• Title/Summary/Keyword: Air-oxidation

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Preparation of Ultrafine Mn-Zn Ferrite by Direct-Wet Synthesis and a Study of Magnetic Properties (습식직접 합성에 의한 초미분 Mn-Zn Ferrite의 합성과 자성특성에 관한 연구)

  • 이경희;이병하;허원도;황우연
    • Journal of the Korean Ceramic Society
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    • v.28 no.10
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    • pp.757-766
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    • 1991
  • These powder properties were investigated and prepared of ultrafine Mn-Zn ferrite powder by Direct-wet process from variation of oxidation condition. H2O2 oxidation the products were ultrafine spherical particles of about 400${\AA}$ in diameter and superparamagnetics. H2O2 and Air oxidation, Coexistance ultrafine spherical particles of about 400${\AA}$ and cubic particles of about 1000${\AA}$. The products were constructed of superparamagnetic and ferromagnetic particles, and Magnetization were about 30 emu/g. Air Oxidation, Above 6 hr Air 120 ι/hr and 4 hr of Air 180 ι/hr were uniform cubic particles of above 1000${\AA}$. The products were ferromagnetic particles and Magnetization of above 45 emu/g.

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Soot Formation and Oxidation in Air-Diluted Propane Diffusion Flames under Elevated Pressures (압력조건에서 공기로 희석된 프로판 확산화염의 매연 생성과 산화 특성)

  • Bae, Seungman;Nam, Younwoo;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.267-268
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    • 2012
  • Soot formation and oxidation characteristics of air-diluted propane diffusion flames have been experimentally investigated under the elevated pressure conditions. PAH concentrations showed more pressure sensitive behavior comparing to soot volume fractions. The flame/soot temperatures in soot oxidation region were obtained using the MOLLIP technique. Under the complete soot oxidation environment, the flame/soot temperature is increased with pressure. The increased temperature could accelerate the soot oxidation process and then exothermic oxidation reaction, in turn, could further raise the flame/soot temperature, which would result in the enhancement of soot oxidation process.

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Oxidation of STS304 Stainless Steel between 1050 and 1200℃ for 1 Hour in Air (STS 304 스테인리스강의 대기중 1050~1200℃, 1시간 동안의 산화)

  • Nguyen, Thuan Dinh;Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.47 no.4
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    • pp.235-241
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    • 2009
  • The STS304 stainless steel was oxidized isothermally and cyclically at temperatures between 1050 and $1200^{\circ}C$ for 1 hr in air. During isothermal oxidation, it displayed good oxidation resistance at $1050^{\circ}C$. However, it suffered from breakaway oxidation above $1100^{\circ}C$, being accompanied with internal oxidation. During cyclic oxidation, it also displayed good oxidation resistance at $1050^{\circ}C$, but it suffered from massive weight loss above $1125^{\circ}C$. The oxide scales formed consisted primarily of $Fe_2O_3$, $Fe_3O_4$ with and without $Cr_2O_3$. They were generally non-adherent.

Structural Changes during Oxidation Process of Anisotopic Mesophase Carbon Fibers(II)-Surface Texture Observation by Scanning Electron Microscopy (산화반응에 의한 이방성 메조페이스 탄소섬유의 구조 변화(II)-주사전자현미경을 이용한 표면구조 관찰)

  • Roh, J.S.
    • Korean Journal of Materials Research
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    • v.13 no.12
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    • pp.831-838
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    • 2003
  • Anisotropic mesophase carbon fiber(AMCFs) was exposed to isothermal oxidation in air and $CO_2$atmosphere, and burn-off rates have measured by TGA. The microstructure changes of oxidized carbon fibers, were observed by SEM. It was observed that oxidation rate in the air is over 100 times faster than that in $CO_2$atmosphere. The activation energy obtained in air was about 43.4 Kcal/mole in the temperature range of $600∼800^{\circ}C$, and in $CO_2$was about 55.2 Kcal/mole in the temperature range of $950∼1200^{\circ}C$. Therefore, the oxidation reaction in both atmospheres was under chemical reaction regime in the above temperature ranges. It was shown that the oxidation of the AMCFs is initiated at the end of fibers at high temperature($1100^{\circ}C$) with developing the large pores, and the small pores are developed on the fiber surface at low temperature($900^{\circ}C$). In conclusion, the oxidation of the AMCFs is progressed through the imperfection.

High Temperature Oxidation Behavior of Cr-Mo Low Alloy Steel According to Atmospheric Pressures in Humid Air (Humid air 분위기로부터 대기 압력에 따른 Cr-Mo 저합금강의 고온 산화 거동)

  • Kwon, Gi-hoon;Park, Hyunjun;Lee, Young-Kook;Moon, Kyoungil
    • Journal of the Korean Society for Heat Treatment
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    • v.35 no.5
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    • pp.246-254
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    • 2022
  • The high-temperature oxidation behavior of Cr-Mo steel AISI 4115 in air at different temperatures (600, 850, 950℃) for 120 min was studied by mass gain analysis, phase analysis (optical microscopy, electron probe micro-analysis, x-ray diffraction) and hardness measurement of each iron oxide-phase. The oxidation scales that formed on oxidation process consisted outer layer (Hematite), middle layer (Magnetite) and the inner layer (Chromite). In the case of 850 and 950℃, the oxidation mass gain per unit area of AISI 4115 steel increased according to the logarithmic rate as atmospheric pressure increased. Especially, It has been observed that with an increase in the atmospheric pressure at 600℃, the oxidation mass gain per unit area changed from a linear to logarithmic relationship.

Effect of Oxidation on Hot Ductility Behavior of Plain Carbon Steel (탄소강의 열간연성 거동에 미치는 산화의 영향)

  • Park, Tae Eun;Lee, Un Hae;Sohn, Kwang Suk;Lee, Sung Keun;Kim, In Soo;Yim, Chang Hee;Kim, Donggyu
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.394-400
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    • 2010
  • The effects of oxidation behavior on the hot ductility of plain carbon steels were investigated at various temperatures in order to simulate the continuous casting process more precisely, in which the process undergoes in air atmosphere rather than Ar atmosphere. The high temperature oxidation behavior and scale morphology of the carbon steels exposed to the air and Ar atmosphere at various temperatures were also investigated in order to assess the mechanism of the RA value decreasing in an air atmosphere. The RA values obtained from the air atmosphere were marked below 45% by the test temperature, except for over 1000${^{\circ}C}$, with the RA values remaining in low values in both the low and high temperature region, at which the RA values generally recovered in the Ar atmosphere. The surface roughness of the specimen was developed by external and internal oxidation when the specimen was deformed in an air atmosphere at high temperature, with the result being the stress concentrated at the roughness of the specimen surface, resulting in low RA values. The hot ductility in the air atmosphere was found to be likely controlled by the oxidation rate instead of the microstructures corresponding to test temperatures.

Study of Stabilizing 5,6-dihydroxyindole with Coating Process Against Oxidation and Light (코팅프로세스를 사용한 5,6-디하이드록시인돌의 산화 및 광에 대한 안정화 연구)

  • Han, Sang-Keun;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.3
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    • pp.518-527
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    • 2013
  • 5,6-dihydroxyindole was easily oxidation with air and light Conditions. Availability of 5,6-dihydroxyindole was studied for hair dye as a precursor of melanin. This study used wet and dry coating process to stabilize 5,6-dihydroxyindole. In wet process used dimethicone and cyclometicone, the 5,6-dihydroxyindole had darkened through the drying process at $58^{\circ}C$. Wet coating process was inappropriate to stabilize the coating. In dry coating process, shea butter coating was stable until 3 days. Dextrin palmitate was most efficient ingredient to prevent oxidation by sun light and air until 7days. Oxidation test with 1.0% and 1.5% of dextrin palmitate was not different under conditions of sun light and air and was not dependent on contents. Vitamin E acetate under conditions of sun light and air, there were no significant effect in preventing oxidation.

Wear and Oxidation Charateristics of Two Phase Intermetallic Compounds (다상 금속간 화합물의 내마모 및 내산화 특성)

  • Lee, Jong-Hun;Bae, Jong-Uk;Lee, Sang-Yul
    • 연구논문집
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    • s.28
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    • pp.183-192
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    • 1998
  • The wear and oxidation resistance of two phase nickel aluminides was investigated. Wear tests of various heat-treated specimens at room temperature and at $500^{\circ}C$ were performed under no lubricant condition in air by using a ball-on-disk type tribotester. Isothermal oxidation tests were made at $1100^{\circ}C$ in air flowing at the rate of 70cc/min and at $1000^{\circ}C$ in air by using TGA. Experimental results from wear tests showed that nickel aluminide with a higher content of Al had an improved wear resistance at both temperatures. Also the examination of the wear tracks after wear test at both room temperature and $500^{\circ}C$ indicated that regardless of the alloy compositions the wear tracks of the two phase nickel aluminides showed an abrasive type wear The improved oxidation resistance observed in the Ni-34at%Al alloy could to be attributed to the microstructural difference between the aluminides. An accelerated oxidation along the thin layer of $Ni_3AL$ along the grain boundary observed in the microstructure of the Ni-32at%Al aluminide could be attributed to the poor oxidation resistance.

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Effects of the Gas Composition on Internal Oxidation Characteristics of Low Carbon Alloy Steel during Carburizing in Nitrogen-Propane-Air Atmospheres (질소-프로판-공기분위기에서 저탄소 합금강의 침탄시 내부산화 특성에 미치는 가스조성의 영향)

  • Roh, Y.S.;Kim, S.M.;Kim, Y.H.;Kim, H.K.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.4
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    • pp.53-60
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    • 1991
  • This study has been performed to investigate into the internal oxidation characteristics of low carbon steel with respect to the added amount of air in nitrogen-propane atmosphere after gas carburizing for various times at $930^{\circ}C$. The results obtained from the experiment are as follows ; (1) Optical micrographs have shown that the internal oxidation is unlikely to occur in the gas atmosphere without air and that oxidized zone in the outer surface layer is formed in the gas atmosphere with air revealing that the depth of oxidized zone increases with increasing the added amount of air. (2) The formation of internally oxidized zone in the outer surface layer has been found to be inhibited as Ni content increases, i. e, the amount of alloying element increases. (3) The depth of oxidation has been measured to increase with almost parabolically gas carburizing time of up to 6 hours.

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A Study on the Flow Characteristics of an Oxidizer Feed Section for Wet-air Oxidation in Gravity Pressure Reactor (중력식 습식산화반응기 내 산화제 공급부의 유동특성에 관한 연구)

  • Lee, Hongcheol;Hwang, Inju
    • The KSFM Journal of Fluid Machinery
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    • v.19 no.3
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    • pp.10-13
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    • 2016
  • The wet-air oxidation in gravity pressure reactor is effective for organic waste treatment with energy saving under high pressure and high temperature. But its oxidation control is difficulty because its multi-phase flow characteristics is very complicated. The flow characteristics of an oxidizer feed section in the gravity pressure reactor were investigated using numerical method which are verified by comparison with experimental results. In this study, the results showed that the flow rate of oxidizer have an effect on the generation of bubble around feed section.