• 제목/요약/키워드: Al-bound P

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추계 대청호 퇴적물 내 인의 지화학적 특성 (Geochemical Properties of Sedimentary Phosphorus of Daechung Lake in Autumn, Korea)

  • 심무준;양윤모;오다연;황윤호;이수형
    • 생태와환경
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    • 제48권3호
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    • pp.168-175
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    • 2015
  • 추계 대청호 퇴적물에서 가장 많이 존재하는 인의 형태는 환원환경이 되면 용출될 수 있는 Al-bound와 Fe-bound 인으로 나타났다. 총인, Al-bound와 Fe-bound 인은 가두리 양식장이 분포하였던 회남 지점과 대청댐 앞에서 높게 나타났다. 그 이유는 가두리 양식장 같은 인위적인 활동보다는 세립질 퇴적물의 이동과 연관이 있는 것으로 판단된다. 대청호 퇴적인의 농도는 그 어느 존재형태도 타 인공호수에 비해 높지 않았다. 그러나 보다 더 객관적인 비교를 위해서 존재형태별 연속추출법을 표준화해야 할 것이다.

시화호 퇴적물에서 인의 지화학적 특성 (The geochemical properties of phosphorus from sediments of Lake Shihwa)

  • 심무준;조성록;나공태;신진선;김은수
    • 한국해양환경ㆍ에너지학회지
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    • 제4권3호
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    • pp.16-27
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    • 2001
  • 시화호 퇴적물에서 인의 지화학적 특성을 연구하였다 퇴적인의 가장 큰 형태는 detrital apatite P와 Al-bound P이며 무산소환경이기 때문에 Fe-bound f는 그 비중이 낮았다. 퇴적총인과 유기물의 상관성으로 볼 때, 퇴적물로 제거되는 인의 거동은 유기물에 의해 조절되는 것으로 나타났다. 또한, 유기물 유입의 영향을 직접적으로 받는 정점 Cl에서 정점 C2에 비해 퇴적인의 함량, 유기물과의 상관성, 황산염환원에 의한 공극수내 인산염의 함량 및 플럭스가 높게 나타났다. 결국 시화호 퇴적물에서 인의 함량, 형태 및 공간에 따른 차이는 유기물에 의해 조절되는 것으로 밝혀졌다.

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Biosorption of Cr, Cu and Al by Sargassum Biomass

  • Lee, Hak-Sung
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제2권2호
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    • pp.126-131
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    • 1997
  • The biosorption and desorption of Cr, Cu and Al were carried out using brown marine algae Sargassum fluitans biomass, known as the good biosorbent of heavy metals. The content of alginate bound to light metals could be changed by physical and chemical pretreatment. The maximum uptake of Cr, Cu and Al was independent of the alginate content. The maximum uptaker of Al was two times(mole basis) than those of Cu and Cr. The aluminum-alginate complex was found in the sorption solution of raw and protonated biomass. Most of Cu, Al and light metals sorbed in the biomass were eluted at pH 1.1. However, only 5 to 10% of Cr sorbed was eluted at pH 1.1. The stoiceometric ion exchange between Cu and Ca ion was observed on Cu biosorption with Ca-loaded biomass. A part of Cr ion was bound to biomass as Cr(OH)2+ or Cr(OH)2+. Al was also bound to biomass as multi-valence ion and interfered with the desorbed Ca ion. The behavior of raw S. fluitans in ten consecutive sorption-desorption cycles has been investigated in a packed bed flow-through-column during a continuous removal of copper from a 35 mg/L aqueous solution at pH 5. The eluant used was a 1%(w/v) CaCl2/HC solution at pH 3.

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서해 근소만 조간대 퇴적물에서 여름과 겨울에 인의 존재형태 (Phosphorus Speciation and Bioavailability in Intertidal Sediments of Keunso Bay, Yellow Sea During Summer and Winter)

  • 김동선;김경희
    • Ocean and Polar Research
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    • 제32권3호
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    • pp.177-186
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    • 2010
  • A sequential extraction technique was used to study sediment phosphorus speciation and its relative importance in the intertidal flat of Keunso Bay during summer and winter for a better understanding of the phosphorus cycle and bioavailability in intertidal sediments. Loosely sorbed P contents were the lowest among the five P-pools and showed little seasonal or spatial variation. Although Fe-bound P contents were almost constant in winter, they decreased rapidly with sediment depth in summer. The dissolution of Fe oxides, used as an oxidant for the anaerobic respiration, ascribed the rapid decrease of Fe-bound P in summer. Al-bound P contents displayed little seasonal variation, but showed a large spatial variation, with higher values in the upper intertidal flat. Comprising about 50% of total P, Ca-bound P contents were the highest among the five P-pools. Ca-bound P contents were higher in winter than summer, but did not exhibit a clear spatial variation. Organic P contents were higher in summer than winter, which was associated with higher primary production and clam biomass in summer. Organic P contents were higher in the lower intertidal flat than the upper intertidal flat. In Keunso Bay, bioavailable P contents of the intertidal flat comprising about one third of total P ranged from 2.41 to 5.09 ${\mu}molg^{-1}$ in summer and 3.82 to 5.29 ${\mu}molg^{-1}$ in winter. The bioavailability of P contents was higher in the lower intertidal flat than the upper intertidal flat, which was attributed to the large clam production in the lower intertidal flat.

Error Control Strategy in Error Correction Methods

  • KIM, PHILSU;BU, SUNYOUNG
    • Kyungpook Mathematical Journal
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    • 제55권2호
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    • pp.301-311
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    • 2015
  • In this paper, we present the error control techniques for the error correction methods (ECM) which is recently developed by P. Kim et al. [8, 9]. We formulate the local truncation error at each time and calculate the approximated solution using the solution and the formulated truncation error at previous time for achieving uniform error bound which enables a long time simulation. Numerical results show that the error controlled ECM provides a clue to have uniform error bound for well conditioned problems [1].

Mechanical properties of Al/Al2O3 and Al/B4C composites

  • Pandey, Vinod K.;Patel, Badri P.;Guruprasad, Siddalingappa
    • Advances in materials Research
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    • 제5권4호
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    • pp.263-277
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    • 2016
  • Mechanical properties of $Al/Al_2O_3$ and $Al/B_4C$ composites prepared through powder metallurgy are estimated up to 50% $Al_2O_3$ and 35% $B_4C$ weight fractions using micromechanics models and experiments. The experimental Young's modulus up to 0.40 weight fraction of ceramic is found to lie closely between Ravichandran's/Hashin-Shtrikman lower/upper bounds, and close to self consistent method/Miller and Lannutti method/modified rule of mixture/fuzzy logic method single value predictions. Measured Poisson's ratio lies between rule of mixture/Ravichandran lower and upper bound/modified Ravichandran upper bounds. Experimental Charpy energy lies between Hopkin-chamis method/equivalent charpy energy/Ravichandran lower limit up to 20%, and close to the reciprocal rule of mixture for higher $Al_2O_3$ content. Rockwell hardness (RB) and Micro-hardness of $Al/Al_2O_3$ are closer to modified rule of mixture predictions.

The Nature of Water in Tactic Poly (2-Hydroxyethyl Methacrylate) Hydrogels

  • Kim, Eui-Hwan;Jeon, Sang-Il;Yoon, Sung-Chul;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • 제2권2호
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    • pp.60-66
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    • 1981
  • The hypothesis that three classes of water exist in hydrogels, namely X water (free water-like), Z-water (bound water-like), and Y water (interfacial water-like), has been verified and generally accepted. To further check the validity of this hypothesis and to study the nature of X, Y, and Z water as conformation changes, several experiments have been done using Tactic Poly(2-hydroxyethyl methacrylate) (P-HEMA) gels. Thermal expansively data for tactic P-HEMA gel was obtained. In each case of isotactic and syndiotactic P-HEMA, the higher water content gels showed an extremely sharp volume change at $0^{\circ}C$, indicating the presence of normal free water-like. Lower water content gels showed no anomalous change in thermal expansion, indicating that the water is bound water-like. The medium water content gels exhibited intermediate behavior. These results were also confirmed by bulk gel conductivity measurments. The differential scanning calorimeter(DSC) experiment was simply introduced to further verify the bound water-like quantities which was obtained by the method of dilatometry and specific conductivity. Observing the amounts of X, Y, and Z water with the change of tacticity, the similar content of bound water-like may be due to the same primary structure of isotactic and syndiotactic polymer and the difference in free and interfacial water-like content may be due to the difference in secondary and tertiary structure of tactic polymer. Therefore, as the polymer conformation varies, the free and interfacial water-like content will be varied. In order to demonstrate these concepts, Russel et al.'s CPK space-filling molecular models of isotactic and syndiotactic P-HEMA was utilized.

EFFICIENT ESTIMATION IN SEMIPARAMETRIC RANDOM EFFECT PANEL DATA MODELS WITH AR(p) ERRORS

  • Lee, Young-Kyung
    • Journal of the Korean Statistical Society
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    • 제36권4호
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    • pp.523-542
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    • 2007
  • In this paper we consider semiparametric random effect panel models that contain AR(p) disturbances. We derive the efficient score function and the information bound for estimating the slope parameters. We make minimal assumptions on the distribution of the random errors, effects, and the regressors, and provide semiparametric efficient estimates of the slope parameters. The present paper extends the previous work of Park et al.(2003) where AR(1) errors were considered.

밭 토양에서 패화석비료 시용에 따른 유효인산의 증대 (Increased Available Phosphate by Shell Meal Fertilizer Application in Upland Soil)

  • 이창훈;이주영;하병연;김필주
    • 한국토양비료학회지
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    • 제38권1호
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    • pp.52-57
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    • 2005
  • 굴껍질을 주원료로 하는 패화석비료가 토양개량제로서 배추의 생육 및 수량을 증진시키고 토양의 이화학적 특성 개선에 효과가 있는 것으로 알려져 있다. 평택통 (Fine silty, Typic Endoaquepts)의 밭 토양에 굴패화석비료를 0, 4, 8, 12, and $16Mg\;ha^{-1}$ 처리하여 봄배추를 재배하는 과정 중 패화석비료 시용량이 증가함에 따라 토양내 유효인산함량은 일정하게 증가되는 것이 확인되었다. 유효인산 함량의 증가는 1차적으로 패화석비료내 포함된 인산 ($1.5g\;P_2O_5\;kg^{-1}$)의 직접투입이 토양 내 전 인산을 증가시키고 유효인산을 증진시킨 것으로 평가되었다. 그리고 알카리성 제재인 패화석비료가 pH 5.8의 공시토양의 pH를 중성범위로 높이면서 간접적으로 유효인산함량을 증진시킨 것으로 해석되었다. 패화석비료의 시용량이 증가함에 따라 토양내 수용성 인산과 Ca-P 함량을 다소 증가시켰으나, Al-P와 Fe-P의 비율을 크게 감소되었다. 결과적으로 패화석비료는 토양내 유효인산함량 증진에 효과가 있으며, 이렇게 많아진 유효인산을 이용하여 인산시비량을 저감하고 나아가 인산유출을 저감할 수 있는 방법이 될 수 있을 것으로 판단된다.