• Title/Summary/Keyword: Al concentration

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Studies on the Flocculation of Algae with Metal Ions (금속이온에 의한 조류 응결에 관한 연구)

  • Park, Yeong Jae;Lee, Sang Soo;Cho, Hye Ryun
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.8
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    • pp.441-449
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    • 2015
  • Studies on the flocculation of algae using various metal ions were carried out by measurements of optical density(OD) and zeta potential. Cyanobacteria were used as algaes. Flocculation efficiencies of cyanobacteria by an addition of metal ions were determined from OD values, and the effect of metal ions was greater in the order of $Al^{3+}$>$La^{3+}$>$Ho^{3+}$>$Fe^{2+}$>$Ca^{2+}$. Especially for trivalent metal ions, percentages of metal removed from cyanobacteria solutions on flocculation were measured, showing the same order as in flocculation efficiencies. Zeta potentials of cyanobacteria alone were measured with increasing the concentration, found to be all negative voltages, and were increased with increasing the concentration. The effect of pH on zeta potential of cyanobacteria solution was investigated. Below pH 5.5, the zeta potentials were steeply decreased with increasing pH, whereas in the range of $5.5{\leq}pH{\leq}10$ they were almost constant ($-46{\pm}1mV$) even with increasing pH. At a constant concentration of cyanobacteria ($A_{730}=0.25$), an increase in concentration of metal ions caused an increase in zeta potential of cyanobacteria solution, showing that the effect was greater in the order of $Al^{3+}$>$Ho^{3+}$>$La^{3+}{\gg}Mg^{2+}{\geq}Ca^{2+}{\gg}K^+$. At a constant metal concentration, zeta potentials were measured with increasing cyanobacteria concentration, showing that zeta potentials for $K^+$, $Mg^{2+}$ and $Ca^{2+}$ ions were negligibly changed, whereas those of $Ho^{3+}$ and $La^{3+}$ ions were decreased. Moreover, the effect of $Ho^{3+}$ ion on decreasing zeta potential was smaller than that of $La^{3+}$ ion. $Al^{3+}$ ions showed quite a different behavior that with increasing cyanobacteria concentration the zeta potentials increased and decreased thereafter. Hydrolysis of $Al^{3+}$ ions caused a difficulty to investigate coagulation or flocculation of cyanobacteria by measurement of zeta potential.

A Study of Color Difference on Fabrics Dyed with Yellow Natural Material - by Natural Gardenia and Japanese Pagoda Tree - (황색계 천연염색물의 색차에 관한 연구 - 치자와 괴화를 중심으로 -)

  • 최인려
    • The Research Journal of the Costume Culture
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    • v.10 no.4
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    • pp.433-440
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    • 2002
  • Natural gardenia and Japanese pagoda tree have been known as them of the most widely used yellow vegetable dyes. Cotton and silk fabrics(KS K 0905) were chosen as specimens. Those were dyed with natural gardenia and Japanese pagoda tree. The conditions of dyeing were varied according to the kinds of mordants, using mordants or not and the concentrations of the natural dyes. Sn, Al, Fe and Cu were chosen for the mordants. 5%(owf), 10%(owf), 15%(owf) and 20%(owf) were used as for the concentration of the natural dyes. The color differences were measured by the Spectrometer(UV-VIS-NIR) before and after dyeing. The results are as follows: 1. Deeper colors were proportionately shown up to the concentration of the natural dye. 2. Silk was shown the higher dye affinity than the cotton at the same concentration of the dye. 3. The color difference between the Sn-mordanted specimens and the Al-mordanted specimens were significant. When the concentration of the dye increased, the colors got darker, specially in b* value. 4. The color difference between the Fe-mordanted specimens and the Cu-mordanted specimens were significant in L* value and b* value. 5. The deeper or lighter yellow were controllable under the concentration of the natural dye and the mordants. 6. The most effective and the economic concentration of the natural dye was 10% owf through the experiments.

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Source Characteristics of Particulate Trace Metals in Daegu Area (대구지역 부유분진 중 미량금속성분의 발생원 특성연구)

  • 최성우;송형도
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.469-476
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    • 2000
  • This study was performed to understand the behavior and source characteristics of particulate trace metals in Daegu area. To do this, total of 84 samples had been collected from January to December 1999. TSP (total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less 10${\mu}{\textrm}{m}$) were collected by filters on portable air sampler, and in TSP and PM-10 were analyzed by ICP(Inductively Coupled Plasma Spectrometer) after preliminary treatment. The results were follow as: first, annul means of TSP and PM-10 concentration were 123 and 69$\mu\textrm{g}$/㎤ respectively. The concentration of TSP adn PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these metals are generally associate with natural contributions. Third, a hierarchical clustering technique was used to group 9 metals. The results from the cluster analysis of TSP and PM-10 shows a similar clustering pattern : Fe, Al in a group and the rest of the metals such as Ni, Cr, As, Mn, Cd, Pb, Zn in the other group. One group of metal such as Fe, Al is associated with natural sources such as soil and dust. The other is closely related to urban anthropogenic sources such as fuel combustion, incineration, and refuse burning, Finally, using Al as a reference element, enrichment factors were used for identifying the major particulate contributors. The enrichment factors of Al. Fe<10 (standard value of enrichment factor) were considered to have a significant dust and soil source and termed nonenriched. Ni, Cr, As, Mn, Cd, Pb, Zn》10 is enriched and has a significant which is contributed by athropogenic sources.

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A Study on Microstructure Formation during Directional Solidification of a Hypoeutectic Al-11.3Si-3.5Cu alloy (아공정 Al-11.3Si-3.5Cu 합금의 응고조직 형성거동에 관한 연구)

  • Seo, Heesik;Gu, Jiho;Park, Kyungmi;Lee, Jeongseok;Lee, Jehyun;Chung, Wonsub
    • Korean Journal of Metals and Materials
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    • v.50 no.12
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    • pp.897-905
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    • 2012
  • Directional solidification experiments were carried out in a hypoeutectic Al-11.3Si-3.5Cu system to investigate the microstructural evolution with the solidification rate. At a fixed temperature gradient, a dendritic microstructure was observed at a constant speed of more than $25{\mu}ms^{-1}$, a cellular interface developed at $5{\mu}ms^{-1}$ and the growth rate of $0.5{\mu}ms^{-1}$ led to the stability of the planar interface. The results revealed that primary silicon phases formed among cells, even though the studied Al-Si alloy system formed the composition within a hypoeutectic silicon composition. This suggests that the liquid concentration among cells during solidification reached a higher concentration, i.e., the eutectic concentration. It is, however, interesting that primary silicon phases did not form during a dendritic growth of more than $25{\mu}ms^{-1}$. These experimental observations are explained using the theoretical models on the interface temperatures.

Anodizing of Aluminium (Part1) (The effect on film by electrolytical conditions) (Al의 양극처리에 관한 연구 (제1보) (전해조건이 피막에 미치는 영향))

  • 이종남;이성주;김회정
    • Journal of the Korean institute of surface engineering
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    • v.1 no.1
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    • pp.14.1-18
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    • 1967
  • The characteristics of sulfuric acid anodized layer was studied under various Conbitions, acid concentration : 5-20%, temperature : 5-25$^{\circ}C$, bath voltate : 16 volts , bath agitain : mech agitation : mechanical . The Al+++ ion increase in anodizing baty, the film thickness under microscope, the comparative porosity and the thickness were determined. It was found that film thickness and the porosithy which are the main factors of determining andoized layet quality, rule the corrosing and abrasiion tesistance of the film, and that the porosity is increasing in the outerlayer. The formation mechanism was assumed as follows : The film thickness -increase is due to OH_ ion diffusion into compact non-conductive layer and Al+ + OH_ \longrightarrowAl(OH), Al(OH)+ + OH_ \longrightarrowAl(OH)+$_2$ , Al(OH)+$_2$ + OH_ \longrightarrowAl(OH)$_3$., the strong adhesion force is alse due to Al(OH) or Al(OH)$_2$ in transtion layer. And the pore-nucleation is produced by volume change between Al and Al$_2$O$_3$ and activated H$_2$O gas created by large reaction heat of Al+(x) +OH_ \longrightarrowAl(OH)x.

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An Evaluation on the Weldability of Al-Li Alloys by Varestraint Testing Method (Varestraint Test법에 의한 Al-Li합금의 용접성 평가)

  • 김형태;이창배;신현식;서창제
    • Journal of Welding and Joining
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    • v.14 no.6
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    • pp.48-57
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    • 1996
  • The weldability of high purity aluminum-lithium binary alloys has been investigated using the Varestraint test. Autogenous GTAW (gas-tungsten-arc-welds) were run along specimens of different lithium concentration using three sets of welding parameters. Welding voltage was held constant at 10 volts. Welding current (70∼100 amps) and travel speed (23∼33 cm/min) were the parameter varied. Hot-tearing susceptibility varied with lithium content and exhibited a steep peak at 2.6 weight percent lithium. Depth of penetration increased with increasing heat input and lithium concentration. The susceptibility is influenced by the wettability of dendrites by the interdendritic eutectic liquid as well as the time available for back-Siting by eutectic liquid. The welding condition of welding current 70A and travel speed 23 cm/min was showed good resistance to cracking in aluminum-lithium alloys. Suggestions for improving weld cracking resistance are also provided.

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The Effect of Manganese and Aluminium on the Germination of the Seeds of Pinus banksiana and Alnus tinctoria (방크스소나무 및 산오리나무의 발아와 묘목의 생장에 미치는 Mn과 Al의 영향)

  • 강상준
    • Journal of Plant Biology
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    • v.10 no.3_4
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    • pp.4-9
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    • 1967
  • The aim of present study is to elucidate the effects of manganese and aluminium ions on the germination and seedling growth of Pinus banksiana and Alnus tinctoria and to estimate the limiting level of those ions in the cultivated soils. The rate of germination of Pinus banksiana was increased under the relatively low concentration of Mn and Al (100 p.p.m), however, the germinating activity was not affected. High concentration over 110 p.p.m. of Mn and Al was related to the reduced percentage of germination and seedling growth of Pinus banksiana and Alnus tinctoria. Soils sampled from various parts of Korea contained Mn as much as high level that would be harmful for the seedling growth of Pinus banksiana and Alnus tinctoria.

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Quantitative analysis of impurity concentration in purification of Al by segregation method (편석법에 의한 Al정련시 불순물농도의 정량적계산에 관한 연구)

  • Kim, Kyoung-Min;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.15 no.5
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    • pp.507-513
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    • 1995
  • The effect of forced convention on the solute redistribution of the Al ingot was studied quantitatively in an effort to fabricate high purity aluminum using a segregation method. Based on the experimental results, the solute concentration in the solid phase tended to decrease at the early state of solidification, and then increased gradually as solidification proceeded. Fe and Si concentrations decreased as growth rate decreased and as revolution speed increased. The solute redistribution obtained from the BPS model incorporated with the tangential flow component as well as the axial flow component within the melt, agreed well with the measurements.

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Formation of Alumian gradient coatings by Ion Beam Assistant Deposition

  • Xue-Jianming
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.118-122
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    • 1998
  • $Al_2O_x$(0$Al_2O_3$ gradient coatings were formed by evaporating pure aluminium(99.9%) in $O_2$ environment with an IBAD facility, 12keV $Ar^+$ was used to irradiate the coatings simultaneously during the deposition. Sample's composition and depth profile were analysed by RBS and AES measurement, and their microhardness and porosity property were also measured in the experiment. Results show that, the oxygen concentration in the deposited coatings has a nearly linear relationship with the inputting gas flow before $O_2$ partial pressure in the target chamber reaches $1.2\times10^{-3}$ mbar under which stoichiometric $Al_2O_3$ could be formed; and sample's microhardness and porosity property is affected significantly by the oxygen concentration in the coatings.

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Optimization of charge and multiplication layers of 20-Gbps InGaAs/InAlAs avalanche photodiode

  • Sim, Jae-Sik;Kim, Kisoo;Song, Minje;Kim, Sungil;Song, Minhyup
    • ETRI Journal
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    • v.43 no.5
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    • pp.916-922
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    • 2021
  • We calculated the correlation between the doping concentration of the charge layer and the multiplication layer for separate absorption, grading, charge, and multiplication InGaAs/InAlAs avalanche photodiodes (APDs). For this purpose, a predictable program was developed according to the concentration and thickness of the charge layer and the multiplication layer. We also optimized the design, fabrication, and characteristics of an APD for 20 Gbps application. The punch-through voltage and breakdown voltage of the fabricated device were 10 V and 33 V, respectively, and it was confirmed that these almost matched the designed values. The 3-dB bandwidth of the APD was 10.4 GHz, and the bit rate was approximately 20.8 Gbps.