soon;Kim Doo-Sang;Kim Hyeng-Rak;Shin Tai-Sun;Kim Heung-Yoon;Oh Myong-Joo;Byun Dae-Seok
    • Fisheries and Aquatic Sciences
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    • v.7 no.2
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    • pp.51-57
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    • 2004
  • Total phosphorus contents in rice bran and soybean meal were determined to be 5.81 and $2.77\%$, respectively, and $97.2\%$ of phosphorus in rice bran and $66.4\%$ in soybean meal were presented as phytate phosphorus. Optimum pH condition for hydrolysis of phytate in rice bran and soybean was determined to be in the pH range of 3.7 and 5.3. The highest activity of phytase for hydrolysis of phytate in both samples was determined to be at $55^{\circ}C$ for rice bran and $55-60^{\circ}C$ for soybean. Hydrolysis of phytate in soybean meal at pH 5.0 increased with the co-reaction or consecutive reaction with protease; however, in rice bran hydrolysis decreased with co-reaction with protease. Phytate degradation of soybean meal in the presence of pepsin at pH 2.5 showed higher than that of rice bran. Phytate degradation of rice bran in the presence of trypsin or pancreatin at pH 7.0 increased the activity around 2-times compared with the activity in the absence of trypsin or pancreatin. The results of this study suggest that hydrolysis of phytate in rice bran or soybean meal with phytase and protease may provide an alternative process for the preparation of aquacultural feed with a low level of organic phosphorus.

Reuse of Treated Sewage Water from Absorbent Biofilter System as Agricultural Water Resources (농업수자원으로서의 흡수성 Biofilter 처리수 재이용)

  • 권순국;김현욱;권용웅;조영현;박상원;임경래
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.5
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    • pp.151-159
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    • 2003
  • Absorbent Biofilter Systems (ABS), composed of an anaerobic septic tank, a pump chamber and an absorbent biofilter tank, have been found to economically provide rural on-site wastewater treatment. This study was conducted to assess the potential of ABS effluent as an alternative water resource for agricultural and environmental use, with respect to the removal of pathogenic microorganism and their fertilization effect. A pilot scale ABS was used to compare its removal efficiency of pathogens from effluent water. Overall, more than 95 percent of Salmonella and E. coli were removed. This result demonstrates that a significant reduction in the pathogenic microorganism of effluents can occur in ABS, which implies the feasibility for the use of ABS effluent in agriculture and environment, with the provision of a further simple disinfection step, in order to satisfy the WHO guidelines for the microbiological quality in agriculture. In addition, because of the abundant nutritional content of ABS effluent, the substitution effect of fertilizer (N, P and K) in paddy irrigation, i.e. 2/3 for nitrogen, l/3 for phosphorus and 1/5 for potassium would be expected. Based on the experimental data, the ABS effluent could be used as a new alternative water resource for paddy irrigation, as well as for environmental purposes, such as supplying water to ecological parks in rural villages.

A Study on Water Quality Improvement of Hoeya Dam Reservoir Using Ecological Constructed Wetland (생태적 인공습지를 이용한 회야댐 수질개선에 관한 연구)

  • Lee, Sang-Hyeon;Cho, Yun-Chul
    • Journal of Wetlands Research
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    • v.13 no.3
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    • pp.489-497
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    • 2011
  • In this study the main purpose is to reduce non-point source pollution and improve water quality of Hoeya reservoir using constructed wetlands. As part of the efforts to improve water quality of the reservoir, cattail and reed-wetland cells were constructed in front of the reservoir to remove nitrogen(N) and phosphorus(P). Also, effects of hydraulic and seasonal variation on removal efficiencies of N and P were investigated. Total P and N removal efficiencies of the wetland system were approximately 20.7% and 42.7%, respectively. Removal efficiencies of N and P during the growth season (july to august) and blooming season of cattail and reed (september to october) were higher than other seasons. These results suggest that wetland system could be an effective alternative for control of non-point source pollutnat such as N and P of reservoir.

Adsorption kinetics and isotherms of phosphate and its removal from wastewater using mesoporous titanium oxide

  • Lee, Kwanyong;Jutidamrongphan, Warangkana;Lee, Seokwon;Park, Ki Young
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.161-169
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    • 2017
  • The adsorption of phosphate onto mesoporous $TiO_2$ was investigated in order to reduce phosphorus concentrations in wastewater and provide a potential mode of phosphorus recovery. Three equilibrium isotherms were used to optimize and properly describe phosphate adsorption ($R^2$>0.95). The maximum capacity of phosphate on the adsorbent was found to be 50.4 mg/g, which indicated that mesoporous $TiO_2$ could be an alternative to mesoporous $ZrO_2$ as an adsorbent. A pseudo-second order model was appropriately fitted with experimental data ($R^2$>0.93). Furthermore, the suitable pH for phosphate removal by $TiO_2$ was observed to be in the range of pH 3-7 in accordance with ion dissociation. In contrast, increasing the pH to produce more basic conditions noticeably disturbed the adsorption process. Moreover, the kinetics of the conducted temperature study revealed that phosphate adsorption onto the $TiO_2$ adsorbent is an exothermic process that could have spontaneously occurred and resulted in a higher randomness of the system. In this study, the maximum adsorption using real wastewater was observed at $30^{\circ}C$.

Ecotoxicity Assessment of Potassium Hydrogen Phthalate and Verification of Standard Reference Toxicity Test Method Using Potassium Hydrogen Phthalate

  • Dong Jin Choi
    • Proceedings of the National Institute of Ecology of the Republic of Korea
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    • v.4 no.1
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    • pp.49-62
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    • 2023
  • Phthalates are animal carcinogens. Potassium hydrogen phthalate (KHP), which has the least complicated structure among phthalates, is used for the analysis of total organic carbon and formaldehyde. However, its toxicity has not been confirmed. A 24-hour acute toxicity test was performed using Daphnia magna, a water flea used to evaluate aquatic toxicity owing to its high sensitivity. The lowest observed effect concentration of KHP was found to be 240 mg/L. The effects of phosphorus, nitrogen, and Cr(6+), which are able to be discharged along with KHP, were also confirmed using tests. At 240 mg/L KHP, toxicity increased as phosphorus, nitrogen, and Cr(6+) increased. In addition, tests were performed to confirm the half maximal effective concentration of KHP. Through 10 test repetitions, the average ecotoxicity value was found to be 0.3, the average half maximal effective concentration was 327.75 mg/L, and the coefficient of variation (%) was 3.16%; because the latter value is lower than 25%, which is what is generally suggested for the water pollution standard method, the reproducibility of the tests is sufficient to replace the existing standard reference toxicity test that uses potassium dichromate. In addition, the half maximum effective concentration of potassium hydrogen phthalate is approximately 218 times more than that of potassium dichromate; therefore, toxicity is relatively low. In conclusion, KHP is a feasible alternative to the highly toxic potassium dichromate for performing the standard reference toxicity test.

Evaluation of Bio-V-Pro® as an Alternative Protein Source in Broiler Diets

  • Han, In K.;Kim, J.H.;Piao, X.S.;Bae, S.H.;Han, Y.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.1
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    • pp.71-77
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    • 1998
  • The experiment was conducted to evaluate Bio-V-Pro as an alternative protein source in broiler diets. Treatments were control, Bio-V-Pro 1% (BP 1), Bio-V-Pro 3% (BP 3), and Bio-V-Pro 5% (BP 5). During the starter period, all treated groups showed beter performance than control group in weight gain and feed intake (p < 0.05). The best FCR was observed in BP 1 group and the worst was found in BP 5 group. For the overall period, chicks fed BP 1 and BP 3 diets gained more than the chicks fed the control and BP 5 diets. All Bio-V-Pro fed groups consumed more feed than the control group (p < 0.05). FCR were similar between the control and BP 1 group, but BP 3 and BP 5 groups showed higher FCR than the control group. During the starter period, all BP groups showed better utilizability of crude protein, crude ash and phosphorus than the control group (p < 0.05). For the finisher period, except for the BP 5 group, the nutrient utilizability was not significantly different in most nutrients. Nutrients utilizability had a tendency (not significant) to decrease as the level of Bio-V-Pro in the diet was increased. Lysine utilizability was not affected by the dietary treatment, however, methionine utilizability was higher in BP 1 and BP 3 group than in the control group. From the results of this experiment, it seems that Bio-V-Pro is a good alternative protein source which can replace fish meal in starter diet up to 3% of the diet effectively.