• Title/Summary/Keyword: Ag electrode

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Simulations of Transmittance for the ITO/Ag/ITO Multiple Transparent Electrode Layers by 3 Dimensional FDTD Method (3차원 FDTD 방법에 의한 ITO/Ag/ITO 다층 투명전극막의 투과도 시뮬레이션)

  • Kim, Ki Rak;Cho, Eou Sik;Kwon, Sang Jik
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.3
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    • pp.88-92
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    • 2020
  • As a highly conductive and transparent electrode, the optical transmittances of ITO/Ag/ITO were simulated and compared with the experimental results. The simulations are based on the finite-difference time-domain (FDTD) method in solving linear Maxwell equations. In our simulations, the computation domain is set in the XZ-plane with 3D dimension, and a plane wave with variable wavelengths ranging from 250 nm to 850 nm is incident in the z-direction at normal incidence to the ITO/Ag/ITO film surrounded by free-air space. As the results through both simulations and experiments, it was shown that the thickness combinations by the ITO layers of about 40 nm and the Ag layer of about 10 nm could be most suitable conditions as a high conductive transparent electrode having the transmittance similar to that of a single ITO layer.

A study on Stripping Voltammetric Determination of Ag(I) by Poly(3-methylthiophene) Conducting Polymer Film Electrode Containing 18-crown-6 (18-crown-6을 포함하는 poly(3-methylthiophene) 전도성 고분자 막전극에 의한 Ag(I)의 벗김 전압-전류법적 정량에 관한 연구)

  • Lee, Ihn Chong;Sohn, Jeong-In;Kim, Kuk Gin
    • Analytical Science and Technology
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    • v.7 no.2
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    • pp.181-186
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    • 1994
  • Using poly(3-methylthiophene) conducting polymer film electrodes, feasiblity for Ag determination by stripping voltammetry has been studied. Ag ions accumulated by complexation with 18-crown-6, which are existing on the surface of the polymer film electrode, migrate inside of polymer film through potential scanning within limited potential range, and then are reduced and oxidized on the glassy carbon substrate. Therefore, the polymer film must have proper thickness and porosity for easy penetration of Ag ions. On the basis of these experimental results, $5.0{\times}10^{-6}M$ Ag(I) in aqueous solution could be determined.

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Highly Flexible and Transparent ISO/Ag/ISO Multilayer Grown by Roll-to-roll Sputtering System

  • Cho, Da-Young;Shin, Yong-Hee;Na, Seok-In;Kim, Han-Ki
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.278.2-278.2
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    • 2014
  • We have investigated the highly flexible and transparent Si-doped $In_2O_3$(ISO)/Ag/ISO multilayer grown on polyethylene terephthalate (PET) substrates using a roll-to-roll sputtering system. The electrical and optical properties of ISO/Ag/ISO multilayer electrodes depended on the insertion of a nano-size Ag layer. Due to the high conductivity of a nano-size Ag layer, the optimized ISO/Ag/ISO multilayer electrodes showed the lowest resistivity of $3.679{\times}10^{-5}Ohm-cm$, even though the ISO/Ag/ISO multilayer electrodes was sputtered at room temperature. Furthermore, the ISO/Ag/ISO multilayer electrodes exhibited a high transmittance of 86.33%, because of the anti-reflection effect, comparable to Sn-doped $In_2O_3$ (ITO) electrodes. In addition, the ISO/Ag/ISO multilayer electrodes had a very smooth surface morphology without surface defects and showed good flexibility. The flexible OSCs fabricated on ISO(30nm)/Ag(8nm)/ISO(30nm) multilayer electrode showed a power conversion efficiency of 3.272%. This result indicates that the ISO/Ag/ISO multilayer is a promising transparent conducting electrode for flexible OSCs.

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Electro-oxidation of Cyclohexanol on a Copper Electrode Modified by Copper-dimethylglyoxime Complex Formed by Electrochemical Synthesis

  • Hasanzadeh, Mohammad.;Shadjou, Nasrin.;Saghatforoush, Lotfali.;Khalilzadeh, Balal.;Kazeman, Isa.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2943-2948
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    • 2009
  • Copper-dimethylglyoxime complex (CuDMG) modified Copper electrode (Cu/CuDMG) showed a catalytic activity towards cyclohexanol oxidation in NaOH solution. The modified electrode prepared by the dimethylglyoxime anodic deposition on Cu electrode in the solution contained 0.20 M $NH_4Cl\;+\;NH_4OH\;(pH\;9.50)\;and\;1\;{\times}\;10^{-4}$ M dimethylglyoxime. The modified electrode conditioned by potential recycling in a potential range of -900${\sim}$900 mV vs. Ag/AgCl by cyclic voltammetry in alkaline medium (1 M NaOH). The results show that the CuDMG film on the electrode behaves as an efficient catalyst for the electro-oxidation of cyclohexanol in alkaline medium via Cu (III) species formed on the electrode.

The Effects of Ag Addition on the Electrode Properties of Hydrogen Storage Alloys (Zr계 수소저장합금의 전극특성에 미치는 은 첨가의 영향)

  • Noh, Hak;Jeong, So-yi;Choi, Seung-jun;Choi, Jeon;Seo, Chan-yeol;Park, Choong-Nyeon
    • Journal of Hydrogen and New Energy
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    • v.8 no.3
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    • pp.137-141
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    • 1997
  • The effects of Ag addition to Zr-based hydrogen storage alloys ($Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.4}$, $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ and $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.3}Fe_{0.1}$) on the electrode properties were examined. Ag-free and Ag-added Ze-based alloys were prepared by arc melting, crushed mechanically, and subjected to the electrochemical measurement. In $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy, 0.08 wt% Ag addition to the alloy improved the activation rate. Also Ag addition improved both activation property and discharge capacity in $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$. For these Ag-added alloys, discharge capacities with the change of charge-discharge current density(10mA, 15mA and 30mA) are almost constant. Showing very high rate capability, discharge capacity of $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.3}Fe_{0.1}$ alloy increased by Ag addition to the alloy. When the amount of Ag addition in $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy increased too much, the electrode properties became worse. Unveiling mechanism of effect of Ag addition is now progressing in our laboratory.

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A Study on the Electronic Properties of Poly-$\gamma$ Benzyl $_D$-Glutamate Organic Thin Films (Poly-${\gamma}$ Benzyl $_D$-Glutamate 유기박막의 전자이동특성에 관한 연구)

  • Song, Jin-Won;Lee, Kyung-Sup;Lee, Bong-Ju;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.86-89
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    • 2002
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Al and Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Au; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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A Study on the Interface Properties of Metal/Organic Films/Metal (Metal/Organic Films/Metal에서 계면특성에 관한 연구)

  • Song, Jin-Won;Cho, Su-Young;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.723-726
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    • 2002
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-$\gamma$ Benzyl $_D$-Glutamate/Al; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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Effect. of $TiO_2$ and PZT powder additions on the Ag/Pd Electrode for Step-down Multilayer Piezoelectric Transformer (적충 강압형 압전변압기 Ag/Pd 전극의 $TiO_2$ 와 PZT 분말의 첨가에 따른 효과연구)

  • Joo, Hyeon-Kyu;Kim, In-Sung;Vo, Vietthang;Jeong, Soon-Jong;Kim, Min-Soo;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.334-334
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    • 2010
  • In order to fabricate the multilayer piezoelectric transformer by tape casting method, we investigated the effect of $TiO_2$ and PZT powder additions on the Ag/Pd electrode. Meanwhile, effects of $TiO_2$ and PZT powder additives on the microstructure and electrical properties of Ag/Pd electrode were investigated in detail. In addition, the multilayer piezoelectric transformers were fabricated and the characteristics with various load resistance were measured at resonance frequency. The voltage step-up ratio was continuously change with increasing input voltage and load resistance, and then output voltage and powers were increased with increasing input voltage at matching impedance. The temperature rise of multilayer piezoelectric transformers were increased with increasing input voltage and load resistance. Meanwhile, multilayer piezoelectric transformers sintered at $1100^{\circ}C$ show the favorable characteristics with a power of 15 W at $100\;{\Omega}$.

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A Study on the Electronic Properties of LB Thin Films (LB박막의 전자이동 특성에 관한 연구)

  • Song, Jin-Won;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.08a
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    • pp.101-104
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    • 2002
  • Abstract We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Al; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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Determination of Copper(II) ion with a nafion-ethylenediamine modified glassy carbon electrode (내피온-에틸렌디아민이 수식된 유리탄소전극으로 구리(II) 이온의 정량)

  • Ko, Young Chun;Kim, Hee Cheol
    • Analytical Science and Technology
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    • v.20 no.3
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    • pp.213-218
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    • 2007
  • Copper(II) ion was measured with the use of a perfluorinated sulfonated polymer-ethylenediamine (nafion-en) modified glassy carbon electrode. The electrode mechanism was based on the chemical reactivity of an immobilized layer (nafion-en) to yield complex $[Cu(en)_2]^{+2}$. The reduction potential peak by differential pulse voltammetry(DPV) was observed at -0.4402V(${\pm}0.0050V$) (vs. Ag/AgCl). The linear calibration curve was obtained from $1.0{\times}10^{-6}$ to $1.0{\times}10^{-4}M$ copper(II) ion concentration, and the detection limit(3s) was $1.96{\times}10^{-6}M$.