• Title/Summary/Keyword: Al-bound P

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Geochemical Properties of Sedimentary Phosphorus of Daechung Lake in Autumn, Korea (추계 대청호 퇴적물 내 인의 지화학적 특성)

  • Shim, Moo Joon;Yang, Yun Mo;Oh, Da Yeon;Hwang, Yun Ho;Lee, Soo Hyung
    • Korean Journal of Ecology and Environment
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    • v.48 no.3
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    • pp.168-175
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    • 2015
  • This study was conducted in autumn to determine phosphorus (P) fraction in sediments of Daechung Lake, to elucidate controlling factors for sedimentary P, and to compare with the other areas. For this study, sediment samples were collected at 6 sites only once on November 2014 using ponar grab and analyzed for solid-phase P (Loosely adsorbed, Fe-bound, Al-bound, detrital apatite, and refractory organic P) by sequential extraction. Total phosphorus (TP) was relatively high in front of Daechung Dam and Hoinam where fish farm was run until 1997. The dominant sedimentary P form was Al-bound P, followed by Fe-bound P, which could be released from sediment to water column during suboxic state. Based on principal component analysis, Al-bound P, Fe-bound, and TP were controlled by grain size of sediments. Loosely adsorbed, detrital apatite, and refractory organic P were relatively highly accumulated at the mouth of major tributaries where suspended sediments were delivered. Sedimentary P concentrations in Daechung Lake sediments were not higher than in other lake sediments. Therefore, based on these results, major controlling factors were grain size and input of suspended sediments from tributaries.

The geochemical properties of phosphorus from sediments of Lake Shihwa (시화호 퇴적물에서 인의 지화학적 특성)

  • Shim Moo-Joon;Cho Sung-Rok;Na Kong-Tae;Shin Jin-Sun;Kim Eun-Soo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.4 no.3
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    • pp.16-27
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    • 2001
  • We have studied the phosphorus geochemistry in sediments from anoxic environments of Lake Shihwa. The dominant sedimentary phosphorus forms were detrital apatite P and Al-bound p, whereas the amount of Fe-bound P was low because of anoxic condition. Based on the correlation between TP(Total Phosphorus) and OC(Organic Carbon), the behavior of sedimentary phosphorus was influenced by organic matters. It shows that dissolved and solid phosphorus concentrations, the flux of phosphate and the correlation coefficients between sedimentary phosphorus and organic matter In St. Cl were higher than those in St. C2. The results indicate that the concentrations and distributions of phosphorus In sediments were controlled by organic matters.

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Biosorption of Cr, Cu and Al by Sargassum Biomass

  • Lee, Hak-Sung
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.126-131
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    • 1997
  • The biosorption and desorption of Cr, Cu and Al were carried out using brown marine algae Sargassum fluitans biomass, known as the good biosorbent of heavy metals. The content of alginate bound to light metals could be changed by physical and chemical pretreatment. The maximum uptake of Cr, Cu and Al was independent of the alginate content. The maximum uptaker of Al was two times(mole basis) than those of Cu and Cr. The aluminum-alginate complex was found in the sorption solution of raw and protonated biomass. Most of Cu, Al and light metals sorbed in the biomass were eluted at pH 1.1. However, only 5 to 10% of Cr sorbed was eluted at pH 1.1. The stoiceometric ion exchange between Cu and Ca ion was observed on Cu biosorption with Ca-loaded biomass. A part of Cr ion was bound to biomass as Cr(OH)2+ or Cr(OH)2+. Al was also bound to biomass as multi-valence ion and interfered with the desorbed Ca ion. The behavior of raw S. fluitans in ten consecutive sorption-desorption cycles has been investigated in a packed bed flow-through-column during a continuous removal of copper from a 35 mg/L aqueous solution at pH 5. The eluant used was a 1%(w/v) CaCl2/HC solution at pH 3.

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Phosphorus Speciation and Bioavailability in Intertidal Sediments of Keunso Bay, Yellow Sea During Summer and Winter (서해 근소만 조간대 퇴적물에서 여름과 겨울에 인의 존재형태)

  • Kim, Dong-Seon;Kim, Kyung-Hee
    • Ocean and Polar Research
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    • v.32 no.3
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    • pp.177-186
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    • 2010
  • A sequential extraction technique was used to study sediment phosphorus speciation and its relative importance in the intertidal flat of Keunso Bay during summer and winter for a better understanding of the phosphorus cycle and bioavailability in intertidal sediments. Loosely sorbed P contents were the lowest among the five P-pools and showed little seasonal or spatial variation. Although Fe-bound P contents were almost constant in winter, they decreased rapidly with sediment depth in summer. The dissolution of Fe oxides, used as an oxidant for the anaerobic respiration, ascribed the rapid decrease of Fe-bound P in summer. Al-bound P contents displayed little seasonal variation, but showed a large spatial variation, with higher values in the upper intertidal flat. Comprising about 50% of total P, Ca-bound P contents were the highest among the five P-pools. Ca-bound P contents were higher in winter than summer, but did not exhibit a clear spatial variation. Organic P contents were higher in summer than winter, which was associated with higher primary production and clam biomass in summer. Organic P contents were higher in the lower intertidal flat than the upper intertidal flat. In Keunso Bay, bioavailable P contents of the intertidal flat comprising about one third of total P ranged from 2.41 to 5.09 ${\mu}molg^{-1}$ in summer and 3.82 to 5.29 ${\mu}molg^{-1}$ in winter. The bioavailability of P contents was higher in the lower intertidal flat than the upper intertidal flat, which was attributed to the large clam production in the lower intertidal flat.

Error Control Strategy in Error Correction Methods

  • KIM, PHILSU;BU, SUNYOUNG
    • Kyungpook Mathematical Journal
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    • v.55 no.2
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    • pp.301-311
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    • 2015
  • In this paper, we present the error control techniques for the error correction methods (ECM) which is recently developed by P. Kim et al. [8, 9]. We formulate the local truncation error at each time and calculate the approximated solution using the solution and the formulated truncation error at previous time for achieving uniform error bound which enables a long time simulation. Numerical results show that the error controlled ECM provides a clue to have uniform error bound for well conditioned problems [1].

Mechanical properties of Al/Al2O3 and Al/B4C composites

  • Pandey, Vinod K.;Patel, Badri P.;Guruprasad, Siddalingappa
    • Advances in materials Research
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    • v.5 no.4
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    • pp.263-277
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    • 2016
  • Mechanical properties of $Al/Al_2O_3$ and $Al/B_4C$ composites prepared through powder metallurgy are estimated up to 50% $Al_2O_3$ and 35% $B_4C$ weight fractions using micromechanics models and experiments. The experimental Young's modulus up to 0.40 weight fraction of ceramic is found to lie closely between Ravichandran's/Hashin-Shtrikman lower/upper bounds, and close to self consistent method/Miller and Lannutti method/modified rule of mixture/fuzzy logic method single value predictions. Measured Poisson's ratio lies between rule of mixture/Ravichandran lower and upper bound/modified Ravichandran upper bounds. Experimental Charpy energy lies between Hopkin-chamis method/equivalent charpy energy/Ravichandran lower limit up to 20%, and close to the reciprocal rule of mixture for higher $Al_2O_3$ content. Rockwell hardness (RB) and Micro-hardness of $Al/Al_2O_3$ are closer to modified rule of mixture predictions.

The Nature of Water in Tactic Poly (2-Hydroxyethyl Methacrylate) Hydrogels

  • Kim, Eui-Hwan;Jeon, Sang-Il;Yoon, Sung-Chul;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.2 no.2
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    • pp.60-66
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    • 1981
  • The hypothesis that three classes of water exist in hydrogels, namely X water (free water-like), Z-water (bound water-like), and Y water (interfacial water-like), has been verified and generally accepted. To further check the validity of this hypothesis and to study the nature of X, Y, and Z water as conformation changes, several experiments have been done using Tactic Poly(2-hydroxyethyl methacrylate) (P-HEMA) gels. Thermal expansively data for tactic P-HEMA gel was obtained. In each case of isotactic and syndiotactic P-HEMA, the higher water content gels showed an extremely sharp volume change at $0^{\circ}C$, indicating the presence of normal free water-like. Lower water content gels showed no anomalous change in thermal expansion, indicating that the water is bound water-like. The medium water content gels exhibited intermediate behavior. These results were also confirmed by bulk gel conductivity measurments. The differential scanning calorimeter(DSC) experiment was simply introduced to further verify the bound water-like quantities which was obtained by the method of dilatometry and specific conductivity. Observing the amounts of X, Y, and Z water with the change of tacticity, the similar content of bound water-like may be due to the same primary structure of isotactic and syndiotactic polymer and the difference in free and interfacial water-like content may be due to the difference in secondary and tertiary structure of tactic polymer. Therefore, as the polymer conformation varies, the free and interfacial water-like content will be varied. In order to demonstrate these concepts, Russel et al.'s CPK space-filling molecular models of isotactic and syndiotactic P-HEMA was utilized.

EFFICIENT ESTIMATION IN SEMIPARAMETRIC RANDOM EFFECT PANEL DATA MODELS WITH AR(p) ERRORS

  • Lee, Young-Kyung
    • Journal of the Korean Statistical Society
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    • v.36 no.4
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    • pp.523-542
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    • 2007
  • In this paper we consider semiparametric random effect panel models that contain AR(p) disturbances. We derive the efficient score function and the information bound for estimating the slope parameters. We make minimal assumptions on the distribution of the random errors, effects, and the regressors, and provide semiparametric efficient estimates of the slope parameters. The present paper extends the previous work of Park et al.(2003) where AR(1) errors were considered.

Increased Available Phosphate by Shell Meal Fertilizer Application in Upland Soil (밭 토양에서 패화석비료 시용에 따른 유효인산의 증대)

  • Lee, Chang-Hoon;Lee, Ju-Young;Ha, Byung-Hyun;Kim, Pil-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.1
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    • pp.52-57
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    • 2005
  • Previous studies showed that shell meal fertilizer from the oyster farming industry could be a potential inorganic soil amendment to increase Chinese cabbage productivity and to restore the soil nutrient balance in upland soil (Lee et al., 2004). Herein, shell meal fertilizer was applied at rates of 0, 4, 8, 12, and $16Mg\;ha^{-1}$ to upland soil (Pyeontaeg series, Fine silty, Typic Endoaquepts) for Chinese cabbage cultivation. We found available phosphate increased significantly with shell meal fertilizer application, due to high content of phosphate ($1.5g\;P_2O_5\;kg^{-1}$) in the applied shell meal fertilizer. In addition, high pH of shell meal fertilizer contributed to increase available phosphate content by neutralization of acidic soil. Total and residual P contents increased significantly with increasing shell meal fertilizer application, but we could not find any tendency in organic and inorganic P fraction. Of extractable P fraction, water-soluble phosphorus (W-P) and calcium-bound P (Ca-P) contents increased significantly with increasing application level. By contrast, aluminum and iron-bound P (Al-P and Fe-P) decreased slightly with shell meal application. The present experiment indicated that shell meal fertilizer had a positive benefit on increasing available phosphate content in arable soil. And so the increased available phosphate by shell meal fertilizer may decrease phosphate application level and then reduce phosphorus loss in arable soil.